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    Process for preparing Hypofluorites and bis-hypofluorites
    1.
    发明公开
    Process for preparing Hypofluorites and bis-hypofluorites 失效
    制备次氟酸盐和双次氟酸盐的方法

    公开(公告)号：EP0259817A2

    公开(公告)日：1988-03-16

    申请号：EP87113058.9

    申请日：1987-09-07

    申请人： AUSIMONT S.p.A.

    发明人： Marraccini, Antonio, Dr. ,  Guglielmo, Giorgio, Dr. ,  Malacrida, Alessandro, Dr. ,  Roberti, Lamberto

    IPC分类号： C07C71/00 ,  C07C309/80 ,  B01J27/12

    CPC分类号： C07C71/00 ,  C07C309/00

    摘要： Mono- and bis-hypofluorites respectively of formula: FO₂S-R f -CF₂OF and FOCF₂-Rʹ f -CF₂OF wherein R f is perfluoroalkylene or perfluorochloroalkylene and Rʹ f is perfluoroalkylene or perfluorooxyalkylene are prepared by a process which is conducted continuously, at a temperature from 0 to 60°C and comprises starting from the respective acyl fluorides
    by reaction of fluorine in the gas phase in the presence of a catalyst consisting of K, Rb, Cs or Ba fluorine, preferably supported on a metal material.

    摘要翻译： 分别为式FO 2 S-R f-CF 2 OF和FOCF 2 -R f-CF 2 OF的单 - 和双 - 次氟酸，其中R f为全氟亚烷基或全氟亚氯代亚烷基，R'f为全氟亚烷基或全氟氧亚烷基通过连续进行的方法制备， 包括从各自的酰基氟化物开始，通过氟在气相中在由K，Rb，Cs或Ba氟组成的催化剂存在下反应，所述催化剂优选负载在金属材料上。

    Process for the preparation of fluoroxy halo compounds
    2.
    发明公开
    Process for the preparation of fluoroxy halo compounds 失效
    制备氟氧卤代化合物的方法

    公开(公告)号：EP0194862A2

    公开(公告)日：1986-09-17

    申请号：EP86301748.9

    申请日：1986-03-11

    申请人： AUSIMONT S.p.A.

    发明人： Guglielmo, Giorgio ,  Conte, Lino ,  Carlini, Filippo Maria

    IPC分类号： C07C71/00

    CPC分类号： C07C71/00

    摘要： Fluoroxy-halo-compounds are prepared by direct reaction between fluorine and organic compounds having a molecular structure in which at least one oxygen atom is directly bound to a carbon atom in the carbonylic form, in the presence of a fluorination catalyst, in a gaseous phase, at an absolute pressure of between 50 and 800 kPa and at a temperature higher than -50°C and up to 250°C, under conditions of continuous feeding of the reactants and a continuous removal of the reaction product.

    摘要翻译： 氟氧卤代化合物通过氟和具有分子结构的有机化合物直接反应来制备，所述分子结构中至少一个氧原子直接与碳原子形式的碳原子在氟化催化剂存在下以气相 在绝对压力为50-800kPa之间，温度高于-50℃且高达250℃的条件下，在连续加入反应物和连续除去反应产物的条件下进行。

    Process for the preparation of fluoroxy halo compounds
    5.
    发明公开
    Process for the preparation of fluoroxy halo compounds 失效
    制备氟氧化合物的方法

    公开(公告)号：EP0194862A3

    公开(公告)日：1989-01-11

    申请号：EP86301748.9

    申请日：1986-03-11

    申请人： AUSIMONT S.p.A.

    发明人： Guglielmo, Giorgio ,  Conte, Lino ,  Carlini, Filippo Maria

    IPC分类号： C07C71/00

    CPC分类号： C07C71/00

    摘要： Fluoroxy-halo-compounds are prepared by direct reaction between fluorine and organic compounds having a molecular structure in which at least one oxygen atom is directly bound to a carbon atom in the carbonylic form, in the presence of a fluorination catalyst, in a gaseous phase, at an absolute pressure of between 50 and 800 kPa and at a temperature higher than -50°C and up to 250°C, under conditions of continuous feeding of the reactants and a continuous removal of the reaction product.

    Process for the preparation of bromofluoroethylhypofluorite
    7.
    发明公开
    Process for the preparation of bromofluoroethylhypofluorite 失效
    溴氟乙基次氟酸的制备方法

    公开(公告)号：EP0263309A2

    公开(公告)日：1988-04-13

    申请号：EP87113057.1

    申请日：1987-09-07

    申请人： AUSIMONT S.p.A.

    发明人： Gregorio, Guglielmo, Dr. ,  Calini, Pierangelo ,  Guglielmo, Giorgio, Dr.

    IPC分类号： C07C71/00 ,  B01J27/12

    CPC分类号： C07C71/00 ,  B01J23/78 ,  B01J27/12

    摘要： The new compound bromofluoroethylhypofluorite, having the formula CF₂BrCF₂OF is obtained by starting from
    by the reaction in gaseous phase with fluorine, in the presence of a catalyst constituted by CsF on a support constituted by copper (or by another metal) in the form of a porous material having a surface area of at least 0.1m²/g.

    摘要翻译： 具有式CF 2 BrCF 2 OF的新型化合物溴氟乙基次氟酸是通过以下方式获得的：在由在由多孔形式的铜（或另一种金属）构成的载体上由CsF构成的催化剂存在下，通过气相与氟的反应 材料具有至少0.1m 2 / g的表面积。

    PROCESS FOR PREPARING FLUOROBENZENE AND BENZOIC ACID HYPOFLUORITE
    9.
    发明公开
    PROCESS FOR PREPARING FLUOROBENZENE AND BENZOIC ACID HYPOFLUORITE 审中-公开

    公开(公告)号：EP3786142A1

    公开(公告)日：2021-03-03

    申请号：EP20165422.5

    申请日：2020-03-24

    申请人： Fujian Yongjing Technology Co., Ltd.

    发明人： CUI, Weilong ,  ZHOU, Changyue ,  DU, Hongjun ,  WU, Wenting

    IPC分类号： C07C17/363 ,  C07C25/13 ,  C07C71/00

    摘要： The invention relates to a use of a fluorination gas, wherein the elemental fluorine (F 2 ) is preferably present in a high concentration, for example, in a concentration of elemental fluorine (F 2 ), especially of equal to much higher than 15 % or even 20 % by volume (i.e., at least 15 % or even 20 % by volume), and to a process for the manufacture of a fluorinated benzene starting from benzoic acid by direct fluorination employing a fluorination gas, wherein the elemental fluorine (F 2 ) is preferably present in a high concentration, and subsequent decarboxylation of the benzoic acid hypofluorite obtained by direct fluorination. The process of the invention is also directed to the manufacture of a benzoic acid hypofluorite by direct fluorination of benzoic acid. Especially the invention is of interest in the preparation of fluorinatedbenzene, final products and as well intermediates, for usage in agro-, pharma-, electronics-, catalyst, solvent and other functional chemical applications. The fluorination process of the invention may be performed batch-wise or in a continuous manner. If the process of the invention is performed batch-wise, a column (tower) reactor may be used. If the process of the invention is continuous a micro reactor may be used. The invention is characterized in that the starting compound is benzoic acid, and the fluorinated compound produced is a benzoic acid hypofluorite obtained by direct fluorination, which benzoic acid hypofluorite can be converted by decarboxylation to a fluorinated benzene, preferably monofluorobenzene.