Abstract:
To provide a powder coating material capable of forming a coating film that is excellent in weather resistance, processability and impact resistance and that improves corrosion resistance of a substrate (in particular, a substrate made of aluminum or of an aluminum alloy). A powder coating material comprising a powder of a resin composition, wherein the resin composition comprises a fluorinated polymer (A) having a number average molecular weight of from 10,000 to 50,000 and a fluorine content of at least 10 mass%, a resin (B) having a fluorine content of less than 10 mass% or containing no fluorine atom, a curing agent, a plasticizer having a melting point of from 50 to 150°C and core-shell particles, and wherein the absolute value of the difference between the melting point of the plasticizer and the glass transition temperature of a polymer of a shell portion in the core-shell particles is within 30°C and the content of the plasticizer is from 5 to 25 parts by mass based on 100 parts by mass of the fluorinated polymer (A).
Abstract:
The invention provides a coating material capable of forming a film that is free of squeakiness and is less likely to suffer staining of clothing dye on the surface of a base such as a rubber molded article. The coating material of the invention contains fluororesin primary particles having an average particle size of 0.2 to 200 nm, a curable silicone resin in an amount of 0.1 to 250 mass% relative to the fluororesin primary particles, and water.
Abstract:
A composition for solid coating formation, includes a composition made by containing, in a mixed solvent including water and a dipolar aprotic solvent, a powdery organic resin which is partially soluble at least in the dipolar aprotic solvent. The powdery organic resin is present in a state of being dissolved or dispersed in the mixed solvent.
Abstract:
To provide a process for producing a powder coating material capable of forming a cured film which is excellent in weather resistance and which has few voids (gaps); a coated article having a cured film which is excellent in weather resistance and which has few voids; and a method for producing a carboxy group-containing fluororesin less susceptible to gelation. A process for producing a powder coating material containing a powder (X) composed of a composition (±) comprising a fluororesin (A) having carboxy groups, or alkoxysilyl groups and urethane bonds, and a curing agent (D), said process comprising (a) a step of melt-kneading a mixture comprising a hydroxy group-containing fluororesin (B), an acid anhydride (C1) or a compound (C2) having an alkoxysilyl group and an isocyanate group, and the curing agent (D), to obtain a kneaded product composed of the composition (±), and (b) a step of pulverizing the kneaded product to obtain the powder (X).
Abstract:
To provide a process for producing a powder coating material capable of forming a cured film which is excellent in weather resistance and which has few voids (gaps); a coated article having a cured film which is excellent in weather resistance and which has few voids; and a method for producing a carboxy group-containing fluororesin less susceptible to gelation. A process for producing a powder coating material containing a powder (X) composed of a composition (α) comprising a fluororesin (A) having carboxy groups, or alkoxysilyl groups and urethane bonds, and a curing agent (D), said process comprising (a) a step of melt-kneading a mixture comprising a hydroxy group-containing fluororesin (B), an acid anhydride (C1) or a compound (C2) having an alkoxysilyl group and an isocyanate group, and the curing agent (D), to obtain a kneaded product composed of the composition (α), and (b) a step of pulverizing the kneaded product to obtain the powder (X).
Abstract:
A composition for solid coating formation, includes a composition made by containing, in a mixed solvent including water and a dipolar aprotic solvent, a powdery organic resin which is partially soluble at least in the dipolar aprotic solvent. The powdery organic resin is present in a state of being dissolved or dispersed in the mixed solvent.
Abstract:
A composition for solid coating formation, includes a composition made by containing, in a mixed solvent including water and a dipolar aprotic solvent, a powdery organic resin which is partially soluble at least in the dipolar aprotic solvent. The powdery organic resin is present in a state of being dissolved or dispersed in the mixed solvent.