摘要:
A nitrogen oxide removing catalyst for removing nitrogen oxides from an exhaust gas is prevented from being poisoned by a phosphorous compound included in the exhaust gas. A nitrogen oxide removing catalyst superior in durability and a method of removing nitrogen oxides are provided. A porous material having fine holes with controlled diameters and a catalyst having an active ingredient supported in the fine holes in the porous material are used. A first invention is characterized in that the diameter of the plurality of fine holes is within a range of 8 to 9 Å. The fine hole diameter is preferably from 8 to 9 Å when the diameter is measured in a gas adsorption method in which fine holes with diameters of 3.4 to 14 Å can be measured. The fine hole diameter is also preferably from 8 to 9 Å when the fine hole diameter is calculated from a crystal structure. A second invention is characterized in that the porous material is mesoporous silica. The primary particle diameter of the mesoporous silica is preferably within a range of 150 to 300 nm.
摘要:
An absorbing tower (4) is provided in its side wall with a gas entrance (3) for introducing a combustion exhaust gas into the absorbing tower, and an absorbing liquid is sprayed from the nozzles (8a) of a spray header (8) into the exhaust gas (1) introduced to rise from the gas entrance (3). A trough (23) is arranged in the side wall of the absorbing tower (4) and above the gas entrance (3), and a nose (22) having a horseshoe shape in a top plan view and extending into tower is disposed in the tower side wall portion of the gas entrance (3) other than the portion arranging the trough (23) and at the same or at substantially the same height as the portion of the trough (23). The absorbing liquid, which is sprayed from the nozzle (8a) and drops along the absorbing tower wall portion, is rescattered to the center portion of the absorbing tower excepting the entrance of the absorbing tower, so that the gas-liquid contact efficiency is improved while suppressing an increase in pressure loss, thereby to prevent the drift of the gas at the tower wall portion.
摘要:
Tertiary nozzle (3) of port (31) for gas injection into furnace (34) comprising a contracted flow producing channel provided obliquely toward central axis (C) from the upstream side of gas flow so that the gas flow has a velocity component heading from the outer circumferential side of the port (31) toward the central axis (C) and a velocity component heading along the central axis (C) toward the interior of the furnace, and comprising louver (32) disposed for guiding so that the gas flows along the surface of throat wall (26) of enlarged pipe configuration wherein the gas channel is enlarged at a furnace wall opening disposed at an outlet area of the contracted flow producing channel. Accordingly, there can be provided a gas injection port that not depending on conditions, such as the flow rate of gas injected from the port, without inviting any complication of apparatus structuring or cost increase, enables preventing of the growth in lump form of clinker caused by ash adhesion and fusion on the wall surface of throat enlarged pipe portion of the furnace.
摘要:
A cylinder-shaped flow passage (11) in which a first fluid (1) flows includes an internal cylinder (13) which is smaller in diameter than the flow passage (11). A swirl-generating stator (15) having four vanes is radially fixed in the internal cylinder (13). A header space for supplying a second fluid (2) is provided to the outer circumference of a wall surface of the internal cylinder (13) in contact with flow separation areas which are formed along downstream surfaces of the swirl-generating stator (15) as the first fluid (1) runs into the swirl-generating stator (15). The wall surface of the internal cylinder (13) is formed with openings (16) through which the flow separation areas communicate with the header space. The second fluid (2) supplied into the header space flows through the openings (16) into the flow separation areas, and is diffused along the vanes of the swirl-generating stator (15) to be swirled and mixed into the first fluid (1) applied with swirling force by the swirl-generating stator (15).
