Abstract:
The present invention has its object to provide a curable composition which comprises a guanidine compound as a non-organotin type catalyst, is less discolored, has good surface curability, depth curability, strength rise and adhesiveness, and can retain the curability even after storage; the above object can be achieved by a curable composition which comprises: (A) an organic polymer containing a silyl group capable of crosslinking under siloxane bond formation, the silyl group being a group represented by the general formula (1): -SiX 3 (1) (wherein X represents a hydroxyl group or a hydrolyzable group and the three X groups may be mutually the same or different), (B) a guanidine compound (B-1) as a silanol condensation catalyst, and (C) a plasticizer, wherein the content of the component (B-1) is not lower than 0.1 part by weight but lower than 8 parts by weight per 100 parts by weight of the component (A), and a non-phthalate ester plasticizer accounts for 80 to 100% by weight of the (C) component plasticizer.
Abstract:
A curable film-forming coating composition, typically a clearcoat, having improved compatibility over waterborne and solventborne basecoats. The composition includes a film-forming binder comprising a carbamate material, a curing agent, typically a monomeric melamine curing agent, and a hydroxy functional silane component. When used as a clearcoat over a standard pigmented basecoat, the resulting coating provides a substantially wrinkle free appearance and excellent adhesion to both waterborne and solventborne basecoats.
Abstract:
The present invention has its object to provide a curable composition which comprises a reactive silyl group-containing organic polymer, does not contain, as a silanol condensation catalyst, any organotin type curing catalyst currently of concern because of the toxic feature thereof, is excellent in surface curability and depth curability and, further, can provide cured products excellent in adhesiveness; the above obj ect can be achieved by a curable composition which comprises: an organic polymer (A) containing a silicon-containing group capable of crosslinking under siloxane bond formation; and a guanidine compound (B-1), as a silanol condensation catalyst (B), represented by the general formula (1):
R 1 N=C(NR 1 2 ) 2 (1)
(wherein one of the five R 1 s is an aryl group and the other four R 1 s each independently is a hydrogen atom or a hydrocarbon group in which the carbon atom at position 1 is saturated).
Abstract:
A hydrophilic member includes, in the following order: a substrate; an undercoat layer; and a hydrophilic layer formed by heating a hydrophilic composition containing a hydrophilic polymer having a structural unit represented by the formula (I-a) defined herein and a structural unit represented by the formula (I-b) defined herein, and a non-volatile catalyst.
Abstract:
The present invention has its object to provide a curable composition which allows slight bleedout of a liquid compound to occur to the cured product and shows good curability and adhesiveness using a non-organotin catalyst, an amine compound, as a silanol condensation catalyst. The present invention relates to a non-organotin-based curable composition which comprises: (A) an organic polymer having a silicon-containing group capable of crosslinking by siloxane bond formation, and (B) a specific amidine compound and/or a guanidine compound having a melting point of not lower than 23°C, as a silanol condensation catalyst.
Abstract:
Coatings are formed by applying to article a copolymer of a water soluble base polymer having graft polymerized thereto an organic moiety that includes a group that reacts with water to form a silanol group, and then curing the copolymer to form a crosslinked hydrogel coating that is absorbent, lubricious and substantially non-water soluble. Coating compositions, coated articles the subject coatings are also described.
Abstract:
The invention relates to a multicomponent, isocyanate-terminated or silane-functionalized coating and adhesive material that is continuously produced by mixing the individual components and by heating the latter and continuing mixing until said components reach a liquid state, wherein the resulting reactive coating and adhesive material is fed for direct use especially in profile sheathing plants, coating plants or the like. In the case of the isocyanate-terminated material, one component has a reactive high-molecular weight starting polymer and a second component has a reactive isocyanate-terminated cross-linking agent. In the case of the silane-functionalized material, one component has a high-molecular weight starting polymer and a second component has a reactive, silane-functionalized cross-linking agent.
Abstract:
A coating composition excellent in storage stability, excellent in coating appearance, adhesion and weather resistance, high in hardness, having ultraviolet absorbing ability, and capable of preventing deterioration of a ground or a substrate, which comprises (A) a polymer containing (a1) a silyl group having a silicon atom bound to a hydrolytic group and/or a hydroxyl group, (a2) a group having ultraviolet absorbing ability and (a3) a group having ultraviolet stability in the same polymer chain, and further optionally comprises (B) at least one component selected from the group consisting of an organosilane represented by (R 1 ) n Si (OR 2 ) 4-n , a hydrolyzate of the organosilane and a condensate of the organosilane; and a cured product thereof.