公开(公告)号：EP2029508A1

公开(公告)日：2009-03-04

申请号：EP07726528.8

申请日：2007-02-27

Applicant: BASF SE

Inventor： MAAS, Steffen ,  JOHANN, Thorsten ,  KOCH, Michael ,  SIRCH, Tilman ,  SCHLITTER, Stephan ,  RITTINGER, Stefan ,  STEINIGER, Michael ,  SPENGEMAN, Todd, C.

IPC: C07C29/141 ,  C07C31/20

CPC classification number: C07C29/141 ,  C07C31/20

Abstract: A process for catalytically hydrogenating methylolalkanals of the general formula (I) in which R1 and R2 each signifies, independent of one another, a further methylol group or an alkyl group having from 1 to 22 C atoms, or an aryl or aralkyl group having from 6 to 33 C atoms, in the liquid phase with hydrogen over a hydrogenation catalyst, characterized by the use of the molar ratio of hydrogen to methylolalkanal of greater than 1.

公开(公告)号：EP2376413B2

公开(公告)日：2018-10-31

申请号：EP09764533.7

申请日：2009-12-07

Applicant: BASF SE

Inventor： SIRCH, Tilman ,  STEINIGER, Michael ,  MAAS, Steffen ,  RITTINGER, Stefan ,  SCHLITTER, Stephan

IPC: C07C29/141 ,  C07C31/24 ,  C07C31/20 ,  C07C31/22 ,  C07C29/80 ,  C08G18/56 ,  C08G63/16

CPC classification number: C07C29/141 ,  C07C29/80 ,  C08G18/56 ,  C08G63/16 ,  C08L67/00 ,  C08L75/04 ,  C07C31/245 ,  C07C31/20 ,  C07C31/22

公开(公告)号：EP2376413A2

公开(公告)日：2011-10-19

申请号：EP09764533.7

申请日：2009-12-07

Applicant: BASF SE

Inventor： SIRCH, Tilman ,  STEINIGER, Michael ,  MAAS, Steffen ,  RITTINGER, Stefan ,  SCHLITTER, Stephan

IPC: C07C29/80 ,  C07C31/20 ,  C07C31/22 ,  C07C31/24

CPC classification number: C07C29/141 ,  C07C29/80 ,  C08G18/56 ,  C08G63/16 ,  C08L67/00 ,  C08L75/04 ,  C07C31/245 ,  C07C31/20 ,  C07C31/22

Abstract: The invention relates to a method for distilling an aqueous polymethylol mixture, comprising a polymethylol of formula (I), where R independently = a further methylol group, or 1 to 22 C alkyl, or a 6 to 22 C aryl or aralkyl group, a tertiary amine, water and the adduct of tertiary amine and formic acid, (amine formate), characterised in that the distillation is carried out in a distillation column connected to an evaporator at the kettle, wherein the kettle temperature is maintained above the boiling point of the mono-ester of formic acid and polymethylol (polymethylol formate) formed during the distillation. The invention further relates to a composition comprising polymethylol and 1 to 10,000 ppm by weight of polymethylol formate and the use thereof.

公开(公告)号：EP1694438B1

公开(公告)日：2010-11-24

申请号：EP04803522.4

申请日：2004-12-04

Applicant: BASF SE

Inventor： SCHLITTER, Stephan ,  SCHUBERT, Olga ,  HESSE, Michael ,  BORCHERS, Sabine ,  RÖSCH, Markus ,  PINKOS, Rolf ,  WECK, Alexander ,  WINDECKER, Gunther

IPC: B01J23/72 ,  B01J37/00 ,  C07D307/08 ,  C07D315/00 ,  C07C29/136

CPC classification number: B01J23/72 ,  B01J21/04 ,  B01J23/94 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/18 ,  B01J38/10 ,  B01J38/12 ,  C07C29/149 ,  C07D315/00 ,  Y02P20/584

Abstract: The invention relates to a catalyst provided in the form of an extrudate, which contains 5 to 85 % by weight of copper oxide and comprises, in the active material and as binders, the same oxidic carrier material. The invention also relates to the use of the catalyst for hydrogenating carbonyl compounds.