摘要:
The pulverized coal burner suitable for lowering the concentration of nitrogen comprises a pulverized coal nozzle (10) for jetting a mixture of pulverized coal and primary air, a secondary air nozzle (11) and a tertiary air nozzle (12), concentrically arranged around the outer periphery of the pulverized coal nozzle (10), and a tube expanded portion (20) at the end of a partition wall separating two adjacent air nozzles. A flow shift means for shifting the secondary air in the secondary air nozzle so as to flow along the tube expanded portion, for example a guide plate (30), is provided. The secondary air comes to be jetted outward by the guide plate, and mixing of the secondary air and the tertiary air with pulverized coals is delayed, whereby an amount of occurrence of NOx can be decreased. The guide plate (61) is a ring disposed in an outlet region of the secondary air nozzle (11), which ring has a taper-shaped ring portion for guiding a part of the secondary air (52) in a radially outward direction.
摘要:
An object is to provide a pulverized coal combustion burner and a combustion method by the burner in which occurrence of NOx is small and unburnt carbons in combustion ashes are small. In a combustion method by a pulverized coal combustion burner which is provided with a pulverized coal nozzle (10) for injecting a mixture (13) of pulverized coal and air and an air nozzle (11) for injecting air (14), a combustion flame formed by the above-mentioned pulverized coal combustion burner forms a zone (17) of gas phase air ratio of 1 or less at a radially central portion of the flame and a zone (16) of gas phase air ratio of more than 1 outside the zone, in the vicinity of the burner jet port, and a zone of gas phase air ratio of 1 or less in the downstream side of the flame.
摘要:
Areliable and cost-effective boiler equipped with a sound air supply nozzle which enables the following is provided: even when there is a gap between the nozzle provided in a through hole communicating with the interior of a furnace and the through hole, a strong swirl flow along the inner surface of the furnace wall can be formed; and burnout due to radiant heat can be suppressed. The air supply nozzle has the through hole in the furnace wall comprised of a water pipe, the nozzle supplying air is inserted into the through hole, and there is the gap between the nozzle and the through hole. The air supply nozzle is so configured that the position of the tip of the nozzle is located at a distance of 0.8 times the nozzle inside diameter or more away from the furnace wall inner surface and a tangential velocity component is given to gas jetting out of the nozzle.
摘要:
Exhaust (Flue) gas of boiler is introduced through gas inlet part (port) (2) of flue-gas desulfurization apparatus (system), and absorbent liquid sprayed from spray nozzle (5) of absorbent liquid spray section (4) is trapped (stored) in liquid trapping (recirculation tank) section (7). There, agitation is performed by means of propeller (11) of oxidation agitator (8) to thereby oxidize SO 2 absorbed from the exhaust (flue) gas into gypsum. In the liquid trapping section (7), oxidation air is fed from posterior air pipe (10) and anterior air pipe (13) behind and ahead of liquid propulsion (to the rear and front of a liquid discharge) by the propeller (11). Thus, even when the amount of oxidation air must be increased in accordance with an increase of boiler load, the oxidation efficiency can be enhanced without increasing of the number of agitators. Accordingly, there can be provided a wet flue-gas desulfurization apparatus (system) and method with which even when the amount of oxidation air fed to the liquid trapping section is increased, highly efficient oxidation can be performed without increasing the number of agitators installed and the operating cost.
摘要:
A denitration catalyst for use in the reduction of nitrogen oxides contained in an exhaust gas containing highly deliquescent salts as dust with ammonia, which bears thereon a porous coating of a water-repellent organic resin, a porous coating of a mixture of a water-repellent organic resin with inorganic oxide particles, or a porous coating of a mixture of a water-repellent organic resin with catalyst component particles. The denitration catalyst can be prepared, for example, by coating the surface of a denitration catalyst with an aqueous dispersion containing a water-repellent organic resin having a lower concentration, drying the coating, further coating the dried coating with an aqueous dispersion containing a water-repellent organic resin having a higher concentration, and then drying the coating to form a porous coating of a water-repellent organic resin. This denitration catalyst, even when used in the treatment of an exhaust gas containing ash containing highly deliquescent salts, enables the water-repellent porous coating formed on the surface to prevent the salts that have deliquesced from entering the catalyst. This can prevent the deterioration of the catalyst and enables a high catalytic activity to be maintained for a long period of time.