A novel method of preparing phenoxy ethers for use as agrochemical intermediates
    42.
    发明公开
    A novel method of preparing phenoxy ethers for use as agrochemical intermediates 失效
    制备用于农业中间体的酚氧化物的新方法

    公开(公告)号:EP0404092A3

    公开(公告)日:1992-02-12

    申请号:EP90111631.9

    申请日:1990-06-20

    摘要: N-n-propyl-N-2-(2,4,6-trichlorophenoxy)-ethylamine is prepared by selectively chlorinating 2-phenoxy ethanol by reacting it with chlorine either in the presence of hydrogen chloride at a temperature of from -10°C to 50°C or in the presence of urea at a temperature of from 20°C to 55°C in a water/carbon tetrachloride solvent mixture to form 2-(2,4,6-tri­chlorophenoxy)ethanol; reacting the 2-(2,4,6-trichloro­phenoxy)ethanol with thionyl chloride in the presence of a catalytic amount of tetraalkyl ammonium chloride, optionally in the presence of a solvent to form 2-(2,4,6-trichlorophenoxy,ethyl chloride; and reacting the 2-(2,4,6-trichlorophenoxy) ethyl chloride with n-propylamine at a temperature of from 20°C to 150°C, optionally in the presence of water to form N-n-propyl-­N-2-(2,4,6-trichlorophenoxy) ethyl amine,

    Method of preparing flame retardant thermoplastic nylon resins
    44.
    发明公开
    Method of preparing flame retardant thermoplastic nylon resins 失效
    Verfahren zur Herstellung flammfester thermoplastischer Nylonharze。

    公开(公告)号:EP0100582A1

    公开(公告)日:1984-02-15

    申请号:EP83302578.6

    申请日:1983-05-06

    IPC分类号: C08L77/00 C08L63/02

    摘要: A method of preparing flame retardant thermoplastic nylon compositions comprises incorporating into the thermoplastic nylon a halogenated, preferably brominated, bisphenol-A epoxy resin having a halogen content of at least 20% and a molecular weight about 8,000, e.g. in an amount comprising 3 to 40 parts by weight, preferably 5 to 25 parts by weight of the composition. Antimony trioxide may also be incorporated, e.g. in a weight ratio of epoxy resin to antimony trioxide of 0.25 to 6.

    摘要翻译: 一种制备阻燃热塑性尼龙组合物的方法包括将具有至少20%的卤素含量和约8,000的分子量的卤化的,优选溴化的双酚A环氧树脂掺入热塑性尼龙中。 其量为组合物的3至40重量份,优选5至25重量份。 也可以掺入三氧化锑。 环氧树脂与三氧化锑的重量比为0.25〜6。

    Pesticidal composition
    45.
    发明授权
    Pesticidal composition 有权
    农药组合物

    公开(公告)号:EP2258194B1

    公开(公告)日:2013-01-02

    申请号:EP10178570.7

    申请日:2005-10-31

    IPC分类号: A01N51/00 A01N47/02 A01N43/90

    摘要: The present invention provides an insecticidal composition comprising of at least one insecticidal compound with effective knock-down action selected from among group (A) comprising of imidacloprid, acetamiprid, thiamethoxam, thiacloprid, nitenpyram, dinotefuran, clothianidin, abamectin, emamectin, emamectin benzoate and fipronil, and at least one insecticidal compound with effective long-term action selected from among group (B) of insect growth regulators comprising of benzoylphenyl urea (BPU) compounds selected from among novaluron, lufenuron, hexaflumuron, triflumuron, diflubenzuron, chlorfluazuron, flufenoxuron, noviflumuron and teflubenzuron. Optionally, said insecticidal composition may further contain excipients and/or additives and/or surface active agents. Further provided is a method for insect control, comprising of applying at least one insecticidal compound with effective knock-down action selected from among group (A) comprising of imidacloprid, acetamiprid, thiamethoxam, thiacloprid, nitenpyram, dinotefuran, clothianidin, abamectin, emamectin, emamectin benzoate and fipronil, and at least one insecticidal compound with effective long-term action selected from among group (B) of insect growth regulators (IGR) comprising of benzoylphenyl urea (BPU) compounds; to a crop, agricultural product, plant matter, animal or locale.

