公开(公告)号：EP2404983A1

公开(公告)日：2012-01-11

申请号：EP10305745.1

申请日：2010-07-06

申请人： Total Raffinage Marketing

发明人： Borremans, Didier ,  Lacroix, Maxime ,  Le Lannic- Dromard, Katell ,  Ropars, Marie ,  Vendrell, Gloria

IPC分类号： C10G49/00 ,  C10G49/12 ,  C10G49/04 ,  C10G65/02 ,  C10G49/02 ,  B01J31/22 ,  B01J27/047 ,  B01J27/049

CPC分类号： C10G65/12 ,  B01J31/2295 ,  B01J2231/645 ,  B01J2231/646 ,  B01J2531/56 ,  B01J2531/64 ,  B01J2531/842 ,  C10G49/00 ,  C10G49/02 ,  C10G49/04 ,  C10G49/12 ,  C10G65/02 ,  C10G67/12 ,  C10G2300/1011 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/42 ,  C10G2300/703 ,  Y02P30/20

摘要： The invention concerns a process for hydroconversion of a hydrocarbonaceous feedstock comprising:
- a preparation step of at least one catalyst in one or more preparation reactor upstream from a reaction section, wherein
- (i) at least one preparation reactor feeds one or more reactor of the reaction section, or
- (ii) preparation reactors are dedicated for catalysts fed to at least a hydroconversion reactor or at least a hydrotreatment reactor of the reaction section;

- a separation step of solids contained in the liquid effluents issued from the reaction section,
- a treatment step of residues issued from separation section, comprising a partial oxidation step wherein said residues are partially oxidized to produce carbon monoxide, hydrogen an a metal containing residue.
Such process permits improving of products quality, operation of the separation section, recovering of catalytic metals contained in the feed and supplying hydrogen to the reaction section.

摘要翻译： 本发明涉及一种用于烃类原料包括加氢转化的方法： - 从反应段，worin至少一种催化剂的制备步骤中的一个或多个制备反应器上游 - （i）至少一个制备反应器进料的一个或多个反应器 该反应段，或 - （ⅱ）制备的反应器专门用于馈送到至少一个加氢转化反应器或至少一个反应段的加氢处理反应器的催化剂; - 包含在从该反应段，发出的液体流出物的固体的分离步骤 - 从分离单元发出残基的处理工序中，包括部分氧化步骤worin所述残基被部分氧化，以产生一氧化碳，氢气在含有金属残余物 ， 这种方法允许提高产品质量，分离段的操作中，进料中所含的催化金属的回收和供给氢到反应部。

公开(公告)号：EP2404649A1

公开(公告)日：2012-01-11

申请号：EP10305746.9

申请日：2010-07-06

申请人： Total Raffinage Marketing

发明人： Le Lannic-Dromard, Katell ,  Vendrell, Gloria ,  Prout, Sylvain

IPC分类号： B01D37/00 ,  C10G49/00 ,  C10G49/12 ,  C10G49/22 ,  C10G65/02 ,  C10G67/02

CPC分类号： C10G49/22 ,  C10G49/00 ,  C10G49/12 ,  C10G65/02 ,  C10G67/02

摘要： The instant invention discloses a method for the separation of solids contained in a solid containing treated hydrocarbon feedstock issued from an industrial unit, wherein an ultimate reactor is fed with an ultimate catalyst, an ultimate hydrocarbon feedstock and an ultimate hydrogen containing gas, and wherein after reaction, the resulting ultimate treated hydrocarbon feedstock undergoes a liquid-solid filtration before a final fractionation is performed.

