摘要:
A process for producing a halogenated β-lactam compound represented by general formula (4), characterized by reacting a β-lactam-derived amino compound represented by general formula (1) with nitrous acid or a nitrite in the presence of halogen molecules under acid conditions while keeping the reactants in an aqueous slurry state to obtain the target compound. In formula (1) n is an integer of 0 to 2; and A represents formula (2) or (3), wherein R?1 and R2¿ are the same or different and each is hydrogen, halogeno, C¿1-3? alkyl, C2-4 alkenyl, C2-4 alkynyl, a nucleophilic group, or CH2R?3¿, where R3 represents halogeno or a nucleophilic group. In formula (4) A is the same as the above; X1 represents hydrogen or halogeno; and X2 represents halogeno.
摘要:
A manganese complex represented by the formula (1): [Mn(H2NNHCONH2)3](NO3)2 which has a weight loss of at most 1 % after being heated at 107 DEG C for 400 hr. The manganese complex possesses an excellent heat stability and can be used as an active ingredient of a gas generator for an air bag. The gas generator contains the above manganese complex. When the manganese complex is incorporated in the form of a complex mixture thereof with a semicarbazide and/or a carbohydrazide into the gas generator, the gas generator has such a characteristic that the content of the combustion residue in an inflator is high.
摘要:
A gas generator for air bags comprising (1) biscarbamoylhydrazine as a base of the generator, (2) a salt of oxoacid of halogen as an oxidizing agent, (3) a nitrate as another oxidizing agent, and (4) a combustion catalyst as the active ingredients. This generator has a proper combustion performance and a low combustion temperature, generates a gas lowered in the content of toxic components such as CO and NOx and that of emitted suspended particles, is excellent in heat stability, and is preferably far superior to azide and non-azide gas generators of prior art in safeness.
摘要:
A gas generating agent for air bags, which has such favorable characteritics as moderate combustion performances, a low combustion temperature, a reduced content of toxic components, such as CO and NOx, in the gas formed by the combustion, and a higher safety than that of conventional azide-based gas generating agents. The agent comprises at least one gas generating base selected among urazole and metal salts thereof and an oxidizing agent as the active ingredients.
摘要:
A process for producing a 2-isocephem derivative which comprises treating, in a water-containing organic solvent, a 2-azetidinyl-3,4-dihalogeno-2-butenoic acid compound represented by general formula (1) with a thioacetic acid derivative showing basicity per se or a mixture of a base with a thioacetic acid derivative to thereby give a 3-halomethyl-2-isocephem derivative represented by general formula (2); and a process for producing a 2-oxaisocephem derivative which comprises treating, in a water-containing organic solvent, a 2-azetidinyl-3,4-dihalogeno-2-butenoic acid compound represented by general formula (1) with a base to thereby give a 3-halomethyl-2-oxaisocephem derivative represented by general formula (3); in formula (1), R1 represents hydrogen or optionally protected amino; R2 represents hydrogen or lower alkoxy, or R?1 and R2¿ may form together a cyclic amino protecting group; R3 represents hydrogen or a carboxyl protecting group; W represents a leaving group; and X and Y may be the same or different and each represents halogeno; in formula (2), R?1, R2, R3¿ and X are each as defined above; in formula (3), R?1, R2, R3¿ and X are each as defined above.
摘要:
A flame-retardant epoxy resin composition excellent in heat resistance and moist resistance. It is characterized in that it comprises (A) an epoxy resin, (B) a phosphazene compound, (C) an epoxy hardener, and (D) an inorganic filler, that the amounts of the ingredients (B) and (C) are 0.01 to 70 wt.% and 0 to 70 wt.%, respectively, based on the sum of the ingredients (A), (B), and (C) and the amount of the ingredient (D) is 0 to 95 wt.% based on the sum of the ingredients (A), (B), (C), and (D), and that the ingredient (B) is at least one member selected from the group consisting of (1) a cyclic and/or chain phosphazene compound having a specific structure, (2) a polymer of the cyclic and/or chain phosphazene compound, and (3) a product of the reaction of the cyclic and/or chain phosphazene compound with at least one compound selected among epoxy compounds, phenol compounds, amine compounds, and acid anhydrides.
摘要:
An electroconductive fiber comprising a fibrous core material whose surface is coated with an electroconductive substance, the fibrous core material having an average fiber length of 1 to 5 mu m, an average fiber diameter of 0.01 to 0.5 mu m and an aspect ratio of 3 or more, electroconductive resin composition containg the electroconductive fibers, and electroconductive thread prepared by spinning the electroconductive resin composition.
摘要:
A process for producing a treated part made of magnesium and/or a magnesium alloy, characterized by treating a part made of magnesium and/or a magnesium alloy with (A) a surface-treating agent containing a phosphoric acid salt, subsequently treating it with (B) a rust-preventive pretreating agent, optionally further treating the part with (C) a detergent containing a surfactant and at least one member selected among aromatic carboxylic acids and salts of these, and then optionally treating the part with (D) a rust preventive for magnesium.
摘要:
A hardener for epoxy resins which comprises as the active ingredients a compound represented by formula (1): NH2N(R )(R ); or salt thereof and an amine compound or salt thereof, characterized in that at least either of the compound represented by formula (1) and the amine compound is a thiocyanate; and an epoxy resin composition containing the hardener. (In the formula, R and R are the same or different and each represents C1-8 alkyl, aryl, or a nitrogenous heterocyclic group or R and R are bonded together to form C2-11 alkylene or a group represented by R -R -R -, wherein R and R are the same or different and each represents C1-8 alkylene and R represents oxygen, sulfur, or a group represented by =NR or =NNH2, provided that R represents hydrogen or C1-8 alkyl.)
摘要:
3-Halogenomethylcephem compounds represented by general formula (2) or salts thereof, produced by reacting a 7-amino-3-halogenomethylcephem compound represented by general formula (1) or a salt thereof with a phenol derivative to remove the 4-position carboxy-protective group; and 3-thiomethylcephem compounds represented by general formula (4) or salts thereof, produced by reacting the 3-halogenomethylcephem compound represented by formula (2) or its salt with either a thiol compound represented by general formula (3): R2S-M or a salt thereof, wherein X?1, R1, R2¿, and M are each as defined in the description.