AQUEOUS POLYMER DISPERSION FOR PAPER WITH A COPOLYMER OF VINYL ACETATE AND AN ACRYLATE MONOMER PREPARED IN THE PRESENCE OF A STARCH DERIVATIVE
    31.
    发明公开
    AQUEOUS POLYMER DISPERSION FOR PAPER WITH A COPOLYMER OF VINYL ACETATE AND AN ACRYLATE MONOMER PREPARED IN THE PRESENCE OF A STARCH DERIVATIVE 审中-公开
    水性聚合物分散体拟从醋酸乙烯酯的共聚物和丙烯酸酯单体,MADE以衍生物强度的存在

    公开(公告)号:EP3129439A1

    公开(公告)日:2017-02-15

    申请号:EP15714223.3

    申请日:2015-04-07

    Applicant: BASF SE

    Abstract: The invention relates to a process for preparing an aqueous dispersion of a polymer P, which comprises the emulsion polymerization of vinyl acetate, an acrylate monomer, which is a C
    1 -C
    10 alkyl acrylate or a C
    1 -C
    10 methacrylate, an α,β-ethlyenically unsaturated C3-C8 carboxylic acid and at least one out of glycidyl methacrylate, glycidyl acrylate, allyl methacrylate and allyl acrylate, in the presence of a starch derivative. Optionally, an additional monomer is an ethylenically unsaturated sulfonic acid, an ethylenically unsaturated other monomer or both of them. Furthermore, the aqueous polymer dispersion obtainable from this process and a powder form thereof are disclosed. They are useful for a paper coating slip containing one of the aforementioned forms. A paper or a cardboard, which is coated with the paper coating slip, shows surface strength, which is expressed by a good dry pick resistance, a good wet pick resistance or good offset test results. The aqueous polymer dispersion or the powder form thereof is furthermore useful as a binder.

    Abstract translation: 本发明涉及一种用于在聚合物P,其包含醋酸乙烯酯的乳液聚合的丙烯酸酯单体,的wässrige分散制备,所有这是一个C1-C10烷基丙烯酸酯或C1-C10甲基丙烯酸酯,α,β-ethlyenically 不饱和的C 3 -C 8羧酸和至少一个出甲基丙烯酸缩水甘油酯,丙烯酸缩水甘油酯,甲基丙烯酸烯丙酯和丙烯酸烯丙酯,在淀粉存在衍生物。 任选附加的单体是烯属不饱和磺酸,以烯属不饱和单体或其他的它们两者。 进一步,从该过程中wässrige聚合物分散体获得的A和粉末形式是其游离缺失光盘。 他们是一纸涂料包含前述形式中的一种非常有用。 涂有涂纸浆的纸或纸板,所有,示出了表面强度,所有这些都通过一个很好的干抗起毛性,良好的湿抗起毛性或良好的偏移的测试结果中过表达。 所述wässrige聚合物分散体或它们的粉末形式是另外作为粘合剂更加有用。

    WATER BORNE POLYOLEFIN DISPERSION COATINGS, AND METHODS OF MAKING
    36.
    发明公开
    WATER BORNE POLYOLEFIN DISPERSION COATINGS, AND METHODS OF MAKING 有权
    水性聚烯烃分散体涂料及其制备方法

    公开(公告)号:EP3072925A1

    公开(公告)日:2016-09-28

    申请号:EP16160914.4

    申请日:2016-03-17

    Abstract: The present invention provides aqueous polyolefin dispersion compositions for use in metal coatings, such as can coatings, comprising one or more polyolefin base polymer, one or more at least partially neutralized olefinic stabilizing agent having an acid number (AN) of from 80 to 250, preferably, a polyolefin stabilizing agent, such as an olefin-carboxylic acid copolymer or a blend of two such polymers, an optional coupling agent having an acid number (AN) of from 10 to 70 and a melt index of from 500 to 5,000,000 grams of polymer melt passing in 10 minutes through a heated syringe or cylinder at 190 °C with a plunger loaded with 2.16 kg, preferably, a polymer, and a hindered phenolic antioxidant containing an ester linkage dispersed in the polyolefin dispersion composition. The hindered phenolic antioxidant containing an ester linkage can be masterbatched with a polyolefin base polymer, polyolefin stabilizing agent or a coupling agent which is a polymer, melt mixed with the remaining polyolefin composition and then dispersed with aqueous media and a neutralizing agent to form the aqueous dispersion.

    Abstract translation: 本发明提供用于金属涂料例如罐涂料的含水聚烯烃分散体组合物,其包含一种或多种聚烯烃基础聚合物,一种或多种至少部分中和的烯属稳定剂,其酸值(AN)为80-250, 优选地,聚烯烃稳定剂如烯烃 - 羧酸共聚物或两种这样的聚合物的共混物,任选的酸值(AN)为10至70且熔体指数为500至5,000,000克的偶联剂 聚合物熔体在190℃用加载有2.16kg,优选聚合物的柱塞和含有分散在聚烯烃分散体组合物中的酯键的受阻酚抗氧化剂通过加热的注射器或圆筒在10分钟内通过。 含有酯键的受阻酚抗氧化剂可以与聚烯烃基础聚合物,聚烯烃稳定剂或聚合物偶联剂一起进行母炼胶,与剩余的聚烯烃组合物熔融混合,然后用水介质和中和剂分散以形成水溶液 分散。

    HIGH EFFICIENCY RHEOLOGY MODIFERS WITH CATIONIC COMPOMENTS AND USE THEREOF
    37.
    发明公开
    HIGH EFFICIENCY RHEOLOGY MODIFERS WITH CATIONIC COMPOMENTS AND USE THEREOF 审中-公开
    与阳离子成分及其用途高效的流变改性剂

    公开(公告)号:EP3055285A2

    公开(公告)日:2016-08-17

    申请号:EP14851637.0

    申请日:2014-10-03

    Abstract: The presently disclosed claimed inventive concept(s) relates generally to a rheology modifier composition and an aqueous protective coating composition containing the rheology modifier composition. More particularly, the presently disclosed and/or claimed inventive concept(s) relates to a rheology modifier composition comprising (a) about 50 to about 99% by weight of a water soluble polymer and about 1 to about 50% by weight of a cationic polymer, wherein the cationic polymer is produced by polymerizing a quaternized monomer or by polymerizing a quaternized monomer and a non-quaternized monomer. Additionally, the presently disclosed and/or claimed inventive concept(s) relates generally to the methods of making the rheology modifier composition and the aqueous protective coating composition.

    Abstract translation: 目前游离缺失盘要求保护的发明构思涉及基因集会流变改性剂组合物和wässrige保护涂料组合物包含流变改性剂组合物。 50至约更具体地,当前盘游离缺失和/或要求保护的发明构思涉及一种流变改性剂组合物(重量)的水溶性聚合物与约1至约50%,其包含(a)约99%重量的阳离子的 聚合物,worin阳离子聚合物是由季铵化的单体聚合或通过季铵化单体和非季铵化的单体聚合来制造。 此外,当前盘游离缺失和/或要求保护的发明构思涉及基因反弹到使所述流变改性剂组合物和wässrige保护性涂层组合物的方法。

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