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    FIXED BED HYDROPROCESSING METHODS AND SYSTEMS AND METHODS FOR UPGRADING AN EXISTING FIXED BED SYSTEM
    1.
    发明授权
    FIXED BED HYDROPROCESSING METHODS AND SYSTEMS AND METHODS FOR UPGRADING AN EXISTING FIXED BED SYSTEM 有权
    固定床加氢处理方法和用于升级现有固定床系统的系统和方法

    公开(公告)号：EP1753845B1

    公开(公告)日：2018-01-03

    申请号：EP05741051.6

    申请日：2005-04-28

    申请人： Headwaters Heavy Oil, LLC

    发明人： LOTT, Roger, K. ,  LEE, Lap-Keung ,  QUINN, Peter, C.

    IPC分类号： A61K39/12 ,  C07K14/025

    CPC分类号： B01J27/047 ,  B01J27/051 ,  B01J35/0013 ,  B01J37/02 ,  B01J37/086 ,  B01J38/00 ,  B01J38/68 ,  C10G45/00 ,  C10G47/00 ,  C10G49/04 ,  C10G65/02 ,  C10G65/12

    摘要： A fixed bed hydroprocessing system, and also a method for upgrading a pre-existing fixed bed hydroprocessing system, involves preliminarily upgrading a heavy oil feedstock in one or more slurry phase reactors using a colloidal or molecular catalyst and then further hydroprocessing the upgraded feedstock within one or more fixed bed reactors using a porous supported catalyst. The colloidal or molecular catalyst is formed by intimately mixing a catalyst precursor composition into a heavy oil feedstock and raising the temperature of the feedstock to above the decomposition temperature of the precursor composition to form the colloidal or molecular catalyst in situ. Asphaltene or other hydrocarbon molecules otherwise too large to diffuse into the pores of the fixed bed catalyst can be upgraded by the colloidal or molecular catalyst. One or more slurry phase reactors may be built and positioned upstream from one or more fixed bed reactors of a pre-existing fixed bed system and/or converted from one or more pre-existing fixed bed reactors.

    HYDRODESULFURIZATION CATALYST FOR HYDROCARBON OIL, PRODUCTION METHOD FOR SAME, AND HYDROREFINING METHOD FOR HYDROCARBON OIL
    7.
    发明公开
    HYDRODESULFURIZATION CATALYST FOR HYDROCARBON OIL, PRODUCTION METHOD FOR SAME, AND HYDROREFINING METHOD FOR HYDROCARBON OIL 审中-公开
    加氢脱硫催化剂的烃油，加工为油气石油生产国和HYDRO精炼过程

    公开(公告)号：EP2586529A1

    公开(公告)日：2013-05-01

    申请号：EP11798112.6

    申请日：2011-06-21

    申请人： JX Nippon Oil & Energy Corporation ,  JGC Catalysts And Chemicals Ltd.

    发明人： SEKI, Hiroyuki ,  YOSHIDA, Masanori ,  TAGAWA, Shogo ,  KAGAWA, Tomoyasu

    IPC分类号： B01J27/051 ,  B01J37/02 ,  B01J37/04 ,  B01J37/08 ,  B01J37/20 ,  C10G45/08

    CPC分类号： B01J27/051 ,  B01J21/063 ,  B01J21/12 ,  B01J23/882 ,  B01J27/19 ,  B01J35/0013 ,  B01J37/0045 ,  B01J37/0203 ,  B01J37/20 ,  C10G45/08 ,  C10G2300/1059 ,  C10G2300/1074 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/4018

    摘要： The present invention provides a hydrodesulfurization catalyst exhibiting a high desulfurization activity when used for hydrotreating a hydrocarbon oil, particularly straight-run gas oil. The hydrodesulfurization catalyst is a catalyst produced by pre-sulfurizing a hydrodesulfurization catalyst Y comprising a support containing silica, alumina and titania and at least one type of metal component supported thereon and selected from VIA and VIII groups of the periodic table (comprising at least Mo), in which the total area of the diffraction peak area indicating the crystal structure of anatase titania (101) planes and the diffraction peak area indicating the crystal structure of rutile titania (110) planes in the support, measured by X-ray diffraction analysis being 1/4 or less of the alumina diffraction peak area assigned to γ-alumina (400) planes, the molybdenum is formed into molybdenum disulfide crystal and disposed in layers on the support by the pre-sulfurization, and the molybdenum disulfide crystal layers having an average length of longer than 3.5 nm and 7 nm or shorter in the plane direction and an average number of laminated layers of more than 1.0 and 1.9 or fewer.

