Method of manufacturing chemically adsorbed film
    21.
    发明公开
    Method of manufacturing chemically adsorbed film 失效
    Verfahren zur Herstellung einer chemisch adsorptionbierten Schicht。

    公开(公告)号:EP0492417A2

    公开(公告)日:1992-07-01

    申请号:EP91121741.2

    申请日:1991-12-18

    摘要: According to the invention, a chemically adsorbing material (1) is reacted with a substrate (4) surface having active hydrogen groups by dipping the substrate (4) into a solution (2) of the chemically adsorbing material (1) simultaneous and applying ultrasonic waves to the solution (2) by an ultrasonic washer (3). In this way, a high concentration monomolecular and/or polymer film (5) substantially free from pin holes can be formed in a short period of time. That is, while the ultrasonic waves are applied, a chemical adsorbing material (1) having an end functional chlorosilyl group is adsorbed onto the substrate surface (4), thereby forming a chemically adsorbed monomolecular and/or polymer film (5). The frequency of the ultrasonic waves are suitably in a range of 25 to 50 kHz. In addition, after formation of the adsorbed film (5), the substrate (4) is washed for making monomolecular film by dipping it in a washing solution while applying ultrasonic waves. In this way, non-reacted chemical adsorbing material (1) remaining on the substrate (4) can be efficiently washed away.

    摘要翻译: 根据本发明,化学吸附材料与具有活性氢基团的基材表面反应,通过将基材浸入化学吸附材料的溶液中同时施加超声波至溶液。 以这种方式,可以在短时间内形成基本上没有针孔的高浓度单分子和/或聚合物膜。 也就是说,当施加超声波时,具有末端官能化氯甲硅烷基的化学吸附材料被吸附到基材表面上,从而形成化学吸附的单分子和/或聚合物膜。 超声波的频率适当地在25〜50kHz的范围内。 此外,在形成吸附膜之后,通过在施加超声波的同时将基板浸渍在洗涤溶液中来洗涤基板以制备单分子膜。 以这种方式,残留在基板上的未反应的化学吸附材料可以被有效地洗去。

    FLUORINE-CONTAINING ETHER COMPOSITION, METHOD FOR PRODUCING SAME, COATING LIQUID, BASE MATERIAL HAVING SURFACE TREATMENT LAYER, AND METHOD FOR PRODUCING SAME
    28.
    发明公开
    FLUORINE-CONTAINING ETHER COMPOSITION, METHOD FOR PRODUCING SAME, COATING LIQUID, BASE MATERIAL HAVING SURFACE TREATMENT LAYER, AND METHOD FOR PRODUCING SAME 审中-公开
    FLUORHALTIGE ETHERZUSAMMENSETZUNG,VERFAHREN ZUR HERSTELLUNG DAVON,BESCHICHTUNGSFLÜSSIGKEIT,BASISMATERIALIAL MIT EINEROBERFLÄCHENBEHANDLUNGSSCHICHTUND VERFAHREN ZUR HERSTELLUNG DAVON

    公开(公告)号:EP3081597A4

    公开(公告)日:2017-06-28

    申请号:EP14869646

    申请日:2014-12-10

    摘要: To provide a fluorinated ether composition useful for surface treatment to impart water/oil repellency to the surface of a substrate, a method for producing the fluorinated ether composition, and a coating liquid containing the fluorinated ether composition, as well as a substrate having a surface-treated layer, and a method for producing the same. Said composition comprises at least two fluorinated ether compounds which are represented by A-O-Q-(C b F 2b O) d -X-O-B 10 and which are different in B 10 . X is a divalent organic group having no CF 2 O. B 10 is -CH 2 CH 2 CH 2 SiL m R n , -CH 2 CH(SiL m R n )CH 3 , -CH 2 CH=CH 2 or -CH=CHCH 3 . A is a perfluoroalkyl group or group B 10 . Of the total of group B 10 in said composition, the proportion of -CH 2 CH 2 CH 2 SiL m R n is from 90 to 99 mol%, and the proportion of -CH=CHCH 3 is from 1 to 10 mol%. L is a hydrolyzable group, and R is a monovalent hydrocarbon group. b is an integer of from 1 to 10, and d is an integer of from 1 to 200.

    摘要翻译: 为了提供可用于表面处理以赋予基材表面防水/防油性的含氟醚组合物,含氟醚组合物的制备方法以及含有该含氟醚组合物的涂布液,以及具有表面的基材 处理层及其制造方法。 所述组合物包含至少两种由A-O-Q-(C b F 2b O)d -X-O-B 10表示并且在B 10中不同的氟化醚化合物。 X为不具有CF 2 O的二价有机基团.B 10为-CH 2 CH 2 CH 2 SiL m R n,-CH 2 CH(SiL m R n)CH 3,-CH 2 CH = CH 2或-CH = CHCH 3。 A是全氟烷基或B 10。 上述组合物中的B 10组的总量中,-CH 2 CH 2 CH 2 SiL m R n的比例为90〜99摩尔%,-CH = CHCH 3的比例为1〜10摩尔%。 L是可水解基团,R是一价烃基。 b为1〜10的整数,d为1〜200的整数。