摘要翻译： 本发明公开了一种用于分离由工业单元发行的含固体处理的烃原料中所含的固体的方法，其中最终反应器被供给极限催化剂，最终烃原料和最终含氢气体， 反应，所得最终处理的烃原料在进行最终分馏之前进行液固过滤。

公开(公告)号：EP1999233A4

公开(公告)日：2011-04-13

申请号：EP07758375

申请日：2007-03-12

申请人： HEADWATERS HEAVY OIL LLC

发明人： LOTT ROGER K

IPC分类号： C10C1/00 ,  B01J27/047 ,  B01J27/051 ,  B01J35/00 ,  B01J37/02 ,  B01J37/08 ,  B01J38/00 ,  B01J38/68 ,  C10G45/00 ,  C10G47/00 ,  C10G47/02 ,  C10G49/04 ,  C10G65/02 ,  C10G65/12

CPC分类号： C10G47/00 ,  B01F3/088 ,  B01F2003/105 ,  B01J8/0015 ,  B01J27/047 ,  B01J27/051 ,  B01J35/0013 ,  B01J37/02 ,  B01J37/086 ,  B01J38/00 ,  B01J38/68 ,  B01J2208/00752 ,  C10G45/00 ,  C10G49/04 ,  C10G65/02 ,  C10G65/12 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/802

摘要： Methods and systems for mixing a catalyst precursor with a heavy oil feedstock preparatory to hydroprocessing the heavy oil feedstock in a reactor to form an upgraded feedstock. Achieving thorough dispersion of the catalyst precursor facilitates and maximizes the advantages of the colloidal or molecular hydroprocessing catalyst. A catalyst precursor and a heavy oil feedstock having a viscosity greater than the viscosity of the catalyst precursor are provided. The catalyst precursor is pre-mixed with a hydrocarbon oil diluent, forming a diluted catalyst precursor. The diluted precursor is then mixed with a first portion of the heavy oil feedstock to form a blended oil feedstock composition. Finally, the blended oil feedstock composition is mixed with a second remaining portion of the heavy oil feedstock, resulting in the catalyst precursor being homogeneously dispersed on a colloidal and/or molecular level within the heavy oil feedstock.

公开(公告)号：EP1753845A4

公开(公告)日：2010-12-15

申请号：EP05741051

申请日：2005-04-28

申请人： HEADWATERS HEAVY OIL LLC

发明人： LOTT ROGER K ,  LEE LAP-KEUNG ,  QUINN PETER C

IPC分类号： A61K39/12 ,  B01J8/00 ,  B01J8/02 ,  B01J27/047 ,  B01J27/051 ,  B01J35/00 ,  B01J37/02 ,  B01J37/08 ,  B01J38/00 ,  B01J38/68 ,  C07K14/025 ,  C10G45/00 ,  C10G45/16 ,  C10G47/00 ,  C10G47/02 ,  C10G47/26 ,  C10G49/04 ,  C10G65/02 ,  C10G65/04 ,  C10G65/12

CPC分类号： B01J27/047 ,  B01J27/051 ,  B01J35/0013 ,  B01J37/02 ,  B01J37/086 ,  B01J38/00 ,  B01J38/68 ,  C10G45/00 ,  C10G47/00 ,  C10G49/04 ,  C10G65/02 ,  C10G65/12

摘要： A fixed bed hydroprocessing system, and also a method for upgrading a pre-existing fixed bed hydroprocessing system, involves preliminarily upgrading a heavy oil feedstock in one or more slurry phase reactors using a colloidal or molecular catalyst and then further hydroprocessing the upgraded feedstock within one or more fixed bed reactors using a porous supported catalyst. The colloidal or molecular catalyst is formed by intimately mixing a catalyst precursor composition into a heavy oil feedstock and raising the temperature of the feedstock to above the decomposition temperature of the precursor composition to form the colloidal or molecular catalyst in situ. Asphaltene or other hydrocarbon molecules otherwise too large to diffuse into the pores of the fixed bed catalyst can be upgraded by the colloidal or molecular catalyst. One or more slurry phase reactors may be built and positioned upstream from one or more fixed bed reactors of a pre-existing fixed bed system and/or converted from one or more pre-existing fixed bed reactors.

