VERFAHREN ZUR SILYLIERUNG VON MONOCARBONSÄUREN
    11.
    发明公开
    VERFAHREN ZUR SILYLIERUNG VON MONOCARBONSÄUREN 有权
    过程为甲硅烷基化一元羧酸的

    公开(公告)号:EP2379567A1

    公开(公告)日:2011-10-26

    申请号:EP09760918.4

    申请日:2009-12-03

    Applicant: BASF SE

    CPC classification number: C07F7/1896

    Abstract: The invention relates to a method for producing silylated monocarboxylic acids by conversion of C
    2 -C
    10 -Monocarboxylic acids having halogen silanes of the general formula (I) SiHal
    4-x R
    x , wherein HaI is a halogen atom selected from the group fluorine, chlorine, bromine or iodine, R is independent hydrogen, C
    1 -C
    10 -Alkyl or aryl and x is a whole number from 0 to 3, forming hydrogen halide in the presence of an auxiliary base, wherein the auxiliary base forms a salt with the hydrogen halide that, having the desired product or the solution of the desired product in a suitable solvent, forms two unmixable phases and is separated.

    VERFAHREN ZUR HERSTELLUNG VON (METH)ACRYLSÄUREESTERN VON POLYALKOXYGRUPPEN ENTHALTENDEN ALKOHOLEN
    17.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON (METH)ACRYLSÄUREESTERN VON POLYALKOXYGRUPPEN ENTHALTENDEN ALKOHOLEN 审中-公开
    用于生产醇的(甲基)丙烯酸酯的,包括聚烷氧基

    公开(公告)号:EP3107951A1

    公开(公告)日:2016-12-28

    申请号:EP15701801.1

    申请日:2015-01-30

    Applicant: BASF SE

    CPC classification number: C07C67/08 C08G65/3322

    Abstract: Method for producing (meth)acrylic acid esters (E) of polyalkoxy group-containing alcohols by reacting polyalkoxy-group containing alcohols (P) of formula (I), where R1 represents hydrogen, a hydroxy group or a linear or branched, saturated or unsaturated, alcohol having from 1 to 30 C atoms, R
    2 , R
    3 represent independently of one another H or methyl, and m and n represent independently of one another a whole integer between 0 and 100, with the proviso that m and n may not simultaneously be 0, in the presence of at least one basic catalyst (K) having a pK
    B value not above 7.0, with at least one sterically hindered polymerization inhibitor comprising a (meth) acrylic acid anhydride (A), characterized in that following completion of the reaction the reaction mixture is quenched with a C
    1 -C
    6 -alkanol.

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