公开(公告)号：EP2524004A2

公开(公告)日：2012-11-21

申请号：EP11700056.2

申请日：2011-01-06

Applicant: BASF SE

Inventor： FÜßL, Andreas ,  SAMPATH, Bangaru ,  HOFMANN, Maximilian ,  BELLIN, Ingo ,  NALAWADE, Sameer ,  HAHN, Klaus ,  KÜNKEL, Andreas ,  LOOS, Robert

IPC: C08L67/04 ,  C08J9/16

CPC classification number: C08J9/127 ,  C08J9/0061 ,  C08J9/16 ,  C08J9/18 ,  C08J2333/14 ,  C08J2367/02 ,  C08J2367/04 ,  C08J2463/00 ,  C08J2467/02 ,  C08L33/068 ,  C08L67/02 ,  C08L67/04 ,  C08L2666/02

Abstract: Producing expandable polylactic acid-containing granules, comprises: (a) melting and mixing (i) polylactic acid, (ii) at least one additional polymer, (iii) a diepoxide or polyepoxide and (iv) at least one additive, preferably nucleating agent; (b) mixing (v) an organic blowing agent and (vi) a co-blowing agent including nitrogen, carbon dioxide, argon and/or helium, into the polymer melt via a static or dynamic mixer; (c) discharging the mixture via a nozzle plate with holes; and (d) granulating the blowing agent-containing melt directly behind the nozzle plate under water. Producing expandable polylactic acid-containing granules, comprises: (a) melting and mixing (i) polylactic acid (50-99.9 wt.%, based on the total weight of the components (i)-(iii)), (ii) at least one additional polymer (0-49.9 wt.%, based on the total weight of the components (i)-(iii)), (iii) a diepoxide or polyepoxide (0.1-2 wt.%, based on the total weight of the components (i)-(iii)) and (iv) at least one additive, preferably nucleating agent (0-10 wt.%, based on the total weight of the components (i)-(iii)); (b) mixing (v) an organic blowing agent (3-7 wt.%, preferably 1-7 wt.%, based on the total weight of the components (i)-(iv)) and (vi) a co-blowing agent including nitrogen, carbon dioxide, argon and/or helium (0.01-5 wt.%), into the polymer melt via a static or dynamic mixer at a temperature of at least 140[deg] C; (c) discharging the mixture via a nozzle plate with holes, whose diameter at the nozzle outlet is not > 1.5 mm; and (d) granulating the blowing agent-containing melt directly behind the nozzle plate under water at a pressure of 1-20 bar. Independent claims are also included for: (1) the expandable polylactic acid-containing granules with cavities with an average diameter of 0.1-50 mu m and a solid proportion of 93-97 wt.% obtained by the above method, comprising (in wt.%) (i) the polylactic acid (50-98.9, based on the total weight of components (i)-(iii)), (ii) at least one polyester based on aliphatic and aromatic dicarboxylic acids and aliphatic dihydroxy compounds (1-49.9, based on the total weight of components (i)-(iii)), (iii) an epoxide group-containing copolymer based on styrene, acrylic acid ester and/or methacrylic acid ester (0.1-2, based on the total weight of components (i)-(iii)), (iv) the additive (0-10, based on the total weight of components (i)-(iii)), and (v) the organic blowing agent (3-7), or a polylactic acid-containing polymer mixture; (2) producing particles of foam molded parts, comprising pre-foaming the expandable polylactic acid-containing granules with hot air or steam to form the foam particles with a density of 8-100 kg/m 3>, and then welding the foam particles in a closed mold; (3) the polylactic acid-containing polymer mixture comprising (in wt.%) (i) the polylactic acid (60-98.9, based on the total weight of components (i)-(iii)), (ii) at least one polyester (1-39.9, based on the total weight of components (i)-(iii)), based on (a) succinic acid (90-99.5 mol.%, based on the components (i)-(ii)), (b) at least one dicarboxylic acids with 8-20 carbon atoms (0.5-10 mol.%, based on the components (i)-(ii)), (c) 1,3-propanediol or 1,4-butanediol (98-102 mol.%, based on the components (i)-(ii)), (iii) the epoxide group-containing copolymer (0.1-2, based on the total weight of the components (i)-(iii)), and (iv) the nucleating agent (0-1, based on the total weight of components (i)-(iii)); and (4) foam materials comprising the polylactic acid-containing polymer mixture.

