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    VERFAHREN ZUR KONTINUIERLICHEN HERSTELLUNG EINER VERBINDUNG, DIE MINDESTENS ZWEI FUNKTIONELLE GRUPPEN TRÄGT
    21.
    发明公开
    VERFAHREN ZUR KONTINUIERLICHEN HERSTELLUNG EINER VERBINDUNG, DIE MINDESTENS ZWEI FUNKTIONELLE GRUPPEN TRÄGT 有权
    方法链路的连续生产，至少有两个官能团熊

    公开(公告)号：EP1641739A1

    公开(公告)日：2006-04-05

    申请号：EP04739794.8

    申请日：2004-06-11

    申请人： BASF Aktiengesellschaft

    发明人： STÜER, Wolfram ,  SCHEIDEL, Jens ,  VOSS, Hartwig ,  BASSLER, Peter ,  RÖPER, Michael

    IPC分类号： C07C67/347 ,  C07C69/593 ,  C07C67/56 ,  C07C67/303 ,  C07C51/353

    CPC分类号： C07C51/36 ,  C07C51/353 ,  C07C51/47 ,  C07C67/303 ,  C07C67/347 ,  C07C67/56 ,  C07C57/13 ,  C07C55/14 ,  C07C69/44 ,  C07C69/593

    摘要： The invention relates to a method for the continuous production of a compound that carries at least two functional groups, independently selected from the group consisting of nitrile group, carboxylic acid group, carbonic ester group, carbonic amide group. The inventive method comprises the following steps: a) adding two terminal olefins that carry the functional groups required for the production of the compound according to a1) carrying at least two functional groups, in the presence of a compound according to a3) that is suitable as a catalyst for said addition and that is homogenous with respect to the reaction mixture, thereby obtaining a mixture that contains a1) a compound obtained by simple addition of the two above-mentioned terminal olefins that carry at least two functional groups, independently selected from the group consisting of nitrile group, carboxylic acid group, carbonic ester group, carbonic amide group, a2) a compound obtained by multiple addition of the above-mentioned two terminal olefins, and a3) the compound that is suitable as a catalyst for said addition and that is homogenous with respect to the reaction mixture, b) distilling the mixture obtained in step a) while obtaining b1) the compound obtained by simple addition of the two above-mentioned terminal olefins that carry at least two functional groups, independently selected from the group consisting of nitrile group, carboxylic acid group, carbonic ester group, carbonic amide group, as the overhead product, and b2) a mixture containing b2a) a compound obtained by simple addition of the two above-mentioned terminal olefins that carry at least two functional groups, independently selected from the group consisting of nitrile group, carboxylic acid group, carbonic ester group, carbonic amide group, b2b) a compound obtained by multiple addition of the above-mentioned two terminal olefins, and b2c) the compound that is suitable as a catalyst for said addition and that is homogenous with respect to the reaction mixture, c) separating the entire mixture obtained in step b2) or a part thereof by means of a semipermeable membrane while obtaining a permeate and a retentate in such a manner that the weight ratio of component b2b) to component b2c) of the mixture added in step c) is smaller than in the retentate, d) returning, either partially or completely, to step a) the permeate obtained in step c), and e) returning, either partially or completely, to step a) the part of the mixture obtained in step b2) and not separated according to step c).

    VERFAHREN ZUR HERSTELLUNG VON ALDEHYDEN
    26.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON ALDEHYDEN 有权

    公开(公告)号：EP1047655A1

    公开(公告)日：2000-11-02

    申请号：EP99904776.4

    申请日：1999-01-14

    申请人： BASF AKTIENGESELLSCHAFT

    发明人： GEISSLER, Bernhard ,  RÖPER, Michael ,  ZELLER, Edgar ,  PACIELLO, Rocco ,  DECKER, Jürgen ,  VOSS, Hartwig ,  MAHR, Norbert

    IPC分类号： C07C45/50 ,  C07C29/16 ,  B01J31/20 ,  B01J31/18

    CPC分类号： C08G73/0206 ,  B01J31/1658 ,  B01J31/1805 ,  B01J2231/321 ,  B01J2531/80 ,  B01J2531/822 ,  C07C45/50 ,  Y02P20/584 ,  C07C47/02

    摘要： The invention relates to a method for the production of aldehydes or aldehydes and alcohols by hydroformylation of olefins in the presence of a complexing catalyst homogeneously dissolved in a reaction mixture, containing a metal of Group VIIIa of the periodic table of the elements and a phosphorus-free, polydentate nitrogen compound suitable for complex formation as ligand at temperatures ranging from 50 to 100 °C and pressures from 20 to 1,000 bar and recirculating the catalyst complex in the hydroformylation reaction, wherein a) derivatized polyamines are used that are substantially non-water soluble and suitable for complex formation and have a mean molecular weight of more than 1,000 Dalton and at least 10 nitrogen atoms; b) the catalyst complex remaining in the bottom of the distillation column and the excess ligands obtained from the reaction mixture are recirculated totally or partially in the hydroformylation once the hydroformylation reaction and the separation or partial separation by distillation of the aldehydes and the alcohols has been completed; c) continuos or at least batchwise evacuation of at least part of the high boiler from the bottom of the distillation of the reaction mixture is then carried out.

