Abstract:
The invention provides a cathodic electrocoat coating composition having (A) a polymer comprising at least one primary carbarnate group and at least one cationic salting site, (B) a curing agent having groups that are reactive with said fimetional groups on (A), and (C) a reactive additive comprising at least one compound having a 10 molecular weight of from 131 to 2000 and comprising at least one primary carbamate group and at least one alkyl group selected from the group consisting of branched alkyl groups of from 5 to 30 carbons, straight chain alkyl groups of more than 10 carbons, and mixtures thereof, wherein one or both of (A) and (B) comprise groups that are reactive with the primary carbamate group of (C).
Abstract:
The invention thus provides a curable coating composition comprising (A) a polymer resin comprising at least one primary carbamate group, (B) a curing agent having groups that are reactive with said functional groups on (A), and (C) a reactive 'additive comprising at least one compound having a molecular weight of from 131 to 10 2000 and comprising at least one primary carbonate group and at least one alkyl group selected from the group consisting of straight chain alkyl groups of more than 10 carbons, branched alkyl groups of from 5 to 30 carbons, and mixtures thereof, wherein one or both of (A) and (B) comprise groups that are reactive with the primary carbamate group of (C). The invention also provides a method of making a preferred 1 5 embodiment of the reactive additive (C) and the reactive additive (C).
Abstract:
The invention relates to a substance mixture (dual cure substance mixture) which can be cured thermally and by using actinic radiation and which comprises: A) at least one constituent which contains, with a statistical mean, at least one primary or secondary carbamate group per molecule and at least one bond that can be activated by means of actinic radiation, and which can be produced from polyfunctional compounds with at least two isocyanate-reactive, acid-reactive or epoxy-reactive functional groups and suitable monoisocyanates, monoacids or monoepoxies or from polyisocyanates, polyacids or polyepoxies and suitable compounds that have an isocyanate-reactive, acid-reactive or epoxy-reactive functional group, and; B) at least one constituent which comprises, with a statistical mean, at least one carbamate-reactive functional group per molecule and, optionally, at least one bond that can be activated by means of actinic radiation. The invention also relates to the use of said substance mixture as an adhesive, sealing compound and as a coating material.
Abstract:
The invention provides composite color-plus-clear coatings having improved appearance, especially with respect to wrinkling, and to methods and compositions for providing such coatings. The method of the invention utilizes a second coating composition comprising (A) a film forming component comprising (a) a first component comprising a compound having appended thereto at least one carbamate or urea functional group, or a group convertible to a carbamate or urea group, and (b) a second component comprising a compound reactive with said carbamate or urea groups on component (a), (B) a cyclic anhydride, and (C) a catalyst.
Abstract:
Disclosed is a composite coating, comprising a substrate; one or more primer coating layers disposed on said substrate; and at least one topcoat layer disposed on the outermost primer coating layer, wherein said outermost primer coating layer is obtained by reaction of a primer composition comprising an acrylic or novolac resin having primary carbamate functionality and an aminoplast resin. Also claimed is a coating composition comprising a carbamate functional resin and an aminoplast corsslinker.
Abstract:
A method for reducing the molecular weight of aminoplast compounds, the aminoplast compounds obtained thereby, and coating compositions containing said aminoplast compounds are provided. The reduced molecular weight aminoplasts are obtained by reacting (a) an aminoplast compound, having a total number (y) of reactive substituents on the amino nitrogens of the aminoplast, where y= (E x M) and E = equivalents per mole of aminoplast and M= total number of moles of aminoplast, wherein the reactive substituents are selected from the group consisting of -NH, alkylol, alkoxy, alkoxyalkyl, and mixtures thereof and (b) at least one carbamate compound selected from the group consisting of unsubstituted and substituted primary carbamate compounds, unsubstituted and substituted secondary carbamate compounds and mixtures thereof, in the presence of primary or secondary alcohols, at temperatures under 150 DEG C, and at pressures ranging between atmospheric pressure and 20 atm pressure, to form a functionalized aminoplast compound, wherein at least one and up to (y-1) of the amino substituents on the aminoplast are substituted with the carbamate functionality.