摘要翻译： 的固定床加氢处理系统中，并因此用于升级预先存在的固定床加氢处理系统的方法，包括预先在一个或多个淤浆相反应器使用胶体或分子催化剂，然后进一步加氢处理提高的原料升级一个内的重油给料 或多个固定使用多孔负载型催化剂床反应器。 胶体或分子催化剂由催化剂前体组合物充分混合成重油给料，提高原料的温度到高于前体组合物的分解温度以原位形成胶体或分子催化剂形成的。 沥青质或其它的烃分子否则太大扩散到固定床催化剂的孔隙可通过胶体或分子催化剂进行升级。 一个或多个淤浆相反应器可以被内置，并从一个上游或多个固定预先存在的固定床系统的床反应器和/或从一个或多个预先存在的固定床反应器中转化。

公开(公告)号：EP1824947A4

公开(公告)日：2010-11-17

申请号：EP05791327

申请日：2005-09-07

申请人： CHEVRON USA INC

发明人： CHEN KAIDONG ,  LEUNG PAK C ,  REYNOLDS BRUCE E

IPC分类号： C10G65/02 ,  B01J27/051 ,  B01J37/20 ,  C10G47/02 ,  C10G47/22 ,  C10G49/04 ,  C10G49/12

CPC分类号： C10G45/08 ,  B01J27/0515 ,  B01J27/053 ,  B01J35/12 ,  B01J37/20 ,  C10G45/16 ,  C10G47/06 ,  C10G47/26 ,  C10G49/12 ,  C10G2300/1003 ,  C10G2300/1022 ,  C10G2300/1033 ,  C10G2300/1074 ,  C10G2300/1088 ,  C10G2300/207 ,  C10G2300/301 ,  C10G2300/703

摘要： The instant invention is directed to a process for upgrading heavy oils using a slurry composition. The slurry composition is prepared by a series of steps, involving mixing a Group VIB metal oxide and aqueous ammonia to form an aqueous mixture, and sulfiding the mixture to form a slurry. The slurry is then promoted with a Group VIII metal. Subsequent steps involve mixing the slurry with a hydrocarbon oil and combining the resulting mixture with hydrogen gas and a second hydrocarbon oil having a lower viscosity than the first oil. An active catalyst composition is thereby formed.

公开(公告)号：EP2190955A1

公开(公告)日：2010-06-02

申请号：EP08799078.4

申请日：2008-09-03

申请人： UOP LLC

发明人： KALNES, Tom N. ,  MARKER, Terry L. ,  BRADY, John P. ,  KOKAYEFF, Peter

IPC分类号： C10L1/08 ,  C10G3/00 ,  C10G65/02

CPC分类号： C10L1/08 ,  C10G3/46 ,  C10G3/50 ,  C10G45/58 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1022 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/28 ,  Y02E50/13 ,  Y02P30/20

摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant oils and animal oils, fats, and greases. The process involves treating a renewable feedstock by hydrogenating and deoxygenating i.e. decarboxylating, decarbonylating, and/or hydrodeoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel or diesel boiling range fuel blending component. If desired, the hydrocarbon fraction can be isomerized to improve cold flow properties. A portion of the hydrogenated and deoxygenated feedstock is selectively separated and then recycled to the treatment zone to increase the hydrogen solubility of the reaction mixture.

公开(公告)号：EP1084211A4

公开(公告)日：2009-11-25

申请号：EP99920292

申请日：1999-04-30

申请人： EXXONMOBIL RES & ENG CO

发明人： ELLIS EDWARD STANLEY ,  LEWIS WILLIAM ERNEST ,  DANKWORTH DAVID CHARLES ,  GUPTA RAMESH

IPC分类号： C10G65/00 ,  C10G65/04 ,  C10G45/02 ,  C10G65/02

CPC分类号： C10G65/00

公开(公告)号：EP1090092A4

公开(公告)日：2008-11-12

申请号：EP99920033

申请日：1999-04-26

申请人： EXXONMOBIL RES & ENG CO

发明人： GUPTA RAMESH

IPC分类号： C10G45/00 ,  C10G45/04 ,  C10G45/06 ,  C10G47/00 ,  C10G47/02 ,  C10G47/10 ,  C10G65/00 ,  C10G65/02 ,  C10G65/04