Abstract translation: （a）熔化并混合（i）聚乳酸，（ii）至少一种另外的聚合物，（iii）二环氧化物或聚环氧化物和（iv）至少一种添加剂，优选成核剂 ; （b）通过静态或动态混合器将（v）有机发泡剂和（vi）包含氮气，二氧化碳，氩气和/或氦气的共发泡剂混入聚合物熔体中; （c）通过具有孔的喷嘴板排出混合物; 和（d）在水下直接在喷嘴板后面将含发泡剂的熔体造粒。 （a）熔融和混合（i）聚乳酸（基于组分（i） - （iii）的总重量为50-99.9重量％），（ii）在 至少一种另外的聚合物（基于组分（i） - （iii））的总重量为0-49.9重量％），（iii）二环氧化物或聚环氧化物（0.1-2重量％，基于 （i） - （iii））和（iv）至少一种添加剂，优选成核剂（基于组分（i） - （iii）的总重量为0-10重量％）; （b）将（v）有机发泡剂（3-7重量％，优选1-7重量％，基于组分（i） - （iv）的总重量）和（vi） 包括氮气，二氧化碳，氩气和/或氦气（0.01-5重量％）的发泡剂通过静态或动态混合器在至少140℃的温度下进入聚合物熔体; （c）经由具有孔的喷嘴板排出混合物，所述孔的直径在喷嘴出口不大于1.5mm; （d）在1-20巴的压力下，在水下将含发泡剂的熔体直接造粒在喷嘴板后面。 独立权利要求还包括：（1）通过上述方法获得的具有平均直径为0.1-50μm，固体比例为93-97重量％的具有空腔的可膨胀聚乳酸颗粒，其包含（wt （i） - （i）聚乳酸（50-98.9，基于组分（i） - （iii）的总重量），（ii）至少一种基于脂族和芳族二羧酸和脂族二羟基化合物的聚酯（1） （iii）基于苯乙烯，丙烯酸酯和/或甲基丙烯酸酯的含环氧基团的共聚物（0.1-2，基于组分（i） - （iii）的总重量） （iv）添加剂（0-10，基于组分（i） - （iii）的总重量）和（v）有机发泡剂（3-7 ）或含聚乳酸的聚合物混合物; （2）生产泡沫成型部件的颗粒，包括用热空气或蒸汽预发泡含有可发性聚乳酸的颗粒以形成密度为8-100kg / m 3的泡沫颗粒，然后将泡沫颗粒 在封闭的模具中; （3）包含（以重量％计）（i）聚乳酸（60-98.9，基于组分（i） - （iii）的总重量）的含聚乳酸的聚合物混合物，（ii）至少一种 基于（a）基于组分（i） - （ii）的琥珀酸（90-99.5摩尔％））的聚酯（1-39.9，基于组分（i） - （iii）的总重量） （b）至少一种具有8-20个碳原子的二羧酸（基于组分（i） - （ii）的0.5-10摩尔％），（c）1,3-丙二醇或1,4-丁二醇（ 基于组分（i） - （ii）），（iii）含环氧基团的共聚物（0.1-2，基于组分（i） - （iii）的总重量计）为98-102摩尔％ ，和（iv）成核剂（0-1，基于组分（i） - （iii）的总重量）; 和（4）包含含聚乳酸的聚合物混合物的泡沫材料。

