公开(公告)号：EP2697272A1

公开(公告)日：2014-02-19

申请号：EP12723926.7

申请日：2012-04-05

Applicant: Bromine Compounds Ltd.

Inventor： OREN, Jacob

IPC: C08F120/22 ,  C07C69/54

CPC classification number: C07C67/10 ,  C07C67/14 ,  C08F22/10 ,  C08F120/22 ,  C08F220/22 ,  C08F220/68 ,  C07C69/653

Abstract: The invention relates to a process for preparing pentabromobenzyl acrylate through the reaction of pentahalobenzyl halide with a salt of acrylic acid in water-immiscible solvent, wherein said salt is in aqueous form and the reaction is carried out in the presence of a phase transfer catalyst. A process for polymerizing the pentabromobenzyl acrylate in halogenated aromatic solvent and the poly (pentabromobenzyl acrylate) obtained are also disclosed.

公开(公告)号：EP2066616B1

公开(公告)日：2013-07-03

申请号：EP07814193.4

申请日：2007-08-17

Applicant: 3M Innovative Properties Company

Inventor： FLYNN, Richard M. ,  YANDRASITS, Michael A.

IPC: C07C69/653 ,  C07C29/58 ,  C07C29/62 ,  C08F220/24 ,  C07C67/14

CPC classification number: C07C69/653 ,  C07C29/58 ,  C07C29/62 ,  C07C67/14 ,  C08F220/24 ,  Y10T428/3154 ,  C07C29/147 ,  C07C33/025 ,  C07C31/34 ,  C07C31/38

公开(公告)号：EP1995228B1

公开(公告)日：2011-05-04

申请号：EP07738163.0

申请日：2007-03-09

Applicant: Unimatec Co., Ltd.

Inventor： MURATA, Seiichiro ,  HORIUTI, Masayosi ,  SATO, Katsuyuki ,  ABE, Hideki ,  TATSU, Haruyoshi

IPC: C07C31/38 ,  C07C29/124 ,  C07C67/08 ,  C07C69/653 ,  C07B61/00

CPC classification number: C07C31/38 ,  C07C17/275 ,  C07C19/16 ,  C07C29/09 ,  C07C29/124 ,  C07C67/08 ,  C07C69/653

Abstract: A polyfluoroalkyl alcohol, or a (meth)acrylic acid derivative thereof, represented by the following general formula : €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒC n F 2n+1 (CH 2 CF 2 ) a (CF 2 CF 2 ) b (CH 2 CH 2 ) c OR (R : H or (meth)acrylic acid group ; n : 1-6 ; a : 1-4 ; b : 1-3 ; and c : 1-3). Polyfluoroalkyl alcohol (R : hydrogen atom) can be produced by reaction of fluoroalkyl iodide represented by the following general formula : €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒC n F 2n+1 (CH 2 CF 2 ) a (CF 2 CF 2 ) b (CH 2 CH 2 ) c I with N-methyl formamide, followed by hydrolysis in the presence of an acid catalyst, whereas polyfluoroalkyl alcohol (meth)acrylic acid derivative (R : (meth)acrylic acid group) can be produced by reaction of the polyfluoroalkyl alcohol with (meth)acrylic acid.

公开(公告)号：EP2208723A1

公开(公告)日：2010-07-21

申请号：EP10001399.4

申请日：2005-12-22

Applicant: Merck Patent GmbH

Inventor： Kirsch, Peer, Dr. ,  Franz, Klaus-Dieter, Dr. ,  Ruhl, Andreas

IPC: C07C381/00 ,  A62D1/00 ,  B01F17/00

CPC classification number: C07C43/137 ,  A62D1/0085 ,  B01F17/0035 ,  C07C43/123 ,  C07C69/653 ,  C07C309/10 ,  C07C381/00 ,  C07D213/20

Abstract: Gegenstand der vorliegenden Erfindung ist die Verwendung von Verbindungen enthaltend mindestens eine hydrophobe Endgruppen Y als oberflächenaktive Mittel, wobei Y für CF 3 O- oder F 5 S- steht.