CPC分类号： C10L1/003 ,  C10G65/00 ,  C10G65/04

摘要： A process for hydroprocessing middle distillate petroleum streams in two temperature stages is disclosed. The feedstream (11) is hydroprocessed in two or more first temperature stages operated at a temperature from about 360 to about 450 degrees celsius. The reaction product (13) of the first temperature stage(s) is quenched to a temperature from about 260 to about 350 degrees celsius, stripped of hydrogen sulfide, ammonia and other dissolved gases to form a reaction product (17) which is sent to a second temperature stage which is operated at said quenched temperature range. The product from the second temperature stage is also stripped of dissolved gases in a stripping zone (16b). Color bodies produced in the higher temperature first stage are hydrogenated in the last stage.

公开(公告)号：EP1511824A4

公开(公告)日：2008-07-09

申请号：EP03726599

申请日：2003-05-02

申请人： CHEVRON USA INC

发明人： YOON H ALEX ,  PAREKH JAY ,  DAHLBERG ARTHUR J

IPC分类号： C10G65/10 ,  C10G65/12 ,  C10G65/02 ,  C10G65/14 ,  C10G65/18

CPC分类号： C10G65/10 ,  C10G65/12

摘要： This invention relates to a multi-stage process for hydroprocessing gas oils. Preferably, each stage possesses at least one hydrocracking zone. The second stage and any subsequent stages possess an environment having a low heteroatom content. Light products, such as naphtha, kerosene and diesel, may be recycled from fractionation (along with light products from other sources) to the second stage (or a subsequent stage) in order to produce a larger yield of lighter products, such as gas and naphtha. Subsequent zones are maintained at a lower pressure than that of the first zone, thereby reducing operating expenses.

公开(公告)号：EP1931752A1

公开(公告)日：2008-06-18

申请号：EP06791993.6

申请日：2006-09-12

申请人： Haldor Topsoe A/S

发明人： HUNTER, Michael, Glenn ,  VIVAS, Angelica, Hidalgo ,  JENSEN, Lars, Skov ,  LOW, Gordon, Gongngai

IPC分类号： C10G65/02 ,  C10G65/12 ,  C10G65/14

CPC分类号： C10G65/12 ,  C10G65/02 ,  C10G65/14 ,  C10G2300/207 ,  C10G2400/04

摘要： Partial conversion hydrocracking process comprising the steps of (a) hydrotreating a hydrocarbon feedstock with a hydrogenrich gas to produce a hydrotreated effluent stream comprising a liquid/vapor mixture and separating the liquid/vapor mixture into a liquid phase and a vapor phase, and (b) separating the liquid phase into a controlled liquid portion and an excess liquid portion, and (c) combining the vapor phase with the excess liquid portion to form a vapor plus liquid portion, and (d) separating an FCC feed-containing fraction from the controlled liquid portion and simultaneously hydrocracking the vapor plus liquid portion to produce a dieselcontaining fraction, or hydrocracking the controlled liquid portion to produce a diesel-containing fraction and simultaneously separating a FCC feed-containing fraction from the vapor plus liquid portion. The invention also includes an apparatus for carrying out the partial conversion hydrocracking process.

摘要翻译： 部分转化加氢裂化方法包括以下步骤：（a）用富氢气体加氢处理烃原料以产生包含液体/蒸汽混合物的加氢处理流出物流，并将液体/蒸汽混合物分离成液相和气相，和（b ）将液相分离成受控的液体部分和过量的液体部分，和（c）将气相与过量的液体部分组合以形成蒸气加液体部分，和（d）将FCC原料的馏分与 控制液体部分，并同时加氢裂化蒸汽加液体部分以产生含柴油馏分，或加氢裂化受控液体部分以产生含柴油馏分，同时将FCC进料的馏分与蒸气加液体部分分离。 本发明还包括用于进行部分转化加氢裂化过程的装置。