公开(公告)号：EP2513251A1

公开(公告)日：2012-10-24

申请号：EP10790979.8

申请日：2010-12-15

Applicant: BASF SE

Inventor： FLECKENSTEIN, Christoph ,  DENECKE, Hartmut ,  BELLIN, Ingo ,  KRIHA, Olaf ,  SPIES, Patrick ,  FUCHS, Sabine ,  MASSONNE, Klemens ,  HAHN, Klaus ,  DEGLMANN, Peter ,  HOFMANN, Maximilian ,  KINDLER, Alois

IPC: C09K21/12 ,  C08J9/00 ,  C08K5/53

CPC classification number: C09K21/12 ,  C08J9/0038 ,  C08J9/14 ,  C08J9/20 ,  C08J2325/04 ,  C08K5/49 ,  C08K5/523 ,  C08K5/53 ,  C08K5/5313 ,  C08K5/5377 ,  C08K5/5398 ,  C08L2201/02 ,  C08L2203/14 ,  C08L25/00 ,  C08L25/06

Abstract: The invention relates to the use of a phosphorous compound of formula (I) as a flame retardant, wherein the symbols of formula (I) have the following meanings: a group Y is -P(=X
2 )
S R
3 R
4 , H, a straight-chain or branched C
1 -C
12 alkyl group
, C
5 -C
6 cycloalkyl
, C
6 -C
12 aryl, benzyl, wherein the four last cited groups are unsubstituted or substituted by one or more radicals from the group
C
1 -C
4 alkyl
or
C
2 -C
4 alkenylene; R
1 , R
2 , R
3 and R
4 are the same or different hydrogen, OH, C
1 -C
16 -Alkyl, C
2 - C
16 -Alkenyl, C
1 -C
16 -Alkoxy, C
2 -C
16 -Alkenoxy, C
3 -C
10 -Cycloalkyl, C
3 -C
10 -Cycloalkoxy, C
6 -C
10 -Aryl, C
6 -C
10 -Aryloxy, C
6 -C
10 -Aryl-C
1 - C
16 -Alkyl, C
6 -C
10 -Aryl-C
1 -C
16 -Alkoxy, SR
9 COR
10 , COOR
11 , CONR
12 R
13 or two radicals R
1 , R
2 , R
3 , R
4 form a ring system together with the phosphorous atom to which they are bound or the group P-O-A-O-P; R
5 , R
6 , R
7 , and R
8 are the same or different H, C
1 -C
16 -Alkyl, C
2 -C
16 -Alkenyl, C
1 -C
16 -Alkoxy, C
2 -C
16 -Alkenoxy; R
9 , R
10 , R
11 , R
12 , and R
13 are the same or different H d-de-Alkyl, C
2 -C
16 - Alkenyl, C
6 -C
10 -Aryl, C
6 -C
10 -Aryl-C
1 -C
16 -Alkyl,, C
6 -C
10 - Aryl-C
1 -C
16 -Alkoxy; X
1 , and X
2 are the same or different S or O; r, and s are the same or different 0 or 1; and X
3 , X
4 , X
5 , and X
6 are the same or different S or O and n is a whole number from 1 to 50.

