Abstract:
A process for separating emulsions of alkanesulfonyl chloride in aqueous hydrochloric acid comprises passing the emulsion through a carbon bed, a graphite bed, a layer of alkanesulfonyl chloride or a combination thereof; and allowing the emulsion to enter a settling vessel.
Abstract:
A fluorosulfonyl group-containing polymer having units represented by the following formula u1, a sulfonic acid group-containing polymer having fluorosulfonyl groups in the fluorosulfonyl group-containing polymer converted into sulfonic acid groups, its production method and its applications:
wherein R F1 and R F2 are a C 1-3 perfluoroalkylene group.
Abstract:
The preparation of a compound of formula (I) comprising an -SO 2 F function by reacting a compound of formula (II) with a fluorinating agent chosen from hydrofluoric acid and an ionic fluoride of a monovalent or divalent cation is described: R-SO 2 F (I) R'-SO 2 X (II) where R is chosen from the groups R1, R2 and R3: R1 = -C n H a F b with n=1-10, a+b = 2n+1, b ≥ 1; R2 = -C x H y F z -SO 2 F with x = 1-10, y+z = 2x and z ≥ 1; R3 = Φ-C c H h F f with c = 1-10; h+f = 2c and f ≥ 1; where R' is chosen from the following groups R'1, R'2 and R'3: R'1 = -C n H a X b with n=1-10, a+b = 2n+1, b ≥ 1; R'2 = -C x H y X z -SO 2 X with x = 1-10, y+z = 2x and z ≥ 1; R'3 = Φ-C c H h X f with c = 1 -10; h+f = 2c and f ≥ 1; Φ denoting a phenyl group, X = Cl, Br.
Abstract translation:描述了通过使式(II)化合物与选自氢氟酸和一价或二价阳离子的离子氟化物的氟化剂反应制备包含-SO 2 F官能团的式(I)化合物:R-SO 2 F(I )R'-SO2X(II)其中R选自R1,R2和R3组:R1 = -CnHaFb,n = 1-10,a + b = 2n + 1,b≥1; R2 = -CxHyFz-SO2F,其中x = 1-10,y + z = 2x和z≥1; R3 =Φ-CcHhFf,其中c = 1-10; h + f = 2c和f≥1; 其中R'选自具有n = 1-10,a + b = 2n + 1,b≥1的以下基团R'1,R'2和R'3:R'1 = -CnHaXb; 其中x = 1-10,y + z = 2x和z≥1的R'2 = -CxHyXz-SO2X; R'3 =Φ-CcHhXf,其中c = 1-10; h + f = 2c和f≥1; Φ表示苯基,X = Cl,Br。
Abstract:
Higher-alkane sulfonyl halides are prepared by contacting a sulfur-containing compound, a halogen-containing compound, and a phase transfer agent within a reaction zone under reaction conditions.
Abstract:
Pour fabriquer un chlorure d'alcanesulfonyle par réaction photochimique d'un alcane avec du chlore et du dioxyde de soufre, on utilise comme source lumineuse une lampe au mercure moyenne pression dopée au gallium.