    摘要翻译： 本发明提供了一种加氢脱硫催化剂具有高的脱硫活性当用于加氢处理烃油，特别是直馏瓦斯油。 加氢脱硫催化剂通过硫化预加氢脱硫催化剂Y包含载体包含二氧化硅，氧化铝和二氧化钛和至少一种类型的在其上的金属组分的载体的和从VIA选择和VIII组周期表的制备的催化剂（至少含有Mo ），其中，所述衍射峰面积的指示锐钛矿二氧化钛（101）面的晶体结构和衍射峰面积指示金红石二氧化钛（110）面的在载体上的晶体结构，通过X射线衍射分析测得的总面积 为1/4或更小分配给³氧化铝氧化铝衍射峰面积（400）晶面，所述钼形成为二硫化钼晶体和在层布置在由预硫化的支撑，并且具有二硫化钼晶体层 上在平面方向上和在平均数目大于1.0和1.9或叠层的长于3.5 nm和7纳米或更短的平均长度 少。

    PROCESS FOR CRACKING A HYDROCARBON-CONTAINING FEED
    8.
    发明公开
    PROCESS FOR CRACKING A HYDROCARBON-CONTAINING FEED 审中-公开
    裂化含烃原料的方法

    公开(公告)号：EP2526172A2

    公开(公告)日：2012-11-28

    申请号：EP11701343.3

    申请日：2011-01-21

    申请人： Shell Oil Company ,  Shell Internationale Research Maatschappij B.V.

    发明人： MILAM, Stanley Nemec ,  REYNOLDS, Michael Anthony ,  WELLINGTON, Scott Lee

    IPC分类号： C10G47/06

    CPC分类号： C10G47/06 ,  B01J27/04 ,  B01J27/047 ,  B01J27/051 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/031 ,  B82Y30/00 ,  C01G39/006 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C10G47/26 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/207 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012

    摘要： A process for treating a hydrocarbon-containing feed is provided in which a hydrocarbon-containing feed comprising at least 20 wt.% of heavy hydrocarbons is mixed with hydrogen, hydrogen sulfide, and a catalyst to produce a hydrocarbon-containing product, where hydrogen sulfide is provided at a mole ratio relative to hydrogen of at least 0.5:9.5. The catalyst is comprised of a material comprised of a first metal and a second metal, where the first metal is selected from the group consisting of Cu, Fe, Ni, Co, Bi, Ag, Mn, Zn, Sn, Ru, La, Ce, Pr, Sm, Eu, Yb, Lu, Dy, Pb, and Sb and the second metal is Mo, W, V, Sn, and Sb. The material of the catalyst may have a structure according to formula (I), formula (II), formula (III), or formula (IV): where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal; where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal, and X is selected from the group consisting of SO
    4 , PO
    4 , oxalate (C
    2 O
    4 ), acetylacetonate, acetate, citrate, tartrate, Cl, Br, I, ClO
    4 , and NO3; where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal, and X is selected from the group consisting of SO
    4 , PO
    4 , oxalate (C2O
    4 ), acetylacetonate, acetate, citrate, tartrate, Cl, Br, I, ClO
    4 , and NO
    3 ; where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal, and X is selected from the group consisting of SO
    4 , PO
    4 , oxalate (C2O
    4 ), acetylacetonate, acetate, citrate, tartrate, Cl, Br, I, ClO
    4 , and NO
    3 .

    摘要翻译： 提供了用于处理含烃进料的方法，其中将包含至少20重量％重烃的含烃进料与氢气，硫化氢和催化剂混合以产生含烃产物，其中硫化氢 以相对于氢的摩尔比为至少0.5：9.5提供。 催化剂由包含第一金属和第二金属的材料组成，其中第一金属选自Cu，Fe，Ni，Co，Bi，Ag，Mn，Zn，Sn，Ru，La， Ce，Pr，Sm，Eu，Yb，Lu，Dy，Pb和Sb，第二金属为Mo，W，V，Sn和Sb。 催化剂的材料可以具有根据式（I），式（II），式（III）或式（IV）的结构：其中M是第一金属或第二金属，并且至少一个M是 第一金属和至少一个M是第二金属; 其中M是第一金属或第二金属，并且至少一个M是第一金属并且至少一个M是第二金属，并且X选自SO 4，PO 4，草酸根（C 2 O 4），乙酰丙酮，乙酸盐，柠檬酸盐，酒石酸盐，Cl，Br，I，ClO 4和NO 3; 其中M是第一金属或第二金属，并且至少一个M是第一金属并且至少一个M是第二金属，并且X选自SO 4，PO 4，草酸盐（C 2 O 4 ），乙酰丙酮，乙酸盐，柠檬酸盐，酒石酸盐，Cl，Br，I，ClO 4和NO 3; 其中M是第一金属或第二金属，并且至少一个M是第一金属并且至少一个M是第二金属，并且X选自SO 4，PO 4，草酸盐（C 2 O 4 ），乙酰丙酮酸盐，乙酸盐，柠檬酸盐，酒石酸盐，Cl，Br，I，ClO 4和NO 3。