Abstract translation: 在表面活性化合物（A）中使用Y 1>端基（I）作为疏水性端基。 在表面活性化合物（A）中使用Y 1>端基（其中Y是CF 3 O-或F 5 S-）（I）作为疏水性端基。 还包括以下独立权利要求：（1）式（Y 1> -Spacer-X）的低分子化合物（II）的制备，其包括制备式（Y 1> -Spacer-OH）的醇化合物并修饰OH - 标准方法给予（II）; （2）制备式（F 3 CO-（CH 2）n -OH）的三氟甲氧基化合物，其包括将保护的二醇转化为受保护的一氟三氟甲氧基醇，然后在标准方法中脱保护和改性OH-基团; （3）制备式（F 5 S-（CH 2）n X，F 5 S-CH 2 -CH（HalHCH 2）（n-1）-X，F 5 S-CH = CH-（CH 2））的五氟硫醚化合物， （n-1）-X）包括X基的卤代氢消除，然后使用标准方法水合和修饰OH-基团; 和（4）包含（A）与（I）的试剂和用于相应用途的合适载体和其它特定活性物质。 间隔物：饱和或不饱和，支链或非支链烃单元; X：阳离子型，非离子型，两性或阴离子极性基团或可聚合基团。

公开(公告)号：EP2039672A4

公开(公告)日：2010-07-14

申请号：EP07768153

申请日：2007-07-04

Applicant: ASAHI GLASS CO LTD

Inventor： MATSUKAWA YASUHISA ,  SHIRAKAWA DAISUKE ,  MUROTANI EISUKE ,  SHIROTA NAOKO ,  TAKEBE YOKO

IPC: C07C49/467 ,  C07C67/14 ,  C07C69/653 ,  C08F20/22

CPC classification number: C07C49/477 ,  C07C29/143 ,  C07C29/147 ,  C07C31/44 ,  C07C35/52 ,  C07C45/54 ,  C07C61/40 ,  C07C67/14 ,  C07C69/653 ,  C07C69/753 ,  C07C2602/42 ,  C08F220/24

公开(公告)号：EP2081887A2

公开(公告)日：2009-07-29

申请号：EP07811679.5

申请日：2007-09-04

Applicant: GREAT LAKES CHEMICAL CORPORATION

Inventor： JACKSON, Andrew ,  SHARMA, Vimal ,  EDWARDS, E., Bradley ,  BOGGS, Janet ,  HEDRICK, Vicki ,  BRANDSTADTER, Stephan ,  CHIEN, John ,  NORMAN, Edward ,  KAUFMAN, Robert ,  AMEDURI, Bruno ,  KOSTOV, George

IPC: C07C311/09 ,  C07C317/18 ,  C07C19/075 ,  C07C19/10 ,  C07C19/16 ,  C07C21/18 ,  C07C22/02 ,  C07C43/13 ,  C07C69/653 ,  C07F9/09 ,  C07F9/14

CPC classification number: C07C311/09 ,  C07C69/653 ,  C07C317/18 ,  C07F9/091 ,  C08F220/24 ,  C11D1/004 ,  C11D3/0031 ,  C11D3/32 ,  C11D3/349

Abstract: RF-compositions including surfactants, foam stabilizers, monomers, polymers, urethanes, intermediates, metal complexes, phosphate esters as well as telomerization methods are provided.

公开(公告)号：EP2070901A1

公开(公告)日：2009-06-17

申请号：EP08021787.0

申请日：2007-01-31

Applicant: Shin-Etsu Chemical Co., Ltd.

Inventor： Hasegawa, Koji ,  Kinsho, Takeshi ,  Nishi, Tsunehiro ,  Ohashi, Masaki ,  Watanabe, Takeru

IPC: C07C29/136 ,  C07C31/42 ,  C07C31/44 ,  G03F7/004 ,  C08F220/24 ,  C08F22/28

CPC classification number: G03F7/0395 ,  C07C29/147 ,  C07C69/54 ,  C07C69/653 ,  C07C69/753 ,  C07C2601/08 ,  C07C2601/14 ,  C07C2602/42 ,  C08F220/24 ,  C08F220/28 ,  C08F232/08 ,  G03F7/0046 ,  G03F7/0397 ,  C07C31/44 ,  C07C31/42 ,  C07C35/48

Abstract: Fluoroalcohol compounds of formula (4) are prepared by reacting a fluorine compound of formula (1) with reducing agents or organometallic reagents of formulas (2) and (3) wherein R 1 is H or a monovalent C 1 -C 20 hydrocarbon group in which any -CH 2 - moiety may be replaced by -O- or -C(=O)-, R 2 is H or a monovalent C 1 -C 6 hydrocarbon group, R 3 and R 4 are H or a monovalent C 1 -C 8 hydrocarbon group, and M 1 is Li, Na, K, Mg, Zn, Al, B, or Si. From the fluoroalcohol compounds, fluorinated monomers can be produced in a simple and economic way, which are useful in producing polymers for the formulation of radiation-sensitive resist compositions.