公开(公告)号：EP1993983A1

公开(公告)日：2008-11-26

申请号：EP07712307.3

申请日：2007-02-23

Applicant: BASF SE

Inventor： MAAS, Steffen ,  JOHANN, Thorsten ,  KOCH, Michael ,  SIRCH, Tilman ,  SCHLITTER, Stephan ,  RITTINGER, Stefan ,  STEINIGER, Michael

IPC: C07C29/141 ,  C07C31/20

CPC classification number: C07C29/141 ,  C07C31/20 ,  C07C31/22 ,  C07C31/245

Abstract: A process for catalytically hydrogenating methylolalkanals of the general formula (I) in which R1 and R2 are each independently a further methylol group or an alkyl group having from 1 to 22 carbon atoms or an aryl or aralkyl group having from 6 to 33 carbon atoms, in the liquid phase over a hydrogenation catalyst, which comprises setting a pH of from 7.0 to 9.0 in the hydrogenation effluent by adding at least one tertiary amine, an inorganic base or an inorganic or organic acid to the hydrogenation feed.

Abstract translation: 一种催化氢化通式（I）的羟甲基链烷醛的方法，其中R1和R2各自独立地为另一个羟甲基或具有1至22个碳原子的烷基或具有6至33个碳原子的芳基或芳烷基， 在氢化催化剂上的液相中进行，其包括通过将至少一种叔胺，无机碱或无机或有机酸加入到氢化进料中来将氢化流出物中的pH设定为7.0至9.0。

公开(公告)号：EP1986772B1

公开(公告)日：2018-05-30

申请号：EP07704398.2

申请日：2007-02-07

Applicant: BASF SE

Inventor： SCHLITTER, Stephan ,  HATSCHER, Stephan ,  HESSE, Michael ,  URTEL, Heiko

IPC: B01J20/06 ,  B01J20/30 ,  B01J20/34 ,  B01D53/02 ,  B01J23/80

CPC classification number: B01J23/80 ,  B01D53/02 ,  B01D53/865 ,  B01D2255/20715 ,  B01D2255/20761 ,  B01D2257/502 ,  B01J20/06 ,  B01J20/3007 ,  B01J20/3078 ,  B01J20/3236 ,  B01J20/3433 ,  B01J20/3458 ,  B01J20/3483 ,  B01J2220/56

公开(公告)号：EP2385933B1

公开(公告)日：2014-06-25

申请号：EP10700515.9

申请日：2010-01-07

Applicant: BASF SE

Inventor： SCHLITTER, Stephan ,  STEINIGER, Michael ,  RITTINGER, Stefan ,  SIRCH, Tilman ,  MAAS, Steffen

IPC: C07C29/141 ,  C07C45/75 ,  C07C45/82

CPC classification number: C07C29/80 ,  C07C29/141 ,  C07C45/75 ,  C07C45/82 ,  C07C31/22 ,  C07C31/245 ,  C07C47/19

公开(公告)号：EP1694662B1

公开(公告)日：2012-09-05

申请号：EP04803523.2

申请日：2004-12-04

Applicant: BASF SE

Inventor： RÖSCH, Markus ,  PINKOS, Rolf ,  HESSE, Michael ,  SCHLITTER, Stephan ,  JUNICKE, Henrik ,  SCHUBERT, Olga ,  WECK, Alexander ,  WINDECKER, Gunther

IPC: C07D307/08 ,  C07D307/32

CPC classification number: C07D307/33 ,  C07D307/08

公开(公告)号：EP2134669A1

公开(公告)日：2009-12-23

申请号：EP08709204.5

申请日：2008-02-25

Applicant: BASF SE

Inventor： SIRCH, Tilman ,  STEININGER, Michael ,  MAAS, Steffen ,  RITTINGER, Stefan ,  SCHLITTER, Stephan

IPC: C07C29/141 ,  C07C45/75 ,  C07C45/82 ,  C07C47/19

CPC classification number: C07C45/75 ,  C07C29/141 ,  C07C45/82 ,  C07C47/19 ,  C07C31/20

Abstract: The invention relates to hydroxy pivalin aldehyde, which is produced by the aldolization of isobutyraldehyde with formaldehyde and subsequent processing of the reaction product by distillation, wherein the reaction product is fed to a distillation column, which is operated at a top pressure ranging between 0.5 and 1.5 bar and in which a two-stage condensation process is provided in the top region. In this process, the vapors are first fed to a partial condenser operated at a temperature ranging between 50 and 80ºC, the condensate of which is returned at least partially to the distillation column, and the vapors that are not condensed in the partial condenser are fed to a downstream condenser operated at a temperature ranging between -40º and +30ºC, the condensate of which is discharged at least partially.