摘要:
An initiator-free composition is prepared of an ethylenically unsaturated monomer and the inhibitor parabenzoquinone or hydroquinone. The composition is irradiated with light having a wavelength within the absorption spectrum of the inhibitor, other than ultravioiet. The light causes the inhibitor to produce a reactive species which initiates polymerization.
摘要:
Provided is a hollow resin particle that has a shell portion and a hollow portion surrounded by the shell portion and that can achieve reductions in dielectricity and dielectric loss tangent and can exhibit excellent heat resistance. In addition, a method for producing such a hollow resin particle in a simple manner is provided. Furthermore, use of such a hollow resin particle is provided. A hollow resin particle according to an embodiment of the present invention is a hollow resin particle including a shell portion and a hollow portion surrounded by the shell portion, wherein the shell portion has an ether structure represented by formula (1).
摘要:
To provide hollow particles excellent in performance stability in a high-humidity environment and low in relative permittivity. Hollow particles which comprise a shell containing a resin and a hollow portion surrounded by the shell, wherein the shell contains, as the resin, a polymer in which from 70 parts by mass to 100 parts by mass of a crosslinkable monomer unit is contained in 100 parts by mass of all monomer units; wherein a void ratio is 60% or more; wherein a content of a surfactant present on a surface of the hollow particles is 200 ppm or less; and wherein a relative permittivity at a frequency of 1 MHz is 1.6 or less.
摘要:
The purpose of the present invention is to achieve a composition for forming a low dielectric constant resin which is suitable for use in a substrate for radar, next-generation communication devices and the like using higher frequencies, while having high heat dissipation properties. The present invention enables the achievement of a polymerizable composition, which is able to be molded by a solution process, while exhibiting thermal conductivity and low dielectric properties lower than those of conventional liquid crystal polymers, by curing a polymerizable polycyclic compound that has less conjugates or polar groups, while exhibiting higher linearity or symmetry of each molecule.
摘要:
An object of the present invention is to provide a resin composition for stereolithography that can reduce generation of color unevenness and provide excellent formability. The present invention has achieved this object by providing a resin composition for stereolithography including an ultraviolet curable resin (A) and an inorganic pigment (B) that are blended, in which the inorganic pigment (B) has a specific gravity of 2.0 ≤ ρ and a particle size distribution of a particle diameter of D50 ≤ 5 µm and D90 ≤ 20 um, and a viscosity of the resin composition for stereolithography at 25°C is 100 Pa·s or more.
摘要:
Hollow particles which comprise a shell containing a resin and a hollow portion surrounded by the shell and which have a void ratio of 50% or more, wherein the shell contains, as the resin, a polymer in which 70 parts by mass to 100 parts by mass of a crosslinkable monomer unit is contained in 100 parts by mass of all monomer units, and wherein, in a hollow particle immersion test in which a mixture obtained by adding 0.1 mg of the hollow particles to 4 mL of acetone and shaking them for 10 minutes at a shaking rate of 100 rpm, is left to stand for 48 hours in an environment at 25°C, less than 5% by mass of the hollow particles submerge in the acetone.
摘要:
The present invention relates to a thiol-modified polymer compound, and a preparation method therefor and an application thereof. In the present invention, a polymer compound modified by an acryloyl derivative and a polythiol compound are used for preparing a thiol-modified polymer compound by a Michael addition reaction of thiol and conjugated double bonds. In addition to achieving the structural goal of the thiol-modified polymer compound provided in the present invention, the preparation method further has the following advantages: flexibly and effectively controlling the structure and constitution of a synthetic product, and the types and contents of a large number of compound molecular functional groups; using reagents having high biocompatibility, and effectively controlling the production cost and reducing the toxicity in the synthesis process; and obtaining, under the conditions of using safety reagents and simple reaction steps, thiol-modified biocompatible polymer compounds that can be used as extracellular matrix materials and maintain good raw material structure and biological activity, with the types and contents of functional groups adjusted according to requirements, and meeting multiple clinical application requirements.