公开(公告)号：EP2346799A4

公开(公告)日：2012-05-30

申请号：EP08878190

申请日：2008-11-17

申请人： UOP LLC

发明人： KRUPA STEVEN L ,  MEISTER JILL M

IPC分类号： C07C6/04 ,  C07C2/14 ,  C07C5/25 ,  C07C7/163 ,  C07C11/06

CPC分类号： C07C5/2506 ,  C07C2/08 ,  C07C2/14 ,  C07C6/04 ,  C07C7/163 ,  C07C11/02 ,  C07C11/06 ,  C10G2300/1092 ,  C10G2400/20 ,  C10G2400/22 ,  C07C11/08

公开(公告)号：EP2415739A1

公开(公告)日：2012-02-08

申请号：EP10758764.4

申请日：2010-03-31

申请人： Mitsui Chemicals, Inc.

发明人： MIYAZOE, Satoru ,  IKENAGA, Hirokazu ,  KOTANI, Makoto

IPC分类号： C07C6/04 ,  B01J23/10 ,  B01J23/30 ,  C07C11/06 ,  C07B61/00 ,  C07C5/25

CPC分类号： B01J23/10 ,  B01J23/002 ,  B01J23/007 ,  B01J23/02 ,  B01J23/24 ,  B01J23/30 ,  B01J23/36 ,  B01J35/0006 ,  B01J35/1014 ,  B01J37/0009 ,  B01J2523/00 ,  C07C5/2512 ,  C07C6/04 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/10 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/36 ,  Y02P20/52 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/36 ,  C07C11/06 ,  C07C11/08

摘要： [Object] It is an object of the present invention to provide a method for manufacturing an olefin, wherein side reactions of a metathesis reaction are suppressed and the selectivity of a desired product is increased by facilitating double bond isomerization of raw material olefins. Furthermore, it is an object to provide a method for manufacturing an olefin, wherein a desired product can be obtained efficiently at a high productivity by maintaining the activity of a metathesis catalyst for a long term and suppressing deterioration of performance of a catalyst (isomerization catalyst) for facilitating double bond isomerization of the raw material olefins.
[Solution] A method for manufacturing an olefin according to the present invention is a method for manufacturing an olefin through reaction between the same type of or different types of raw material olefins to obtain an olefin having a structure different from the structure of the raw material olefins, the method including using a catalyst containing at least one type of metal element selected from the group consisting of tungsten, molybdenum, and rhenium together with other specific catalysts.

摘要翻译： 本发明的目的是提供一种烯烃的制造方法，其中通过促进原料烯烃的双键异构化，可以抑制复分解反应的副反应并提高所需产物的选择性。 此外，本发明的目的是提供一种制备烯烃的方法，其中通过长期维持复分解催化剂的活性并抑制催化剂（异构化催化剂）性能的劣化，可以以高生产率有效地获得所需产物 ），用于促进原料烯烃的双键异构化。 [方案]根据本发明的烯烃的制造方法是通过相同类型或不同类型的原料烯烃之间的反应制备烯烃的方法，以获得具有不同于原料结构的结构的烯烃 烯烃，该方法包括使用含有选自钨，钼和铼中的至少一种类型的金属元素的催化剂以及其它特定的催化剂。

公开(公告)号：EP2330091A1

公开(公告)日：2011-06-08

申请号：EP09809969.0

申请日：2009-08-27

申请人： Mitsui Chemicals, Inc.

发明人： TAKAI, Toshihiro ,  IKENAGA, Hirokazu ,  KOTANI, Makoto ,  MIYAZOE, Satoru

IPC分类号： C07C6/04 ,  C07C11/06 ,  C07B61/00

CPC分类号： C07C6/04 ,  C07C5/2775 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/16 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/36 ,  C07C2527/232 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/08

摘要： A process is provided which is capable of producing olefins stably and efficiently by a metathesis reaction of identical or different olefins while preventing the lowering in metathesis catalyst activity due to trace impurities such as heteroatom-containing compounds that are contained in a starting olefin.
The olefin production process includes supplying a starting olefin containing more than 0 ppm by weight to not more than 10 ppm by weight of one or more kinds of heteroatom-containing compounds to a reactor that contains a metathesis catalyst and an isomerization catalyst, the metathesis catalyst including at least one metal element selected from the group consisting of tungsten, molybdenum and rhenium, the isomerization catalyst including calcined hydrotalcite or yttrium oxide, and performing a metathesis reaction of identical or different olefins.

公开(公告)号：EP2280017A1

公开(公告)日：2011-02-02

申请号：EP09290578.5

申请日：2009-07-21

申请人： Telene SAS

发明人： Drozdzak, Renata

IPC分类号： C07F15/00 ,  B01J31/28 ,  C07C6/04

CPC分类号： C07F15/002 ,  C07F15/0046

摘要： The present invention relates to a catalytic complex for olefin metathesis reactions, to a process for its preparation and to its use in olefin metathesis reactions, particularly in ring opening metathesis polymerisation (ROMP) reactions.

摘要翻译： 本发明涉及用于烯烃复分解反应的催化络合物，其制备方法及其在烯烃复分解反应中的应用，特别是在开环易位聚合反应（ROMP）中。

公开(公告)号：EP1854776A4

公开(公告)日：2010-07-28

申请号：EP06714632

申请日：2006-02-24

申请人： MITSUI CHEMICALS INC

发明人： TAKAI TOSHIHIRO ,  KUBOTA TAKESHI

IPC分类号： C07C6/04 ,  C07C11/06

CPC分类号： C07C6/04 ,  C07C2523/30 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/02

公开(公告)号：EP1353889B1

公开(公告)日：2010-07-14

申请号：EP02703253.1

申请日：2002-01-24

申请人： Lummus Technology Inc.

