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    DIFLUORBENZONITRILE UND FLÜSSIGKRISTALLINES MEDIUM
    34.
    发明授权
    DIFLUORBENZONITRILE UND FLÜSSIGKRISTALLINES MEDIUM 失效
    DIFLUORBENZONITRILE UNDFLÜSSIGKRISTALLINESMEDIUM

    公开(公告)号：EP0441933B1

    公开(公告)日：1994-04-06

    申请号：EP90912905.8

    申请日：1990-08-24

    申请人： MERCK PATENT GmbH

    发明人： REIFFENRATH, Volker ,  KURMEIER, Hans-Adolf ,  SCHEUBLE, Bernhard

    IPC分类号： C07D239/26 ,  C07D239/34 ,  C07D213/57 ,  C07D213/65 ,  C09K19/34

    CPC分类号： C07D239/26 ,  C07D213/57 ,  C07D213/65 ,  C07D239/34 ,  C09K19/3444 ,  C09K19/3469

    摘要： Disclosed are difluorobenzonitriles of the formula (I) in which Y is an alkyl, alkenyl, alkoxy, oxaalkyl or alkenyloxy with 1-12 C-atoms, one of the residues A?1 and A2¿ in the molecule is (a), in which X is CH or N, and the other residue A1 or A2 is selected from the following: (b) and (c), one of the residues Z?1 and Z2¿ is a single bond and the other residue Z1 or Z2 is -CH¿2?CH2- or a single bond and m is 0 or 1, with the provision that, if m = 1, Z?1 = Z2¿ = a single bond and one of the residues A?1 and A2¿ = pyrimidine-2,5-diyl and the other residue A1 or A2 = 1,4-phenylene, then A1 is pyrimidine-2,5-diyl.

    摘要翻译： 公开了式（I）的二氟苯甲腈，其中Y是具有1-12个碳原子的烷基，烯基，烷氧基，氧杂烷基或烯氧基，分子中残基A 1和A 2中的一个是（a）， 其中X是CH或N，另一个残基A1或A2选自下列：（b）和（c），残基Z1和Z2中的一个是单键，另一个残基Z1或Z2是 -CH 2 --CH 2 - 或单键，并且m为0或1，条件是如果m = 1，则Z 1 = Z 2 =单键并且残基A 1和A 2中的一个= 嘧啶-2,5-二基，另一残基A1或A2 = 1,4-亚苯基，则A1为嘧啶-2,5-二基。

    CYCLOHEXANDERIVATE
    40.
    发明授权
    CYCLOHEXANDERIVATE 失效

    公开(公告)号：EP0215120B1

    公开(公告)日：1989-08-23

    申请号：EP86902808.4

    申请日：1986-03-21

    申请人： MERCK PATENT GmbH

    发明人： POHL, Ludwig ,  SCHEUBLE, Bernhard ,  HITTICH, Reinhard ,  EIDENSCHINK, Rudolf ,  KURMEIER, Hans-Adolf ,  WÄCHTLER, Andreas

    IPC分类号： C07C121/60 ,  C07C121/75 ,  C07C13/28 ,  C07C25/18 ,  C07C121/46 ,  C07C121/48 ,  C07C43/21 ,  C07C43/184

    CPC分类号： C07C255/00 ,  C07C13/28 ,  C07C25/18 ,  C07C43/184 ,  C07C43/188 ,  C07C43/21 ,  C07C43/225 ,  C07C45/004 ,  C07C45/46 ,  C07C49/313 ,  C07C49/792 ,  C09K19/3003 ,  C09K19/3068

    摘要： Cyclohexane derivatives of formula R1-A1-Z1-A2-R2 in which R1 and R2 are in each case an alkyl group with 1-10 C atoms, in which also one or two non neighboring CH2 groups can be replaced by O atoms and/or -CO- groups and/or -CO-O- groups and/or -CH=CH- groups, one of the remainder R1 and R2, also H, F, Cl, Br, CN or R3-A3-Z2-, A1 is -A-, A4-A- or -A-A4-, A is a substituted trans-1,4-cyclohexyl group substituted in 2nd, 3rd, 5th and/or 6th position, substituted once or substituted several times by F and/or Cl and/or Br and/or CN and/or an alkyl group or a fluoridated alkyl group, each with 1-10 atoms, in which also one or two not neighboring CH2 groups can be replaced by O atoms and/or -CO- groups and/or -CO-O- groups; which also, as the case may be, can be substituted in 1st and/or 4th position, A2, A3 and A4 are in each case an unsubstituted 1,4-phenylene, or a 1,4-phenyl substituted by one or two F and/or Cl atoms and/or CH3 groups and/or CN groups, in which also one or two CH groups can be replaced by N atoms and/or NO, 1,4-cyclohexylene, in which one or two not neighboring CH2 groups may be substituted by O atoms, 1,3-dithiane-2,5-diyl, piperidine-1,4-diyl, 1,4-bicyclo(2,2,2)-octylene-, decahydronaphthalene-2,6-diyl-, or 1,2,3,4-tetrahydronaphthalene-2,6-diyl groups, Z1 and Z2 are either -CO-O-, -O-CO-, -CH2CH2-, OCH2-, -CH2O or a single link, and R3 is H, an alkyl group with 1-10, in which also one or two not-neighboring CH2 groups can be replaced by O atoms and/or -CO- groups and/or -CO-O- groups and/or -CH=CH- groups; F, Cl,Br or CN, it being understood that if Z1 = -CO-O- A1 in beta-position, to the -CO-O- bridge it carries no equatorial substitutes, are suitable as components for liquid crystal phases.

    摘要翻译： 式R 1 -A 1 -Z 1 -A 2 -R 2的环己烷衍生物，其中R 1和R 2各自为具有1-10个C原子的烷基，其中一个或两个非相邻的CH 2基团也可以被O原子和/ 或-CO-基团和/或-CO-O-基团和/或-CH = CH-基团，其余的R 1和R 2之一，还有H，F，Cl，Br，CN或R 3 -A 3 -Z 2 - A1是-A-，A4-A-或-A-A4-，A是在第2,3,5和/或6位取代的取代的反式-1,4-环己基，被F取代一次或被F 和/或Cl和/或Br和/或CN和/或烷基或氟化烷基，其各自具有1-10个原子，其中一个或两个不相邻的CH 2基团也可以被O原子替代和/或 -CO-基团和/或-CO-O-基团; 其也视情况可以在第一和/或第四位置取代，A2，A3和A4各自为未取代的1,4-亚苯基或被一个或两个F取代的1,4-苯基 和/或Cl原子和/或CH 3基团和/或CN基团，其中一个或两个CH基团可以被N原子和/或NO取代，1,4-亚环己基，其中一个或两个不相邻的CH 2基团 可以被O原子取代，1,3-二噻烷-2,5-二基，哌啶-1,4-二基，1,4-双环（2,2,2-亚辛基），十氢化萘-2,6-二基 - 或1,2,3,4-四氢萘-2,6-二基，Z 1和Z 2为-CO-O - ， - O-CO - ， - CH 2 CH 2 - ，OCH 2 - ， - CH 2 O或单链 ，并且R3是H，具有1-10的烷基，其中还有一个或两个不相邻的CH2基团可以被O原子和/或-CO-基团和/或-CO-O-基团取代和/或 -CH = CH-基团; F，Cl，Br或CN，应当理解，如果Z1 = -CO-O-A1在β位，与-CO-O-桥不携带赤道取代基，则适合作为液晶相的组分。