摘要:
An article (10) comprising a substrate (12) formed of a silicon-comprising material, such as an article (10) exposed to the hostile thermal environment of a gas turbine engine. The article (10) further comprises an environmental barrier layer (16), e.g., an alkaline earth metal aluminosilicate, and a top coat (18) comprising zirconia or hafnia stabilized with an oxide of a metal selected from the group consisting of magnesium, calcium, scandium, yttrium, and lanthanide metals, and mixtures thereof. The article (10) further comprises a transition layer (20) between the environmental barrier layer (16) and the top coat (18), the transition layer (20) comprising zirconia or hafnia stabilized with an oxide of a metal selected from the group consisting of magnesium, calcium, scandium, yttrium, and lanthanide metals; and a low CTE oxide selected from the group consisting of niobia and tantala; and mixtures thereof. A method for preparing a thermal/environmental barrier coating system (14)
摘要:
A coating system (20) for an article (10) comprising a substrate (22) formed of a metal alloy that is prone to the formation of a deleterious secondary reaction zone (SRZ) as a result of containing more than three weight percent rhenium and at least one additional refractory metal. The coating system (20) comprises an aluminum-containing overlay coating (24) and a diffusion barrier coating (32) between the overlay coating (24) and the substrate (22). The diffusion barrier coating (32) consists of, in atomic percent, about 20% to about 90% ruthenium, about 2% to about 60% chromium, optionally up to about 50% aluminum, optionally up to about 20% of a platinum-group metal, and the balance at least one of nickel, cobalt, and iron and incidental impurities. The diffusion barrier coating (32) sufficiently inhibits diffusion of aluminum from the overlay coating (24) into the substrate (22), such that the substrate (22) remains essentially free of SRZ.
摘要:
An article (10) comprising a substrate (12) formed of a silicon-comprising material, such as an article (10) exposed to the hostile thermal environment of a gas turbine engine. The article (10) further comprises an environmental barrier layer (16), e.g., an alkaline earth metal aluminosilicate, and a physical barrier layer (20) overlying the environmental barrier layer (16). The physical barrier layer (20) comprises zirconia or hafnia stabilized with an oxide of a metal selected from the group consisting of magnesium, calcium, scandium, yttrium, and lanthanide metals; and a low CTE oxide selected from the group consisting of niobia and tantala; and mixtures thereof. A method for preparing an environmental barrier coating system (14) on a substrate (12) formed of a silicon-comprising material is also disclosed.
摘要:
An article (10) comprising a substrate (12) formed of a silicon-comprising material, such as an article (10) exposed to the hostile thermal environment of a gas turbine engine. The article (10) further comprises an environmental barrier layer (16), e.g., an alkaline earth metal aluminosilicate, and a top coat (18) comprising zirconia or hafnia stabilized with an oxide of a metal selected from the group consisting of magnesium, calcium, scandium, yttrium, and lanthanide metals, and mixtures thereof. The article (10) further comprises a transition layer (20) between the environmental barrier layer (16) and the top coat (18), the transition layer (20) comprising zirconia or hafnia stabilized with an oxide of a metal selected from the group consisting of magnesium, calcium, scandium, yttrium, and lanthanide metals; and a low CTE oxide selected from the group consisting of niobia and tantala; and mixtures thereof. A method for preparing a thermal/environmental barrier coating system (14)
摘要:
In accordance with an embodiment of the invention, an article is provided. The article comprises a substrate (16) comprised of silicon containing material, an environmental barrier coating (EBC) (12) overlying the substrate (16) and a thermal barrier coating (TBC) (14) on the environmental barrier coating (12). The thermal barrier coating (14) comprising a compound having a rhombohedral phase.