VERFAHREN ZUR HERSTELLUNG EINES N-UNSUBSTITUIERTEN ODER N-SUBSTITUIERTEN AZIRIDINS
    26.
    发明公开
    VERFAHREN ZUR HERSTELLUNG EINES N-UNSUBSTITUIERTEN ODER N-SUBSTITUIERTEN AZIRIDINS 审中-公开
    法生产N-未取代或取代的N-取代氮丙啶

    公开(公告)号:EP2160379A1

    公开(公告)日:2010-03-10

    申请号:EP08761156.2

    申请日:2008-06-18

    Applicant: BASF SE

    CPC classification number: C07D203/08 C07D203/02

    Abstract: The invention relates to a method for synthesizing an N-unsubstituted or N-substituted aziridine of the formula (III), wherein an olefin of the formula (I), in which R1 to R5 independently of one another represent hydrogen, linear or branched alkyl groups with 1 to 16 carbon atoms, hydroxy alkyl groups with 1 to 4 carbon atoms, cycloalkyl groups with 5 to 7 carbon atoms, benzyl groups, and phenyl groups, which can be substituted in the o, m, or p position of the phenyl group by methoxy, hydroxy, chloro or alkyl groups with 1 to 4 carbon atoms, and the R1 and R2 groups, together with the R3 and R4 groups, can be a closed 5-membered to 12-membered ring, is reacted with ammonia or a primary amine of the formula R5NH2 in the presence of iodine or bromine.

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