VERFAHREN ZUR HERSTELLUNG VON BENZOL AUS METHAN
    4.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON BENZOL AUS METHAN 审中-公开
    VERFAHREN ZUR HERSTELLUNG冯BENZOL AUS METHAN

    公开(公告)号:EP2473463A2

    公开(公告)日:2012-07-11

    申请号:EP10747846.3

    申请日:2010-08-23

    Applicant: BASF SE

    CPC classification number: C07C2/76 Y02P20/584 C07C15/02

    Abstract: The present invention relates to a process for the non-oxidative dehydroaromatization of a feed stream containing C1-C4 aliphatics comprising the steps I, feeding the feed stream E into a reaction zone 1, reacting the feed stream E under non-oxidative conditions in the presence of a particulate catalyst to give a product stream P containing aromatic hydrocarbons, and removing the product stream P from the reaction zone 1; II, transferring the catalyst that is reduced in its activity by deposited coke into a reaction zone 2; III, at least partial regeneration of the catalyst with feed of a hydrogen-containing gas stream H in a reaction zone 2, wherein at least some of the deposited coke is converted into methane and a methane-containing gas stream M is formed that is fed at least in part to the reaction zone 1; IV, removing the catalyst from the reaction zone 2 and V, recirculating at least some of the catalyst that is removed to the reaction zone 1, wherein reaction zone 1 and reaction zone 2 are arranged spatially adjacently in the same reactor.

    Abstract translation: 本发明涉及一种使含有C 1 -C 4脂族化合物的反应物流非氧化脱氢芳构化的方法,包括以下步骤:将反应物流E加入到反应区1中,在非氧化条件下在颗粒催化剂存在下将反应物流E转化 涉及包含芳烃并从反应区1排出产物流P的产物流P,II。 由于沉积的焦炭进入反应区域2,III而导致活性降低的催化剂。 在反应区2中供应含氢气流H至少部分地再生催化剂,至少部分沉积的焦炭转化成甲烷以形成含甲烷的气流M,其至少部分地进料至反应 区域1,IV。 将催化剂从反应区2排出,并将至少一部分排出的催化剂再循环到反应区1中,反应区1和反应区2在相同的反应器中彼此空间上相邻布置。

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