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31.发明公开PROCEDE D'HYDROCRAQUAGE DE COUPES HYDROCARBONNEES UTILISANT UN CATALYSEUR A BASE D'HETEROPOLYANIONS PIEGES DANS UN SUPPORT OXYDE MESOSTRUCTURE 有权FOR加氢裂化的烃馏分与基于在介孔结构氧化物载体的催化剂的方法。包含杂多阴离子
公开(公告)号：EP2655554A1
公开(公告)日：2013-10-30
申请号：EP11808891.3
申请日：2011-12-15
申请人： IFP Energies nouvelles , CNRS
发明人： MARCHAND, Karin , CHAUMONNOT, Alexandra , BONDUELLE, Audrey , DUFAUD, Véronique , LEFEBVRE, Frédéric , BADER, Manuela , LOPES SILVA, Susana
IPC分类号： C10G3/00 , B01J27/185 , B01J35/10 , C10G47/12 , B01J27/186 , B01J37/16 , C10G65/12 , B01J27/19 , B01J23/847 , B01J27/199 , B01J23/888 , B01J32/00
CPC分类号： C10G47/12 , B01J27/186 , B01J27/19 , B01J29/041 , B01J29/044 , B01J29/045 , B01J35/002 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J37/10 , B01J37/20 , C10G3/46 , C10G3/48 , C10G3/50 , C10G65/12 , C10G2300/1011 , C10G2300/1022 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/301 , C10G2300/4018 , Y02P30/20
摘要： A process for the hydrocracking a hydrocarbon-containing feedstock in which at least 50% by weight of the compounds have an initial boiling point above 340° C. and a final boiling point below 540° C., using a catalyst having, in its oxide form, at least one metal selected from the metals of groups VIB, VIII and VB, said metals being present in the form of at least one polyoxometallate of formula (HhXxMmOy)q-, said polyoxometallates being present within a mesostructured matrix based on oxide of at least one element Y, said matrix having a pore size between 1.5 and 50 nm and having amorphous walls of thickness between 1 and 30 nm, said catalyst being sulphurized before used in said process.
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32.发明公开MATERIAU SPHERIQUE A BASE D' HETEROPOLYANIONS PIEGES DANS UNE MATRICE OXYDE MESOSTRUCTUREE ET SON UTILISATION COMME CATALYSEUR DANS LES PROCEDES DU RAFFINAGE D ' HYDROCARBURES 审中-公开基于在介孔结构氧化物基质球状颗粒材料捕获的杂多阴离子和使用的催化剂的KOHLENWASSERSTOFFRAFFINIERUNGSVERFAHREN
公开(公告)号：EP2654946A1
公开(公告)日：2013-10-30
申请号：EP11808894.7
申请日：2011-12-15
申请人： IFP Energies Nouvelles , Université Pierre et Marie Curie , Centre National de la Recherche Scientifique
发明人： CHAUMONNOT, Alexandra , SANCHEZ, Clément , BOISSIERE, Cédric , COLBEAU-JUSTIN, Frédéric , MARCHAND, Karine , DEVERS, Elodie , BONDUELLE, Audrey , UZIO, Denis , DAUDIN, Antoine , GUICHARD, Bertrand
IPC分类号： B01J21/12 , B01J23/20 , B01J23/24 , B01J35/00 , B01J35/10 , C01B37/00 , C10G45/04 , C10G47/12 , B01J37/00 , B01J27/188 , B01J23/882 , B01J23/883 , C10G3/00
CPC分类号： B01J27/199 , B01J23/882 , B01J27/186 , B01J27/188 , B01J27/19 , B01J29/0333 , B01J29/0341 , B01J29/041 , B01J29/044 , B01J29/045 , B01J35/002 , B01J35/006 , B01J35/023 , B01J35/1019 , B01J35/1042 , B01J35/1057 , B01J35/1061 , B01J37/0045 , B01J37/033 , B01J37/10 , B01J37/20 , C01B37/00 , C01B37/005 , C01B37/02 , C01B39/04 , C01B39/06 , C10G3/45 , C10G3/46 , C10G3/48 , C10G3/49 , C10G3/50 , C10G45/06 , C10G47/12 , C10G2300/1011 , C10G2300/104 , C10G2300/1044 , C10G2300/1055 , C10G2300/202 , C10G2300/301 , C10G2400/02 , C10G2400/04 , C10G2400/06 , C10L1/04 , C10L1/06 , C10L1/08 , Y02P30/10 , Y02P30/20
摘要： An inorganic material is described consisting of at least two elementary spherical particles, each of said spherical particles comprising metallic particles in the form of polyoxometalate of formula (XxMmOyHh)q- where H is hydrogen, O is oxygen, X is an element chosen from phosphorus, silicon, boron, nickel and cobalt and M is one or more elements chosen from vanadium, niobium, tantalum, molybdenum, tungsten, iron, copper, zinc, cobalt and nickel, x being equal to 0, 1, 2 or 4, m being equal to 5, 6, 7, 8, 9, 10, 11, 12 and 18, y being between 17 and 72, h being between 0 and 12 and q being between 1 and 20 (y and q being integers). Said metallic particles are present within a mesostructured matrix based on an oxide of an element Y chosen from the group consisting of silicon, aluminium, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium and the mixture of at least two of these elements. Said matrix has pores with a diameter between 1.5 and 50 nm and amorphous walls with a thickness between 1 and 30 nm, said elementary spherical particles having a maximum diameter of 200 microns.