Abstract translation: 本发明涉及式（I）的磷化合物作为阻燃剂的用途，其中式（I）的符号具有以下含义：基团Y是-P（= X 2）SR 3 R 4，H， 直链或支链的C 1 -C 12烷基，C 5 -C 6环烷基，C 6 -C 12芳基，苄基，其中最后引用的四个基团是未取代的或被一个或多个选自C 1 -C 4烷基或C 2 -C 4亚烯基; R 1，R 2，R 3和R 4是相同或不同的氢，OH，C 1 -C 16 - 烷基，C 2 -C 16 - 烯基，C 1 -C 16 - 烷氧基，C 2 -C 16 - 烷氧基，C 3 -C 10 - 环烷基，C 3 -C 10 - 环烷氧基，C 6 -C 10 - 芳基，C 6 -C 10 - 芳氧基，C 6 -C 10 - 芳基-C 1 -C 16烷基， C 6 -C 10芳基-C 1 -C 16烷氧基，SR 9 COR 10，COOR 11，CONR 12R 13或两个基团R 1，R 2，R 3，R 4与磷原子一起形成环体系 他们绑定到哪个组或POAOP组; R 5，R 6，R 7和R 8是相同或不同的H，C 1 -C 16 - 烷基，C 2 -C 16 - 烯基，C 1 -C 16 - 烷氧基，C 2 -C 16 - 烯氧基 ; R 9，R 10，R 11，R 12和R 13是相同或不同的H d-去 - 烷基，C 2 -C 16 - 烯基，C 6 -C 10 - 芳基，C 6 -C 10 - 芳基 -C 1 -C 16 - 烷基，C 6 -C 10 - 芳基-C 1 -C 16 - 烷氧基; X 1和X 2是相同或不同的S或O; r和s是相同或不同的0或1; X 3，X 4，X 5和X 6是相同或不同的S或O，并且n是1-50的整数。

公开(公告)号：EP2162269B1

公开(公告)日：2012-08-15

申请号：EP08774315.9

申请日：2008-06-26

Applicant: BASF SE

Inventor： SCHIPS, Carsten ,  HAHN, Klaus ,  BELLIN, Ingo ,  LONGO, Daniela ,  ASSMANN, Jens ,  GIETL, Andreas ,  GASSAN, Jochen

IPC: B29C44/34 ,  C08J9/00 ,  C08J9/16 ,  C08J9/232

CPC classification number: C08J9/232 ,  B29C44/3461 ,  C08J9/0061 ,  C08J2325/16 ,  C08J2425/00 ,  C08J2477/00

Abstract: Moulded foams, obtainable by fusion of prefoamed foam beads made of expandable, thermoplastic polymer pellets, comprising: from 5 to 100% by weight of a component (A) comprising a1) from 5 to 100% by weight (based on (A)) of an α-methylstyrene/acrylonitrile copolymer and/or α-methylstyrene/styrene/acrylonitrile terpolymer and a2) from 0 to 95% by weight (based on (A)) of a styrene/acrylonitrile copolymer; from 0 to 95% by weight of polystyrene (B) and from 0 to 95% by weight of a thermoplastic polymer (C) different from (A) and (B), feature good heat resistance and good solvent resistance.

公开(公告)号：EP2478044A1

公开(公告)日：2012-07-25

申请号：EP10751679.1

申请日：2010-09-10

Applicant: BASF SE

Inventor： HAHN, Klaus ,  KRIHA, Olaf ,  BELLIN, Ingo ,  SPIES, Patrick ,  FUCHS, Sabine ,  DEGLMANN, Peter ,  MASSONNE, Klemens ,  DENECKE, Hartmut ,  FLECKENSTEIN, Christoph ,  JANSSENS, Geert

IPC: C08J9/00 ,  C09K21/04 ,  C08K5/50

CPC classification number: C08J9/0038 ,  C08J9/232 ,  C08J2325/04 ,  C08K5/50 ,  C09K21/12

Abstract: The invention relates to halogen-free, flame-proof polymer foams containing at least one cyclic or alicyclic oligophosphorus compound as the flame proofing agent, and to a method for the production thereof. Suitable oligophosphorus compounds, for example, are those having structures Ia, Ib, or Ic: Another group of suitable oligophosphorus compounds has one of the following structures IIa, IIb, or IIc: Furthermore, cyclic oligophosphorus compounds of the following structure III are suitable: The radicals R
1 -R
5 are independently selected from among the group consisting of C
1 -C
16 -alkyl, C
1 -C
16 -alkenyl, C
1 -C
16 -alkoxy, C
1 -C
16 -alkenyloxy, C
3 -C
10 -cycloalkyl, C
3 -C
10 -cycloalkoxy, C
6 -C
10 -aryl, C
6 -C
10 -aryloxy, C
6 -C
10 -aryl-C
1 -C
16 -alkyl, C
6 -C
10 -aryl-C
1 -C
16 -alkoxy, NR
2 R
3 , COR
2 , COOR
2 and CONR
2 R
3 , and the radicals X
1 , X
2 and X
3 independently denote O or S.

