摘要:
The present invention relates to a preparation for a polyurethane foam and a polymer polyol preparation for a polyurethane foam, each of which exhibits high coloration and discoloration inhibition properties over a long period of time when stored, and to a composition for a polyurethane foam, which is excellent in storage stability and is preferable as a resin premix. The composition for a polyurethane foam of the present invention is characterized by comprising (i) at least one polyol selected from a polyoxyalkylene polyol and a polymer polyol wherein polymer fine particles obtained by polymerizing a compound having an unsaturated bond are dispersed in the polyoxyalkylene polyol, (ii) a compound having a P=N bond, (iii) an antioxidant having a hydroxyphenyl group, (iv) at least one acid selected from the group consisting of an acyclic aliphatic monocarboxylic acid of 2 to 25 carbon atoms, a hydroxycarboxylic acid of 2 to 25 carbon atoms, a polycarboxylic acid of 20 to 60 carbon atoms, a specific aromatic monocarboxylic acid, a sulfonic acid and an acid having a sulfuric acid ester group, or its salt, (v) a catalyst for polyurethane foam production and (vi) a blowing agent.
摘要:
The present invention relates to a reactive formulation used to make a flame resistant flexible polyurethane foam which is particularly suited for use in under the hood vehicle applications which require sound deadening and vibration management and a process to make said foam. Said foam is particularly suitable for such applications because desirable flame resistant properties are achieved after exposure to heat over an extended period of time. In particular, the flame resistant flexible polyurethane foam is made from a reactive formulation comprising an A side comprising (i) one or more organic isocyanate and a B side comprising (ii) one or more isocyanate-reactive component, (iii) a flame retardant component comprising a combination of red phosphorus, expandable graphite, and optionally sodium citrate wherein the flame retardant component does not contain ammonium polyphosphate; and (iv) one or more additional component selected from a catalyst, a blowing agent, a cell opener, a surfactant, a crosslinker, a chain extender, a filler, a colorant, a pigment, an antistatic agent, reinforcing fibers, an antioxidant, a preservative, or an acid scavenger wherein the resulting foam achieves after heat aging at 150C for seven days a V-0 rating at 0.5 inch according to Underwriters' Laboratories Standard 94 Flammability Test.
摘要:
A flame retardant blend comprises the following components: (a) at least one diester diol of a ring-brominated aromatic compound; (b) at least one alkylated triphenylphosphate; and (c) at least one hindered phenolic anti-oxidant in which the phenolic ring is substituted by at least one alkanoic alkyl ester group in which the alkanoic acid moiety has from about 2 to about 4 carbon atoms and the alkyl group has about 6 to about 16 carbon atoms. The proportions by weight of components (a) and (b) in the blend are in the range of about 30:70 to about 70:30 and the proportion by weight of component (c) to the sum of components (a) and (b) is in the range of about 0.1 : 100 to 1 : 100.
摘要:
An expandable bead material comprising A) a polymer matrix composed of A1) at least 55% by weight of polyester (based on the entirety of components A1) and A2)) having a total enthalpy of fusion of up to 60 J/g, optionally of one or more melting points in the range from 100 to 300°C and of one or more glass transition temperatures in the range from 0 to 250°C, and A2) from 0 to 45% by weight (based on the entirety of components A1) and A2)) of one or more thermoplastic polymers different from component A1); B) a physical blowing agent component, and C) optionally further additives is suitable for producing bead foams for use in the automobile industry, airline industry, construction industry, packaging industry, sports and leisure industry, in transport, in engineering, in lightweight construction, and/or in composite construction.
摘要:
The invention relates to expandable polymers and/or polymer granulates of cellulose acetate butyrate (CAB) having an average molecular weight (Mn), determined as polystyrene-equivalent molecular weight by means of gel chromatography, of ≥ 20.000 g/mol and an average butyryl content of cellulose acetate butyrate of ≥ 20 wt. %, preferably ≥ 30 wt.%, and corresponding polymer foams.
摘要:
The present invention provides expandable beads having an average particle size of 0.5 to 10 mm, a density of 0.033 to 0.80 g/cc, and a flame retardancy of V-0 or V-1 as measured according to the UL-94 vertical test (20 mm vertical burn test) in the UL standards.
摘要:
There is provided herein a polyolefin composition comprising a polyolefϊn and a flame retardant effective amount of a solid phosphate ester of the genera! formula ( 1 ): wherein n has an average value of from about 1.0 to about 2,0 and X is a divalent arylene moiety bonded to both of the oxygen atoms of any one of faydroqtiinnne, resoreinol. 4,4'-biρhenol, bisphenol S, or bisphenol F and wherein the phosphate ester is in the absence of halogen. There is also provided a method of waking the polyolefin composition. This fire relardam polyoleiln composition is ρarticulary useful in polypropylene fiber and films and foams.
摘要:
There is provided herein a composition comprising: (a) a flexible polyurethane foam-forming mixture and; an effective flame retarding amount of at least one nan halogen-containing cyclic phosphate ester of the general formula (I) wherein R 1 and R 2 , are the same or different, linear or branched alkyl group containing from up to about 10 carbon atoms, optionally containing heteroatom substituents, provided that R 1 and R 2 are not both methyl; and R 3 -R 7 are each independently hydrogen or the same or different linear or branched alkyl group containing up to about 4 carbon atoms, optionally containing heteroatom substituents; provided that the cyclic phosphate ester is a liquid or is substantially soluble in at least one different liquid flame retardant and/or the hydroxyl-containing component of the flexible polyurethane foam-forming mixture; the cyclic phosphate ester of formula (I) contains at least 8.5 weight percent phosphorous based on the total weight of any phosphorous containing component(s); and, provided that the composition is in the absence of melamine compound. There is also provided a flame retardant additive composition comprising the cyclic phosphate ester of formula (I) and at least one different liquid flame retardant, Further, there is provided a process of making a flame retarded polyurethane foam mixture.
摘要:
The invention relates to a method for making a fireproof polymer foam, and to a fireproof polymer foam containing a mixture of a polymer composition containing one or more optionally-substituted, sequenced or random, thermoplastic and/or elastomer homopolymers, copolymers or mixtures thereof, from 0.05 to 10 wt %, preferably from 0.5 to 5 wt %, relative to the mixture, of carbon nanotubes, and from 0.05 to 15 wt %, preferably from 0.5 to 10 wt %, relative to the mixture, of red phosphorus.