摘要:
The present invention relates to a method for producing polyurethane foams by reacting an isocyanate component with an isocyanate-reactive component comprising at least one polyethercarbonate polyol, the reaction taking place in the presence of a component K selected from one or more compounds from the group consisting of K1 esters of mono- or polybasic carboxylic acids whose (first) dissociation has a pKa of 0.5 to 4.0, K2 mono-, di- and polysulfonates of mono- and polyfunctional alcohols, and K3 one or more compounds from the group consisting of K 3.1 esters of phosphoric acid, phosphonic acid, phosphorous acid, phosphinic acid, phosphonous acid and phosphinous acid, these esters each containing no P-OH group, K3.2 oligomeric alkyl phosphates of the general formula (II), where a is an integer from 1 to 10, b is an integer from 1 to 10, R1, R2, R3 and R4 are alkyl groups having at least one carbon, and R1, R2, R3 and R4 are alike or, independently of one another, different, and R5 is a linear alkylene group having at least two carbons or is a branched alkylene group having at least three carbons, and K3.3 comprises oligomeric alkyl phosphates of the general formula (III), where a is an integer from 1 to 10, b is an integer from 1 to 10, R1, R4 and R5 are linear alkylene groups having at least two carbons or are branched alkylene groups having at least three carbons, and R1, R4 and R5 are alike or, independently of one another, different, and R2 and R3 are alkyl groups having at least one carbon, and R2 and R3 are alike or, independently of one another, different. The invention also relates to polyurethane foams produced by the method of the invention and to the use thereof.
摘要:
A method of producing a foam is disclosed. The method includes providing an epoxy-containing compound, a cationic catalyst, an optional blowing agent, and at least one additive. The method further includes combining the epoxy-containing compound with the cationic catalyst, the optional blowing agent, and the at least one additive, wherein the epoxy-containing compound and the cationic catalyst react to polymerize the epoxy-containing compound to provide a foam having a density from about 0.3lbs/ft 3 to about 5.0 lbs/ft 3 as measured by ASTM D1622. Further disclosed are the foam and a method for installing the foam.
摘要:
[Problem] To provide a fluorine-containing phosphate ester-amide which has high flame retardancy such as exhibiting flame retardant effects at a small quantity of addition, and sufficient hydrolysis resistance. [Solution] A fluorine-containing phosphate ester-amide represented by general formula (1). (In the formula, R1 and R2 are the same or different and represent a branched or linear alkyl group having 1 to 20 carbon atoms in which at least one carbon bonded to a nitrogen atom is a secondary or tertiary carbon, wherein R1 and R2 may have a substituent group selected from the group consisting of an alkoxy group, a hydroxy group, an amino group, a methyl amino group, an ethyl amino group, a dimethyl amino group, diethyl amino group and a fluorine atom. In addition, R1 and R2 may be bonded together to form a five- to eight-membered cyclic structure. X and Y are the same or different and represent a hydrogen atom or a fluorine atom, and n and m represent an integer of 1 to 6.)
摘要:
A foaming assistant material and a foam-molding method, which can achieve the functions of a nucleating agent, a dispersant, and the like sufficiently so that the cells can have smaller diameter, the mixing of foreign substances is prevented, and so on, and can produce the high-quality foam-molded article, are provided. The foaming assistant material is kneaded together with a raw material pellet and the mixture is subjected to the foam molding. The foaming assistant material is a pellet obtained by adding inorganic particles, a chemical foaming agent, and a dispersant to a dilution resin. An antioxidant may be added further to the dilution resin. In the foam-molding method, inorganic particles, a chemical foaming agent, a dispersant, and an antioxidant are added to a raw material resin at the same time in a state that the inorganic particles, the chemical foaming agent, the dispersant, and the antioxidant are mixed in advance.
摘要:
Die vorliegende Erfindung betrifft eine Additivzusammensetzung, geeignet als Additiv zur Steuerung der Schaumeigenschaften von Polyurethanschäumen, welche dadurch gekennzeichnet ist, dass sie mindestens ein ionisches Tensid A ausgewählt aus solchen der Formel A - M + , mit A - = Anion, ausgewählt aus der Gruppe umfassend Alkyl- und Arylsulfate, Polyethersulfate und -sulfonate, Sulfonate, Alkyl- und Arylsulfonate, Alkyl- und Arylcarboxylate, Saccharinate und Polyetherphosphate, und M + = Kation, und/oder mindestens ein ionisches Tensid B, ausgewählt aus einer quaternisierten Ammoniumverbindung, und mindestens eine tertiäre Aminverbindung C, die eine Molmasse von mindestens 150 g/mol aufweist, und/oder mindestens ein Oxazasilinan D, enthält, ein Verfahren zur Herstellung von Polyurethanschaum unter Verwendung dieser Additivzusammensetzung sowie entsprechend hergestellte Polyurethanschäume und deren Verwendung.
摘要:
An in-situ foaming system for forming a flame-retardant polyurethane foam in situ comprising a first liquid containing a polyisocyanate (A), a second liquid containing a polyol (B), a trimerization catalyst (C), a foaming agent (D), a foam stabilizer (E), and additives (F) comprising red phosphorus and at least one member selected from the group consisting of phosphoric acid esters, phosphate-containing flame retardants, bromine-containing flame retardants, borate-containing flame retardants, antimony-containing flame retardants, and metal hydroxides.
摘要:
Embodiments of the present disclosure are directed towards a flame retardant foam formulation. As an example, the flame retardant formulation can include a mono-phosphonate having a hydroxyl group, a polyisocyanate having a functionality in a range from 2.0 to 10.0, wherein the polyisocyanate is present in an amount to provide for an isocyanate index of from 100 to 320, a compound having active hydrogen groups capable of reacting with the polyisocyanate, a blowing agent, and a catalyst.