Abstract:
The present invention relates to a process for the regeneration of a catalyst comprising a titanium-containing zeolite, said catalyst having been used in a process for the preparation of an olefin oxide and having phosphate deposited thereon, said process for the regeneration comprising the steps: (a) separating the reaction mixture from the catalyst, (b) washing the catalyst obtained from (a) with liquid aqueous system; (c) optionally drying the catalyst obtained from (b) in a gas stream comprising an inert gas at a temperature of less than 300° C.; (d) calcining the catalyst obtained from (c) in a gas stream comprising oxygen at a temperature of at least 300° C.
Abstract:
The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material having a BEA framework structure comprising YO 2 and optionally comprising X 2 O 3 , wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals and at least one source for YO 2 ; and (2) crystallizing the mixture; wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises at least one alkali metal M, wherein when the BEA framework additionally comprises X 2 O 3 , the mixture according to step (1) comprises at least one source for X 2 O 3 , and wherein the seed crystals comprise zeolitic material having a BEA framework structure, preferably zeolite Beta.
Abstract translation:本发明涉及一种用于生产具有包含YO 2且任选地包含X 2 O 3的BEA骨架结构的沸石材料的无机模板合成方法,其中所述方法包括以下步骤:(1)制备包含晶种 和至少一个YO 2来源; 和(2)使混合物结晶; 其中Y是四价元素,X是三价元素,其中沸石材料任选地包含至少一种碱金属M,其中当BEA骨架另外包含X 2 O 3时,根据步骤(1)的混合物至少包含 一种X 2 O 3源,其中晶种包含具有BEA骨架结构的沸石材料,优选沸石β。
Abstract:
A continuous process for the preparation of propylene oxide, comprising(a) reacting propene, optionally admixed with propane, with hydrogen peroxide in a reaction apparatus in the presence of acetonitrile as solvent, obtaining a stream S0 containing propylene oxide, acetonitrile, water, at least one further component B, optionally propene and optionally propane, wherein the normal boiling point of the at least one component B is higher than the normal boiling point of acetonitrile and wherein the decadic logarithm of the octanol-water partition coefficient (log K ow ) of the at least one component B is greater than zero; (b) separating propylene oxidefrom S0, obtaining a stream S1 containing acetonitrile, water and the at least one further component B; (c) dividing S1 into two streams S2 and S3;(d) subjecting S3 to a vapor-liquid fractionation in a fractionation unit, obtaining a vapor fraction stream S4 being depleted of the at least one component B; (e) recycling at least a portion of S4, optionally after work-up, to (a).
Abstract:
A process for the preparation of a titanium-containing zeolitic material having an MWW framework structure, the process comprising (i) providing a zeolitic material having an MWW framework structure comprising SiO2 and B2O3, (ii) incorporating titanium into the zeolitic material provided in (i) comprising (ii.I) preparing an aqueous synthesis mixture containing the zeolitic material provided in (i), an MWW template compound and a titanium source, (ii.2) hydrothermally synthesizing a titanium-containing zeolitic material having an MWW framework structure from the aqueous synthesis mixture prepared in (ii.1), obtaining a mother liquor comprising the titanium-containing zeolitic material having an MWW framework structure; (iii) spray-drying the mother liquor obtained from (ii.2) comprising the titanium-containing zeolitic material having an MWW framework structure.
Abstract translation:一种制备具有MWW骨架结构的含钛沸石材料的方法,该方法包括(i)提供具有包含SiO 2和B 2 O 3的MWW骨架结构的沸石材料,(ii)将钛掺入提供于 i)包括(ii.1)制备含有(i)中提供的沸石材料的水性合成混合物,MWW模板化合物和钛源,(ii.2)水热合成具有MWW骨架结构的含钛沸石材料 从(ii.1)中制备的水性合成混合物得到含有具有MWW骨架结构的含钛沸石材料的母液; (iii)喷雾干燥从包含具有MWW骨架结构的含钛沸石材料的(ii.2)获得的母液。
Abstract:
The invention relates to a storage unit (12) for a drive system (10) in a vehicle, which has at least one sorption store (18), at least one battery (16) and at least one cooling circuit (26), wherein the sorption store (18) is coupled via the cooling circuit (26) to the battery (16). The invention additionally relates to a method of operating the storage unit (12) and also a drive system (10) and a vehicle equipped with such a storage unit (12).
Abstract:
The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material comprising YO 2 and X 2 O 3 , wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals, one or more sources for YO 2 , one or more sources for X 2 O 3 , and one or more solvents; (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material comprising YO 2 and X 2 O 3 as a crystallization product; wherein Y is a tetravalent element, and X is a trivalent element, and wherein at least a portion of the mother liquor obtained in step (2) is recycled to step (1) as a source for YO 2 , optionally after concentration of the mother liquor.
Abstract:
The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of-contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.
Abstract:
Disclosed is a process for the alkylation of an organic compound comprising: (a) providing a catalyst comprising one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO 2 and optionally comprises X 2 O 3 , wherein Y is a tetravalent element, and X is a trivalent element, (b) contacting the catalyst with one or more alkylatable organic compounds in the presence of one or more alkylating agents in one or more reactors for obtaining one or more alkylated organic compounds, wherein the one or more zeolitic materials is obtainable from a synthetic process which does not employ an organotemplate as structure directing agent.
Abstract:
Preparing silicon and oxygen-containing silicates comprises mixing silicon dioxide and/or its precursors with an aqueous solution containing at least an ammonium ion compound (I), tetra-alkyl ammonium compound and at least a base type; and heating the obtained colloidal solution, at a temperature greater than the boiling temperature of the colloidal solution under the selected pressure, at up to 180[deg]C at a normal pressure to obtain a suspension containing the silicate, where the silicon and oxygen-containing silicate is added as a crystallization-supporting agent in the first step. Preparation of silicon and oxygen-containing silicates comprises mixing silicon dioxide and/or its precursors with an aqueous solution containing at least an ammonium ion compound (I) of formula (R 1R 2R 3R 4N +>), tetra-alkyl ammonium compound and at least a base type; and heating the obtained colloidal solution, at a temperature greater than the boiling temperature of the colloidal solution under the selected pressure, at up to 180[deg]C at a normal pressure to obtain a suspension containing the silicate, where the silicon and oxygen-containing silicate is added as a crystallization-supporting agent in the first step. R 1,R 2methyl; and R 3,R 4n-propyl. Independent claims are included for: (1) a layered silicate, obtained from the process, containing a reflection with an intensity of 100, 11-21, 13-23, 5-15, 7-17, 19-29% and a corresponding bending angle of 8-8.4, 11-11.4, 13.2-13.6, 18-18.4, 18.4-18.8 and 19.9-20, where the intensity of the highest peak in the X-ray diffractogram is 100%; (2) a silicate scaffold, obtained from the process, containing a reflection with an intensity of 100, 24-34, 9-19, 12-22 and 19-29 and a corresponding bending angle of 9-8-10.2, 11-11.4, 15.5-15.9, 19.4-19.6 and 19.6-19.8, where the intensity of the highest peak in the X-ray diffractogram is 100%; (3) a molded body comprising the silicate scaffold; and (4) a procedure for preparing the molded body comprising preparing the silicate and kneading a mixture containing the silicate scaffold and at least a binding agent, shaping of the kneaded mixture to form the molded body, and drying and calcinating the molded body.