    摘要翻译： 本发明涉及一种在均匀溶解在反应混合物中的络合催化剂存在下通过烯烃的加氢甲酰化生产醛或醛和醇的方法，该反应混合物含有元素周期表的第VIIIa族金属和磷 - 所述多齿氮化合物适合于在50-100℃和20-1,000巴的压力下将配合物形成配位体并在羰基化反应中再循环所述催化剂配合物，其中a）使用基本上非水的衍生多胺 可溶且适于复合物形成并具有超过1,000道尔顿的平均分子量和至少10个氮原子; b）一旦加氢甲酰化反应和醛和醇的蒸馏分离或部分分离，残留在蒸馏塔底部的催化剂配合物和从反应混合物获得的过量配体在加氢甲酰化中全部或部分再循环 完成; c）然后进行从反应混合物的蒸馏的底部连续或至少分批地排出至少部分高沸点化合物。

    VERFAHREN ZUR HERSTELLUNG VON CHLOR
    28.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON CHLOR 有权

    公开(公告)号：EP1866239A1

    公开(公告)日：2007-12-19

    申请号：EP06743192.4

    申请日：2006-02-20

    申请人： BASF AKTIENGESELLSCHAFT

    发明人： SESING, Martin ,  DIEFENBACHER, Armin ,  VOSS, Hartwig ,  SCHUBERT, Olga ,  SEIDEMANN, Lothar ,  KARCHES, Martin ,  GRASSLER, Thomas ,  STROEFER, Eckhard

    IPC分类号： C01B7/04

    CPC分类号： C01B7/075 ,  C01B7/04 ,  C01B7/0743

    摘要： The invention concerns a method for producing chlorine and a hydrochloric gas including the following steps: a) supplying via a stream containing hydrochloric gas (a1) and a stream containing oxygen (a2) an oxidation zone and a hydrochloric gas catalytic oxidation with chlorine, a stream of gaseous product (a3) containing chlorine, water, oxygen, carbon dioxide, and the inert gases obtained; b) cooling the stream of gaseous products (a3) and separating the water from the hydrochloric gas in the form of hydrochloric acid, a gas stream (b) containing chlorine, water, oxygen, carbon dioxide, and the inert gases still remaining; c) optionally drying the gas stream (b), and obtaining a gas stream (c) substantially water-free, containing chlorine, oxygen, carbon dioxide and inert gases; d) liquefying at least partly the gas stream (c) and a return stream (f1) rich in chlorine, containing chlorine, oxygen, carbon dioxide through thickening and cooling, a partly liquefied stream (d) being preserved; e) gas-liquid separation of the stream (d) into a gas stream (e1) containing chlorine, oxygen, carbon dioxide, and inert gases and into a liquid stream (e2) containing chlorine, oxygen, and carbon dioxide; f) introducing at least part of the gas stream (e1) into a unit with membrane and separating a return stream (f1) rich in chlorine and a gas flow (f2) poor in chlorine, containing chlorine, oxygen, carbon dioxide, via a separation by the membrane and reintroducing the return flux (f1) rich in chlorine in step d); g) separating the liquid stream (e2) by distillation into a stream of chlorine (g1) and a stream (g2) comprising substantially oxygen and carbon dioxide.

    摘要翻译： 本发明涉及一种生产氯气和盐酸气体的方法，包括以下步骤：a）通过含有盐酸气体（a1）和含氧气流体（a2），氧化区域和盐酸气体催化氧化的气流与氯气， 含有氯气，水，氧气，二氧化碳和惰性气体的气体产物（a3）的气流; b）冷却气态产物流（a3）并从盐酸形式的盐酸中分离出水，含有氯气，水，氧气，二氧化碳和剩余的惰性气体的气流（b）; c）任选地干燥气流（b），并获得基本上无水的含有氯气，氧气，二氧化碳和惰性气体的气流（c）; d）通过增稠和冷却至少部分地液化气体物流（c）和富含氯的返回物流（f1），部分液化物流（d）被保留; e）将气流（d）气 - 液分离成含有氯气，氧气，二氧化碳和惰性气体的气流（e1）并进入含有氯气，氧气和二氧化碳的液体流（e2）中; f）将至少一部分气流（e1）引入具有膜的单元中，并通过一个分离器将富含氯的返回流（f1）和贫含氯的气流（f2）分离，所述氯气包含氯气，氧气，二氧化碳 在步骤d）中通过膜分离并重新引入富含氯的返回通量（f1）; g）通过蒸馏将液体流（e2）分离成氯气流（g1）和基本上包含氧气和二氧化碳的气流（g2）。