Abstract:
The invention relates to a method for producing silylated monocarboxylic acids by conversion of C 2 -C 10 -Monocarboxylic acids having halogen silanes of the general formula (I) SiHal 4-x R x , wherein HaI is a halogen atom selected from the group fluorine, chlorine, bromine or iodine, R is independent hydrogen, C 1 -C 10 -Alkyl or aryl and x is a whole number from 0 to 3, forming hydrogen halide in the presence of an auxiliary base, wherein the auxiliary base forms a salt with the hydrogen halide that, having the desired product or the solution of the desired product in a suitable solvent, forms two unmixable phases and is separated.
Abstract:
The invention relates to a method for the heterogeneously-catalysed gas phase partial oxidation of an organic compound on a catalyst fixed bed in a multiple-contact fixed bed reactor, whereby the reduction in quality of the catalyst coating with increasing service duration is compensated by a partial catalyst exchange.
Abstract:
The invention relates to a method for filling a reactor with a catalyst, to the thus obtained reactors filled with said catalyst, and to the use thereof for carrying out catalytic gas phase reactions.
Abstract:
The invention relates to a method for the heterogenically catalysed partial gas phase oxidation of propene to form acrylic acid. According to said method, the reaction starting mixture with a propene charge of
Abstract:
A lubricant composition having improved non-Newtonian viscometrics includes at least 85 weight percent of a base oil and 1 to 15 weight percent of a lubricant additive. The additive itself includes 10 to 80 weight percent of a diluent oil and 30 to 80 weight percent of a random co-polymeric viscosity index improver. The viscosity index improver is the free-radical polymerization product of at least 5 to 15 weight percent methyl methacrylate and 5 to 95 weight percent of a C8-C10 alkyl (meth)acrylate. The additive is formed using a method that includes the step of providing the diluent oil, the methyl methacrylate, the C8-C10 alkyl (meth)acrylate, and a free-radical initiator. The method also includes the steps of flowing the diluent oil into a reactor, flowing the methyl methacrylate and the C8-C10 alkyl (meth)acrylate into the reactor independently from the free-radical initiator, and flowing the free-radical initiator into the reactor.
Abstract:
Method for producing (meth)acrylic acid esters (E) of polyalkoxy group-containing alcohols by reacting polyalkoxy-group containing alcohols (P) of formula (I), where R1 represents hydrogen, a hydroxy group or a linear or branched, saturated or unsaturated, alcohol having from 1 to 30 C atoms, R 2 , R 3 represent independently of one another H or methyl, and m and n represent independently of one another a whole integer between 0 and 100, with the proviso that m and n may not simultaneously be 0, in the presence of at least one basic catalyst (K) having a pK B value not above 7.0, with at least one sterically hindered polymerization inhibitor comprising a (meth) acrylic acid anhydride (A), characterized in that following completion of the reaction the reaction mixture is quenched with a C 1 -C 6 -alkanol.