         R 3 M 1      (2)

         R 4 M 1      (3)

Abstract translation: 式（4）的氟化合物通过使式（1）的氟化合物与式（2）和（3）的还原剂或有机金属试剂反应来制备，其中R 1是H或一价C 1 -C 20烃基 其中任何-CH 2 - 部分可被-O-或-C（= O） - ，R 2为H或一价C 1 -C 6烃基，R 3和R 4为H或一价C 1 -C 8烃基，M 1为Li，Na，K，Mg，Zn，Al，B或Si。 从氟代醇化合物可以以简单和经济的方式制备氟化单体，其可用于制备用于制备辐射敏感抗蚀剂组合物的聚合物。 €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒR 3 M 1€ƒ€ƒ€ƒ€ƒ（2）€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒR 4 M 1€ƒ€ƒ€ƒ€ƒ（3）

公开(公告)号：EP1976820A2

公开(公告)日：2008-10-08

申请号：EP06830802.2

申请日：2006-12-22

Applicant: Clariant International Ltd.

Inventor： GÖTZ, Hans ,  KNAUP, Wolfgang ,  PROBST, Anton ,  AHOLLINGER, Christian

IPC: C07C67/08 ,  C07C69/653 ,  C08F220/24 ,  D06M15/277

CPC classification number: D06M15/277 ,  C07C31/38 ,  C07C69/653 ,  C08F220/18 ,  C08F220/24 ,  C08F220/28 ,  C08F220/32 ,  D06M2200/11 ,  D06M2200/12

Abstract: Claimed are fluorous telomeric co mpounds of the formula: RF - A - [CH2]cCR2R3 - Z where RF is a perfluoroalkyl radical o f 1 to 20 carbon atoms, A is a group of the formulae (I) or (II). R1 is CF3 OR4, Cl, Br or I, R2 and R3 are H, alkyl or aryl R4 is perfluoromethyl, perfluoropropyl or perfluoropropyloxypropyl X and Y are H, Cl or F Z is -OH, -OCOCH=CH2 or -OCOCCH3=CH2 a is fro m 0 to 10, b is fro m 1 to 30 and c is fro m 1 to 30. These co mpounds are copolymerized wit h further mo no mers. The copolymers thus obtained are useful for water-, oil- and soil-repellent finishing of fibrous substrates.

公开(公告)号：EP1942091A1

公开(公告)日：2008-07-09

申请号：EP06822275.1

申请日：2006-10-25

Applicant: Asahi Glass Company, Limited

Inventor： WANG, Shu-zhong ,  MURATA, Koichi ,  OHARU, Kazuya ,  MORIZAWA, Yoshitomi ,  YOKOKOJI, Osamu ,  SHIROTA, Naoko

IPC: C07C17/363 ,  C07C23/38 ,  C07C29/38 ,  C07C31/44 ,  C08F18/20

CPC classification number: C07C31/44 ,  C07C17/361 ,  C07C23/38 ,  C07C29/38 ,  C07C67/14 ,  C07C69/653 ,  C07C2603/74 ,  C08F220/24

Abstract: To provide a novel fluoroadamantane derivative, a novel polymerizable fluoroadamantane derivative and a novel fluoropolymer, and processes for production thereof. To provide the following compound (3), the following compound (4), a polymer obtained by polymerizing the compound (4) and processes for production thereof:

provided that Q represents -CHF- or -CF 2 - (provided that six Qs may be the same or different), Z represents -H, -F or -CH 2 OH (provided that three Zs may be the same or different), W represents -H or a C 1-10 hydrocarbon group, R represents -H, -F, -CH 3 or -CF 3 , and J represents -H, -F, -CHWOH or -CHWOCOCR=CH 2 (provided that three Js may be the same or different).

公开(公告)号：EP1457477B8

公开(公告)日：2007-11-14

申请号：EP02805017.7

申请日：2002-11-20

Applicant: DAIKIN INDUSTRIES, LTD.

Inventor： KATSUBE, Toshiyuki ,  NODA, Kouzou ,  MIKI, Jun

IPC: C07C17/087 ,  C07C19/16 ,  C07C67/11 ,  C07C69/653 ,  B01J27/08 ,  B01J27/053

CPC classification number: C07C17/087 ,  C07C17/08 ,  C07C67/11 ,  Y02P20/582 ,  C07C19/16 ,  C07C69/653

Abstract: A fluoroalkene is reacted with hydrogen iodide gas in the presence of a catalyst to produce a fluoroalkyl iodide represented by the general formula (II): Rf-CH2CH2I (II) wherein Rf represents C1-20 perfluoroalkyl or polyfluoroalkyl. The fluoroalkyl iodide is reacted with a carboxylic acid salt to produce a fluorinated ester.