发明人： GARTSIDE, Robert, J.

IPC分类号： C07C11/04 ,  C07C11/107 ,  C07C6/04 ,  C07C5/25

CPC分类号： C07C11/107 ,  C07C5/25 ,  C07C6/04 ,  C07C11/02 ,  C07C11/04 ,  C07C2521/08 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/36 ,  Y02P20/52

摘要： Ethylene and hexene-1 are produced from butene-1 by metathesis of butene-1 and isomerization of the hexene-3 produced therein to hexene-1. The initial staring material is a mixed butene stream wherein butene-1 is isomerized to butene-2 with isobutylene being separated therefrom, followed by isomerization of butene-2 to butene-1, with the butene-1 being the feed to the metathesis.

公开(公告)号：EP2157071A3

公开(公告)日：2010-03-31

申请号：EP09014595.4

申请日：2003-03-07

申请人： Lummus Technology Inc.

发明人： Gartside, Robert, J. ,  Greene, Marvin, I. ,  Jones, Quincy, J.

IPC分类号： C07C6/04

CPC分类号： C07C11/107 ,  C07C5/2512 ,  C07C6/04 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/16 ,  C07C2523/24 ,  C07C2523/30 ,  C07C2523/32 ,  C07C2529/06

摘要： A C 3 to C 6 hydrogen cut from a cracking unit is processed for the conversion of olefins to propylene and hexene via autometathesis. The autometathesis (16) of a mixed normal butenes feed (10) in the presence of a metathesis catalyst operates without any ethylene in the feed mix to the metathesis reactor. Some fraction of the 2-butene feed may be isomerized to 1-butene and the 1-butene formed plus the 1-butene in the feed react rapidly with the 2-butene to form propylene and 2-pentene. The feed to the reactor also includes the recycle of the 2-pentene (14) formed in the reactor with unreacted butenes to simultaneously form additional propylene and hexene. Some or all (34) of the 3-hexene (26) formed in the reaction is isomerized to 1-hexene (46). In one embodiment, some portion (72) of the 3-hexene (26) produced in the main metathesis reaction is reacted with ethylene to produce 1-butene (96) without the need for superfractionation.

公开(公告)号：EP2162413A1

公开(公告)日：2010-03-17

申请号：EP08767616.9

申请日：2008-05-07

申请人： Lyondell Chemical Technology, L.P.

发明人： LEYSHON, David, W.

IPC分类号： C07C11/06 ,  C07C6/04

CPC分类号： C07C5/2506 ,  C07C6/04 ,  C07C11/06 ,  C07C11/08

摘要： A process for producing propylene from ethylene and a feed stream comprising 1-butene, 2-butene, n-butane, and isobutane is disclosed. A butenes stream (1-butene and 2-butene) is produced from the feed stream by removing the paraffins. The butenes stream is reacted in the presence of an isomerization catalyst to produce an isomerized stream with increased concentration of 2-butene. The isomerized stream is reacted with ethylene in the presence of a metathesis catalyst to produce a reaction mixture comprising propylene; the propylene may be isolated from the reaction mixture by distillation. The removal of paraffins from the feed stream improves the catalyst productivity and the plant throughput.

公开(公告)号：EP2099732A1

公开(公告)日：2009-09-16

申请号：EP07848497.9

申请日：2007-12-11

申请人： BP OIL INTERNATIONAL LIMITED

发明人： Basset, Jean-Marie ,  Stoffelbach, Francois ,  Taoufik, Mostafa ,  Thivolle-cazat, Jean

IPC分类号： C07C6/04 ,  C07C11/107

CPC分类号： C10L1/06 ,  B01J21/04 ,  B01J31/121 ,  B01J37/0209 ,  B01J2531/66 ,  C07C6/04 ,  C07C2521/04 ,  C07C2531/12 ,  C07C11/107

摘要： The present invention relates to a process for manufacturing neohexene, comprising contacting isobutene with a supported catalyst comprising a tungsten compound chosen from tungsten hydrides, organometallic tungsten compounds and organometallic tungsten hydrides, and a support comprising an oxide of aluminium, so as to form a reaction mixture comprising neohexene, and preferably separating neohexene from the reaction mixture, so as to isolate it. The contacting leads to the direct production of neohexene, in particular in a single (reaction) stage and with a high molar selectivity for neohexene. The contacting can be performed at a temperature of 50 to 600 °C, under a total absolute pressure of 0.01 to 100 MPa.

公开(公告)号：EP2019814A1

公开(公告)日：2009-02-04

申请号：EP07729213.4

申请日：2007-05-16

申请人： TOTAL PETROCHEMICALS RESEARCH FELUY

发明人： BOUVART, François ,  VERMEIREN, Walter ,  GARCIA, Wolfgang ,  CHEPDA, Alain

IPC分类号： C07C7/04 ,  C07C6/04 ,  C07C7/163 ,  C07C7/167

CPC分类号： C07C6/04 ,  C07C4/02 ,  C07C7/04 ,  C07C7/163 ,  C07C7/167 ,  Y02P20/52 ,  C07C11/06 ,  C07C9/10 ,  C07C11/08

摘要： The present invention relates to a process for the producing propylene and ethylene from a light hydrocarbon stream comprising essentially ethane and butane. The process involves a non-catalytic cracking of ethane and normal-butane followed by a metathesis of ethylene and 2-butene to increase the propylene yield. Optionally the by-produced iso-butane is dehydrogenated and subsequently the produced iso-butene is converted to other valuable products like di-isobutylene, alkylate for gasoline blending tertiary-butyl-ethers, poly-isobutylene methyl-metacrylate or isoprene.