    POLYMORPHS OF 3-(E)-2-{2-[6-(2-CYANOPHENOXY) PYRIMIDIN-4-YLOXY]PHENYL}-3-METHOXYACRYLATE
    47.
    发明公开
    POLYMORPHS OF 3-(E)-2-{2-[6-(2-CYANOPHENOXY) PYRIMIDIN-4-YLOXY]PHENYL}-3-METHOXYACRYLATE 有权
    多异氰酸酯3-(E)-2- {2- [6-(2-氰基苯氧基)嘧啶-4-基]苯基} -3-甲氧基丙烯酰胺

    公开(公告)号:EP2129221A2

    公开(公告)日:2009-12-09

    申请号:EP08702644.9

    申请日:2008-01-16

    IPC分类号: A01N43/54 C07D239/52

    CPC分类号: C07D239/52 A01N43/54

    摘要: The present invention relates to novel crystalline polymorphic and amorphous forms of the compound methyl (E)-2-{2-[6-(2-cyanophenoxy)pyrimidin-4-yloxy]phenyl}-3-methoxy-acrylate (azoxystrobin). Infrared Raman spectra, X-ray powder diffraction pattern and differential scanning calorimetry thermogram of two polymorphs "A" and "B" are provided. Further, the present invention also provides methods for preparing the novel polymorphic forms "A" and "B", as well as processes for producing mixtures of the polymorphs, and a process for preparing amorphous azoxystrobin. Yet further, the present invention provides anti-fungal compositions comprising the novel crystalline polymorphs "A" and "B" or amorphous azoxystrobin, which are useful for controlling and combating fungi grown on agricultural and horticultural crops and up-land, and methods of using the same as pesticidal agents for combating fungi on agricultural and horticultural crops.

    摘要翻译: 本发明涉及化合物甲基(E)-2- {2- [6-(2-氰基苯氧基)嘧啶-4-基氧基]苯基} -3-甲氧基 - 丙烯酸酯(嘧菌酯)的新型结晶多晶型和无定形形式。 提供了两种多晶型物“A”和“B”的红外拉曼光谱,X射线粉末衍射图和差示扫描量热法。 此外,本发明还提供了制备新型多晶型“A”和“B”的方法,以及制备多晶型物的混合物的方法,以及制备无定形嘧菌酯的方法。 此外,本发明提供了包含新型结晶多晶型物“A”和“B”或无定形嘧菌酯的抗真菌组合物,其可用于控制和对抗在农业和园艺作物和陆地上生长的真菌,以及使用方法 与农业和园艺作物上的杀真菌剂相同。

    PROCESS FOR PREPARING PYRIDINAMINES AND NOVEL POLYMORPHS THEREOF
    48.
    发明公开
    PROCESS FOR PREPARING PYRIDINAMINES AND NOVEL POLYMORPHS THEREOF 审中-公开
    用于生产其PYRIDINAMINEN和新晶型

    公开(公告)号:EP1954271A2

    公开(公告)日:2008-08-13

    申请号:EP06821571.4

    申请日:2006-11-23

    IPC分类号: A61K31/44

    CPC分类号: C07D213/74

    摘要: The present invention relates to an improved process for the synthesis and purification of 3-chloro-N-(3-chloro-5-trifluoromethyl-2-pyridyl)-a,a,a-trifluoro-2,6-dinitro-p-toluidine (fluazinam) and other pyridinamines, which implements methyl isobutyl ketone (MIBK) as the reaction solvent. The process of the invention overcomes the drawbacks of prior art methods, by reducing the side reactions such as hydrolysis, eliminating the need for difficult and labor-intensive purification methods, and providing pure products in higher yields. The present invention relates to novel crystalline polymorphic forms fluazinam, and to mixtures of the polymorphs. The present invention also provides methods for preparing the novel polymorphs, as well as pharmaceutical compositions comprising same, and methods of using the polymorphs as pesticidal agents for combating noxious living organisms on agricultural and horticultural crops.

    PEST CONTROL SHEET
    49.
    发明公开
    PEST CONTROL SHEET 有权
    害虫控制表

    公开(公告)号:EP1330160A2

    公开(公告)日:2003-07-30

    申请号:EP01982691.6

    申请日:2001-11-01

    发明人: BARAZANI, Avner

    IPC分类号: A01N25/34 A01G13/02

    摘要: A sheet for pest control, wherein said sheet is of polymeric material and comprises at least two layers; a top layer and a bottom layer, wherein the bottom layer contains a herbicide and one or more pesticides selected from among fungicides and insecticides, and the top layer optionally containing an insecticide and/or fungicide. Other aspects of the invention include a polymeric composition used in the preparation of the sheets and a method for pest control in agriculture, horticulture and gardens.

    摘要翻译: 一种用于有害生物防治的片材,其中所述片材是聚合物材料并且包含至少两层; 顶层和底层,其中底层含有除草剂和一种或多种选自杀真菌剂和杀虫剂的杀虫剂,顶层任选含有杀虫剂和/或杀真菌剂。 本发明的其它方面包括用于制备片材的聚合物组合物和用于农业,园艺和花园中的害虫防治的方法。