BALLISTIC RESISTANT ARTICLE COMPRISING A STYRENE BUTADIENE RESIN AND PROCESS TO MANUFACTURE SAID ARTICLE
    46.
    发明公开
    BALLISTIC RESISTANT ARTICLE COMPRISING A STYRENE BUTADIENE RESIN AND PROCESS TO MANUFACTURE SAID ARTICLE 有权
    根据上述制造此文章苯乙烯 - 丁二烯树脂和方法防火安全的产品

    公开(公告)号:EP2665985A1

    公开(公告)日:2013-11-27

    申请号:EP12700360.6

    申请日:2012-01-18

    IPC分类号: F41H5/04

    摘要: A ballistic resistant article is presented comprising a plurality of fibrous layers, each of said layers comprising a network of fibers, wherein the fibers have a strength of at least 800 mN/tex (1100 MPa) according to ASTM D 7269-07 and a matrix material, wherein the matrix material comprises a mixture comprising: at least one styrene butadiene random copolymer resin, and at least one tackifier. Compared with an article of the same construction but with a matrix material without a tackifier the article according to the invention comprises a higher adhesion between the fibrous layers both in the unaged and aged state and a lower water pick up after water soak. The article additionally comprising a plate of metal or ceramic exhibits minimal or even no delamination of the fibrous layers after ballistic attack. In contrast an article of the same construction but with a matrix material without the styrene butadiene random copolymer resin exhibits (very strong) interior delamination of the fibrous layers and the article of the same construction with the styrene butadiene random copolymer resin, but without the tackifier as the matrix material exhibits light delamination.

    METHOD FOR INCREASING THE SULFURIC ACID CONCENTRATION OF A SULFURIC ACID SOLUTION
    47.
    发明公开
    METHOD FOR INCREASING THE SULFURIC ACID CONCENTRATION OF A SULFURIC ACID SOLUTION 有权
    法提高硫酸溶液的浓度硫酸

    公开(公告)号:EP2643267A1

    公开(公告)日:2013-10-02

    申请号:EP11779372.9

    申请日:2011-10-26

    IPC分类号: C01B17/88 D01F13/04 B01D1/00

    摘要: The invention pertains to a method of increasing the sulfuric acid concentration of a first aqueous sulfuric acid solution with a sulfuric acid concentration of 82-89% to a concentrated sulfuric acid solution with a sulfuric acid concentration of at least 90%, comprising the steps of evaporating water from the first aqueous sulfuric acid solution in an evaporator vessel to the concentrated sulfuric acid solution, pumping around a mixture of the first aqueous sulfuric acid solution, part of the concentrated sulfuric acid solution, a second aqueous sulfuric acid solution, and hydrogen peroxide through an enameled piping system comprising the evaporator vessel and one or more heaters and pumps, which piping system is operating at a temperature of at least 180°C, characterized in that the sulfuric acid concentration of the second aqueous sulfuric acid solution is at least 90%.

    METHOD FOR SPINNING AND WASHING ARAMID FIBER AND RECOVERING SULFURIC ACID
    49.
    发明授权
    METHOD FOR SPINNING AND WASHING ARAMID FIBER AND RECOVERING SULFURIC ACID 有权
    方法自旋和芳纶纤维洗涤回收选自硫酸

    公开(公告)号:EP2205781B1

    公开(公告)日:2012-06-20

    申请号:EP08842223.3

    申请日:2008-10-10

    IPC分类号: D01F13/04 D01F6/60

    摘要: The invention pertains to a method for spinning and washing aramid fiber and for recovering sulfuric acid, using a spinning unit and a sulfuric acid recovery unit, comprising the steps: a) spinning an aramid polymer from a sulfuric acid spin dope to a yarn and coagulating the yarn in a coagulation bath having an inlet for water or diluted sulfuric acid and an outlet for sulfuric acid enriched water; b) washing the yarn with water to obtain washed yarn and washing water containing 0.5-20 wt.% sulfuric acid; c) recycling the sulfuric acid enriched water and optionally the washing water to the sulfuric acid recovery unit; d) increasing the sulfuric acid content of the recycled sulfuric acid enriched water, and optionally the washing water, by evaporation to obtain 20 to 98% sulfuric acid and water; e) mixing the 20 to 98% sulfuric acid with oleum to obtain 98-105% sulfuric acid; f) recycling the 98-105% sulfuric acid to the spinning unit for use as sulfuric acid spin dope.

    PROCESS FOR PRODUCING A PLURALITY OF HIGH-STRENGTH, HIGH MODULUS AROMATIC POLYAMIDE FILAMENTS
    50.
    发明授权
    PROCESS FOR PRODUCING A PLURALITY OF HIGH-STRENGTH, HIGH MODULUS AROMATIC POLYAMIDE FILAMENTS 有权
    PROCESS FOR几个强势,AROMATIC HOCHMODULUS聚酰胺长丝的制备

    公开(公告)号:EP2321452B8

    公开(公告)日:2012-04-11

    申请号:EP09809302.4

    申请日:2009-07-21

    IPC分类号: D01D5/06 D01F6/60

    CPC分类号: D01D5/06 D01F6/605

    摘要: Process for producing a plurality of high strength, high modulus aromatic polyamide filaments comprising the steps of - extruding an acid solution containing at least 15 % by weight of an aromatic polyamide through linearly arranged orifices in a spinneret thus providing a warp of filaments - passing the warp of filaments through a layer of non-coagulating fluid into a coagulation bath and subsequently - passing the warp through a spin tube, the spin tube having an elongated cross section with at least two opposite sides being parallel to the filament warp with the length of these sides being at least as long as the width of the filament warp - jetting additional coagulating liquid at a constant flow rate about the filaments in a downward direction at an angle between 15° and 75° with respect to the filaments, - the jetted coagulating liquid moving downward with the warp of filaments through the spin tube at a velocity of about 50% to 100% of the velocity of the filaments, the coagulating liquid being jetted through a jet channel from either one side of the spin tube which is parallel to the filament warp, the jet channel having at least the same width as the filament warp