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    Fluorinated supramolecular polymers
    1.
    发明授权
    Fluorinated supramolecular polymers 有权

    公开(公告)号：EP2457940B1

    公开(公告)日：2018-10-24

    申请号：EP10192326.6

    申请日：2010-11-24

    申请人： SupraPolix B.V.

    发明人： Bosman, Anton Willem

    IPC分类号： C08G65/00 ,  C08G18/00 ,  C07D239/47 ,  C08G63/00

    CPC分类号： C08G83/008

    摘要： The present invention relates to a fluorinated supramolecular polymer containing at least 5% by weight of covalently bonded fluorine atoms, based on the total weight of the fluorinated supramolecular polymer, said fluorinated supramolecular polymer comprising a fluorinated polymer chain and a (self-)complementary unit capable of forming at least three hydrogen bonds, said (self-)complementary unit being covalently bonded to said fluorinated polymer chain. The present invention also relates fluorinated supramolecular material comprising (a) a fluorinated supramolecular polymer and (c) a non-fluorinated polymer and/or (d) a fluorinated compound, the non-fluorinated polymer being a polymer containing less than 5% by weight of covalently bonded fluorine atoms, based on the total weight of the non-fluorinated polymer, and the fluorinated compound being either a low molecular weight fluorinated compound comprising at least one fluorine atom and having a molecular weight of 34.(molecular weight of CH 3 F) to 600 atomic mass units (amu), or a fluoropolymer containing at least 5% by weight of covalently bonded fluorine atoms, based on the total weight of the fluoropolymer and having a M n from about 600 to about 5000.

    Supramolecular polymers containing quadruple hydrogen bonding units in the polymer backbone
    7.
    发明公开
    Supramolecular polymers containing quadruple hydrogen bonding units in the polymer backbone 有权
    SUPRAMOLEKULARE聚合物麻醉剂WERERSTOFFBRÜCKENBINDUNGENBILDENDEN EINHEITEN IN DER POLYMERHAUPTKETTE

    公开(公告)号：EP2267062A1

    公开(公告)日：2010-12-29

    申请号：EP10177273.9

    申请日：2003-11-04

    申请人： SupraPolix B.V.

    发明人： Janssen, Henricus Marie ,  Hoorne - van Gemert, Gaby Maria Leonarda ,  Meijer, Egbert Willem ,  Bosman, Anton Willem

    IPC分类号： C08G83/00 ,  C08G18/10 ,  C08G18/32 ,  C08G18/42 ,  C08G18/48 ,  C08G18/71 ,  C08L101/02

    CPC分类号： C08G83/008 ,  A61K8/87 ,  A61Q19/00 ,  B33Y70/00 ,  C08G18/3293 ,  C08G18/4202 ,  C08G18/4277 ,  C08G18/4837 ,  C08G18/714

    摘要： The present invention relates to a supramolecular polymer comprising quadruple hydrogen bonding units 4H within the polymer backbone, said supramolecular polymer being obtainable by reacting a monomeric unit (a) having the structure 4H* - (F i ) r (IV) and a macromonomeric unit (b) having the structure P-(F i ) s , wherein the monomeric unit (a) is represented by formula (VIIa) or (VIIb), and tautomers and/or enantiomers thereof:

    wherein 4H* represents a precursor of the structural element 4H; in formula (IV), F i represents a reactive group linked to the 4H*-unit; r = 2, so that formula (IV) is represented by F 1 -4H*-F 1 or by F 1 -4H*-F 2 ; the 4H*-unit is connected to a reactive group (F 1 ) via R1 and to a reactive group (F 1 ) or (F 2 ) via R3, whereas R2 is a random side chain or a hydrogen atom; P represents a polymer chain; in formula (V), F i represents a complementary reactive group in the macromonomeric unit (b) that is complementary reactive with another F i of monomeric unit (a); and s = 2 - 6.

    摘要翻译： 本发明涉及一种超分子聚合物，其包括聚合物主链内的四重氢键单元4H，所述超分子聚合物可通过使具有4H * - （F i）r（IV）结构的单体单元（a）和大分子单元 （b）具有结构P-（F i）s，其中单体单元（a）由式（VIIa）或（VIIb）表示，及其互变异构体和/或对映异构体：其中4H *表示结构 元素4H; 在式（IV）中，F i表示与4H * - 单元连接的反应性基团; r = 2，使式（IV）由F 1 -4H * -F 1或F 1 -4H * -F 2表示; 4H *单元通过R 1与反应性基团（F 1）连接，经由R 3连接到反应性基团（F 1）或（F 2），而R 2是无规侧链或氢原子; P表示聚合物链; 在式（V）中，F i表示与单体单元（a）的另一F i互补的大分子单体（b）中的互补反应性基团。 s = 2-6。