公开(公告)号：EP2475711A1

公开(公告)日：2012-07-18

申请号：EP10752336.7

申请日：2010-09-06

Applicant: BASF SE

Inventor： HAHN, Klaus ,  RUCKDÄSCHEL, Holger ,  BELLIN, Ingo ,  MERKEL, Peter ,  HARTENSTEIN, Markus

IPC: C08J9/12

CPC classification number: C08J9/127 ,  C08J2201/03 ,  C08J2205/052 ,  C08J2325/12

Abstract: The invention relates to a closed-cell extruded foam that can be produced (a) by at least one styrene-acrylonitrile copolymer (SAN), and optionally at least one thermoplastic polymer from the group consisting of styrene copolymers, polyolefins, polyacrylates, polycarbonates (PC), polyesters, polyamides, polyether sulfones (PES), polyether ketones (PEK) and polyether sulfides, in order to form a polymer melt, (b) introducing between 1 and 12 wt. % (in relation to P) of a foaming constituent (T) containing less than 0.2 wt. % of water (in relation to P) and b1) between 15 and 95 wt. % (in relation to T) of carbon dioxide and b2) between 5 and 85 wt. % (in relation to T) of at least one co-foaming agent selected from the group consisting of C
1 -C
4 alcohols and C
1 -C
4 carbonyl compounds, into the polymer melts in order to form an expandable melt, (c) extruding the expandable melt in a region of lower pressure while expanding to form the extruded foam, and (d) optionally adding additives to form the polymer components (P) in at least one of the steps a), b) and/or c).

Abstract translation: （a）通过至少一种苯乙烯 - 丙烯腈共聚物（SAN）和任选的至少一种选自苯乙烯共聚物，聚烯烃，聚丙烯酸酯，聚碳酸酯（（甲基）丙烯酸酯）的热塑性聚合物制备的闭孔挤出泡沫体 PC），聚酯，聚酰胺，聚醚砜（PES），聚醚酮（PEK）和聚醚硫化物，以形成聚合物熔体，（b）引入1-12wt。 含有小于0.2wt。％的发泡成分（T）的％（相对于P） ％的水（相对于P）和b1）在15和95wt。 ％（相对于T）二氧化碳和b2）5-85wt。 ％（相对于T）至少一种选自C 1 -C 4醇和C 1 -C 4羰基化合物的共发泡剂加入聚合物熔体中以形成可膨胀熔体，（c ）在较低压力的区域内挤出可膨胀的熔体，同时膨胀以形成挤出的泡沫，和（d）任选地添加添加剂以在步骤a），b）和/或c中的至少一个中形成聚合物组分（P） ）。

公开(公告)号：EP2274369A1

公开(公告)日：2011-01-19

申请号：EP09738211.3

申请日：2009-04-30

Applicant: BASF SE

Inventor： BRAUN, Frank ,  BELLIN, Ingo ,  HAHN, Klaus

IPC: C08J9/00

CPC classification number: C08J9/0019 ,  C08J9/0066 ,  C08J2325/04

Abstract: The present invention relates to an expandable styrene polymer, comprising at least one flame retardant as component (A), 0.0001 to 2 wt.%, in relation to component (A), of at least one metal as component (B), and athermanous particles as component (C), to a method for the production of said expandable styrene polymer, to an expanded styrene polymer particle, comprising at least one flame retardant as component (A), 0.0001 to 2 wt.%, in relation to component (A), of at least one metal as component (B), and athermanous particles as component (C), to a method for the production of said expanded styrene polymer particle, to a foam that can be produced from said expandable styrene polymer, to a method for the production of said foam, and to the use of said foam for heat insulation, for the thermal insulation of machines and household appliances, and as a packaging material.