PART-STREAM DISTILLATION
    13.
    发明公开
    PART-STREAM DISTILLATION 有权
    TEILSTROMDESTILLATION

    公开(公告)号:EP2991970A1

    公开(公告)日:2016-03-09

    申请号:EP14719778.4

    申请日:2014-04-28

    CPC classification number: C07D301/12 B01D3/143 C07D301/32

    Abstract: A continuous process for the preparation of propylene oxide, comprising(a) reacting propene, optionally admixed with propane, with hydrogen peroxide in a reaction apparatus in the presence of acetonitrile as solvent, obtaining a stream S0 containing propylene oxide, acetonitrile, water, at least one further component B, optionally propene and optionally propane, wherein the normal boiling point of the at least one component B is higher than the normal boiling point of acetonitrile and wherein the decadic logarithm of the octanol-water partition coefficient (log K
    ow ) of the at least one component B is greater than zero; (b) separating propylene oxidefrom S0, obtaining a stream S1 containing acetonitrile, water and the at least one further component B; (c) dividing S1 into two streams S2 and S3;(d) subjecting S3 to a vapor-liquid fractionation in a fractionation unit, obtaining a vapor fraction stream S4 being depleted of the at least one component B; (e) recycling at least a portion of S4, optionally after work-up, to (a).

    Abstract translation: 一种用于制备环氧丙烷的连续方法,包括(a)在乙腈作为溶剂的存在下,在反应装置中将丙烯任选与丙烷一起与过氧化氢反应,得到含有环氧丙烷,乙腈,水的流S0 至少一种另外的组分B,任选的丙烯和任选的丙烷,其中至少一种组分B的标准沸点高于乙腈的标准沸点,其中辛醇 - 水分配系数(log Kow)的十进制对数 所述至少一个组分B大于零; (b)从S0分离环氧丙烷,得到含有乙腈,水和至少一种其它组分B的料流S1; (c)将S1划分成两个流S2和S3; (d)使S3在分馏装置中进行汽 - 液分馏,得到耗尽至少一种B成分的蒸汽馏分流S4; (e)将至少一部分S4,任选地在后处理之后再循环至(a)。

    PROCESS FOR PREPARING A TITANIUM-CONTAINING ZEOLITIC MATERIAL HAVING AN MWW FRAMEWORK STRUCTURE
    14.
    发明公开
    PROCESS FOR PREPARING A TITANIUM-CONTAINING ZEOLITIC MATERIAL HAVING AN MWW FRAMEWORK STRUCTURE 审中-公开
    VERFAHREN ZUR HERSTELLUNG VON TITANHALTIGEM ZEOLITHMATERIAL MIT EINER MWW-RAHMENSTRUKTUR

    公开(公告)号:EP2953895A1

    公开(公告)日:2015-12-16

    申请号:EP14703328.6

    申请日:2014-02-05

    Applicant: BASF SE

    CPC classification number: B01J37/0045 B01J29/7038 B01J29/89 C01B39/085

    Abstract: A process for the preparation of a titanium-containing zeolitic material having an MWW framework structure, the process comprising (i) providing a zeolitic material having an MWW framework structure comprising SiO2 and B2O3, (ii) incorporating titanium into the zeolitic material provided in (i) comprising (ii.I) preparing an aqueous synthesis mixture containing the zeolitic material provided in (i), an MWW template compound and a titanium source, (ii.2) hydrothermally synthesizing a titanium-containing zeolitic material having an MWW framework structure from the aqueous synthesis mixture prepared in (ii.1), obtaining a mother liquor comprising the titanium-containing zeolitic material having an MWW framework structure; (iii) spray-drying the mother liquor obtained from (ii.2) comprising the titanium-containing zeolitic material having an MWW framework structure.

    Abstract translation: 一种制备具有MWW骨架结构的含钛沸石材料的方法,该方法包括(i)提供具有包含SiO 2和B 2 O 3的MWW骨架结构的沸石材料,(ii)将钛掺入提供于 i)包括(ii.1)制备含有(i)中提供的沸石材料的水性合成混合物,MWW模板化合物和钛源,(ii.2)水热合成具有MWW骨架结构的含钛沸石材料 从(ii.1)中制备的水性合成混合物得到含有具有MWW骨架结构的含钛沸石材料的母液; (iii)喷雾干燥从包含具有MWW骨架结构的含钛沸石材料的(ii.2)获得的母液。

    PROCESS FOR THE SEPARATION OF UNBRANCHED HYDROCARBONS FROM THEIR BRANCHED ISOMERS
    18.
    发明授权
    PROCESS FOR THE SEPARATION OF UNBRANCHED HYDROCARBONS FROM THEIR BRANCHED ISOMERS 有权
    方法用于分离的支链烃不会从支化异构

    公开(公告)号:EP2176201B1

    公开(公告)日:2014-06-04

    申请号:EP08774533.7

    申请日:2008-06-30

    Applicant: BASF SE

    Abstract: The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of-contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.

    VERFAHREN ZUR HERSTELLUNG EINES SILIKATES
    20.
    发明授权
    VERFAHREN ZUR HERSTELLUNG EINES SILIKATES 有权
    用于生产硅酸盐

    公开(公告)号:EP1937594B1

    公开(公告)日:2014-01-29

    申请号:EP06794010.6

    申请日:2006-10-11

    CPC classification number: C01B37/02 Y02P20/582

    Abstract: Preparing silicon and oxygen-containing silicates comprises mixing silicon dioxide and/or its precursors with an aqueous solution containing at least an ammonium ion compound (I), tetra-alkyl ammonium compound and at least a base type; and heating the obtained colloidal solution, at a temperature greater than the boiling temperature of the colloidal solution under the selected pressure, at up to 180[deg]C at a normal pressure to obtain a suspension containing the silicate, where the silicon and oxygen-containing silicate is added as a crystallization-supporting agent in the first step. Preparation of silicon and oxygen-containing silicates comprises mixing silicon dioxide and/or its precursors with an aqueous solution containing at least an ammonium ion compound (I) of formula (R 1R 2R 3R 4N +>), tetra-alkyl ammonium compound and at least a base type; and heating the obtained colloidal solution, at a temperature greater than the boiling temperature of the colloidal solution under the selected pressure, at up to 180[deg]C at a normal pressure to obtain a suspension containing the silicate, where the silicon and oxygen-containing silicate is added as a crystallization-supporting agent in the first step. R 1,R 2methyl; and R 3,R 4n-propyl. Independent claims are included for: (1) a layered silicate, obtained from the process, containing a reflection with an intensity of 100, 11-21, 13-23, 5-15, 7-17, 19-29% and a corresponding bending angle of 8-8.4, 11-11.4, 13.2-13.6, 18-18.4, 18.4-18.8 and 19.9-20, where the intensity of the highest peak in the X-ray diffractogram is 100%; (2) a silicate scaffold, obtained from the process, containing a reflection with an intensity of 100, 24-34, 9-19, 12-22 and 19-29 and a corresponding bending angle of 9-8-10.2, 11-11.4, 15.5-15.9, 19.4-19.6 and 19.6-19.8, where the intensity of the highest peak in the X-ray diffractogram is 100%; (3) a molded body comprising the silicate scaffold; and (4) a procedure for preparing the molded body comprising preparing the silicate and kneading a mixture containing the silicate scaffold and at least a binding agent, shaping of the kneaded mixture to form the molded body, and drying and calcinating the molded body.

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