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33.发明授权
公开(公告)号：EP2197793B1
公开(公告)日：2011-08-17
申请号：EP08844304.9
申请日：2008-08-19
CPC分类号： C01B37/02 , C01B33/46 , C01B39/02 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993
摘要： The invention relates to a material having a hierarchised porosity and consisting of at least two elementary spherical particles. Each of said particles comprises a mesostructured matrix based on silicon oxide, the diameter of the mesopores being between 1.5 and 30 nm, and amorphous and microporous walls having a thickness of between 1.5 and 50 nm, the elementary spherical paricules having a maximum diameter of 200 microns. The matrix based on silicon oxide can contain aluminium. The invention also relates to the preparation of said material.
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34.发明公开CATALYSEUR A BASE D'UN MATERIAU CRISTALLISE COMPRENANT DU SILICIUM À POROSITÉ HIÉRARCHISÉE ET ORGANISEE ET PROCEDE AMELIORE DE TRAITEMENT DE CHARGES HYDROCARBONEES 有权方法催化剂的结晶含硅具有层次结构和组织空隙率，且改良的方法，用于治疗烃流组成
公开(公告)号：EP2296808A1
公开(公告)日：2011-03-23
申请号：EP09754064.5
申请日：2009-05-13
IPC分类号： B01J21/04 , B01J21/08 , B01J29/04 , B01J29/06 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/70 , B01J29/80 , B01J35/08 , B01J35/10 , C10G45/12 , C10G45/64 , C10G47/20
CPC分类号： C10G45/04 , B01J29/041 , B01J29/064 , B01J29/076 , B01J29/16 , B01J29/48 , B01J29/78 , B01J29/7815 , B01J29/80 , B01J35/023 , B01J35/1019 , B01J35/1057 , B01J35/1061 , B01J35/1066 , B01J37/0054 , B01J2229/10 , B01J2229/186 , B01J2229/40 , B01J2229/62 , C10G45/06 , C10G47/20 , C10G65/12
摘要： The present invention concerns a catalyst comprising at least one crystalline material comprising silicon with a hierarchical and organized porosity and at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and/or group VIII of the periodic table of the elements. Said crystalline material comprising silicon with a hierarchical and organized porosity is constituted by at least two spherical elementary particles, each of said particles comprising a matrix based on oxide of silicon, which is mesostructured, with a mesopore diameter in the range 1.5 to 30 nm and having microporous and crystalline walls with a thickness in the range 1.5 to 60 nm, said elementary spherical particles having a maximum diameter of 200 microns. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.
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35.发明公开CATALYSEUR A BASE D'UN MATERIAU AMORPHE COMPRENANT DU SILICIUM A POROSITÉ HIÉRARCHISÉE ET ORGANISEE ET PROCEDE AMELIORE DE TRAITEMENT DE CHARGES HYDROCARBONEES 有权方法催化剂的非晶硅含有分层结构和组织空隙率，且改良的方法，用于治疗烃流组成
公开(公告)号：EP2285486A1
公开(公告)日：2011-02-23
申请号：EP09754063.7
申请日：2009-05-13
IPC分类号： B01J21/04 , B01J21/08 , B01J23/28 , B01J23/30 , B01J23/42 , B01J23/652 , B01J23/75 , B01J23/755 , B01J29/00 , B01J29/04 , B01J29/06 , B01J29/068 , B01J29/072 , B01J29/80 , B01J35/08
CPC分类号： B01J35/1061 , B01J21/12 , B01J23/85 , B01J23/888 , B01J29/041 , B01J29/48 , B01J29/7815 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J37/0054 , C10G45/08 , C10G45/10 , C10G45/12 , C10G47/02 , C10G47/10 , C10G47/14 , C10G47/16 , C10G49/02 , C10G49/04 , C10G49/06 , C10G49/08
摘要： The invention relates to a catalyst containing at least one amorphous material, containing silicon having hierarchical and organized porosity, and at least one hydro-dehydrogenating element selected from the group formed by elements from Group VIB and/or Group VIII of the periodic table. Said amorphous material, which contains silicon having hierarchical and organized porosity, consists of at least two elementary spherical particles, each of said particles including a mesostructured silicon oxide matrix having a mesopore diameter of 1.5 to 30 nm and having amorphous microporous walls with a thickness of 1.5 and 50 nm, said elementary spherical particles having a maximum diameter of 200 microns. The invention also relates to hydrocracking/hydroconversion and hydrotreatment methods implementing said catalyst.
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36.发明公开
公开(公告)号：EP2274235A1
公开(公告)日：2011-01-19
申请号：EP09734713.2
申请日：2009-02-26
CPC分类号： C01B37/00 , B01J21/02 , B01J21/063 , B01J29/061 , C01B37/005 , C01B39/04 , Y10T428/2991 , Y10T428/2993
摘要： An inorganic material is described that is composed of at least two elementary spherical particles, each of said spherical particles comprising metallic nanoparticles having a size between 1 and 300 nm and a mesostructured matrix based on an oxide of at least one element X chosen from the group composed of silicon, aluminium, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium and the mixture of at least two of these elements, said mesostructured matrix having a pore diameter between 1.5 and 30 nm and having amorphous walls of thickness between 1 and 30 nm, said elementary spherical particles having a diameter D greater than 10 µm and less than or equal to 100 µm. Said material may also contain zeolite nanocrystals trapped within said mesostructured matrix.
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