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公开(公告)号：EP1523467B1
公开(公告)日：2007-11-14
申请号：EP03763838.4
申请日：2003-07-14
发明人： GÖBBEL, Hans-Georg , KAIBEL, Gerd , MILLER, Christian , DOBLER, Walter , DIRNSTEINER, Thomas , HAHN, Thilo , BREUER, Klaus , AQUILA, Werner
摘要： A method for the production of tetrahydrogeranylacetone is disclosed, whereby pseudoionone, geranylacetone and/or dihydrogeranylacetone in the liquid phase, in which particles of a catalyst, for the preferential hydrogenation of carbon-carbon double bonds before carbon-oxygen double bonds, are suspended, is fed through a device along in the presence of a gas comprising hydrogen, said device preventing the transport of the catalyst particles.
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公开(公告)号：EP1523467A1
公开(公告)日：2005-04-20
申请号：EP03763838.4
申请日：2003-07-14
发明人： GÖBBEL, Hans-Georg , KAIBEL, Gerd , MILLER, Christian , DOBLER, Walter , DIRNSTEINER, Thomas , HAHN, Thilo , BREUER, Klaus , AQUILA, Werner
摘要： A method for the production of tetrahydrogeranylacetone is disclosed, whereby pseudoionone, geranylacetone and/or dihydrogeranylacetone in the liquid phase, in which particles of a catalyst, for the preferential hydrogenation of carbon-carbon double bonds before carbon-oxygen double bonds, are suspended, is fed through a device along in the presence of a gas comprising hydrogen, said device preventing the transport of the catalyst particles.
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3.发明公开VERFAHREN ZUR KONTINUIERLICHEN ACYLIERUNG VON CHROMANOLESTERDERIVATEN 有权方法CHROMANOLESTERDERIVATEN的不断酰化
公开(公告)号：EP1339704A1
公开(公告)日：2003-09-03
申请号：EP01989492.2
申请日：2001-11-21
发明人： OOST, Carsten , KAIBEL, Gerd , LAAS, Harald , SCHMITT, Peter , VON ERDEN, Jens
IPC分类号： C07D311/72
CPC分类号： C07D311/72 , B01D1/22 , B01D3/009 , B01D3/146 , B01D3/322 , Y02P20/127
摘要： The invention relates to a method for continuously producing chromanol ester derivatives, particularly for continuously producing carboxylic acid esters of tocopherols and tocotrienols, by carrying out a continuous acylation with carboxylic acids or carboxylic acid anhydrides.
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4.发明公开
公开(公告)号：EP1330422A2
公开(公告)日：2003-07-30
申请号：EP01986667.2
申请日：2001-10-09
CPC分类号： C07C209/72 , B01J23/40 , B01J23/462 , B01J23/56 , B01J35/04 , B01J37/0225 , C07B35/02 , C07C5/10 , C07C2521/06 , C07C2521/10 , C07C2521/18 , C07C2523/02 , C07C2523/10 , C07C2523/30 , C07C2523/46 , C07C2601/14 , C07C211/35
摘要： The invention relates to a method for the hydrogenation of unsubstituted or at least monoalkyl substituted uni- or poly-nuclear aromatics by means of bringing the above at least one aromatic into contact with a gas containing hydrogen, in the presence of a catalyst comprising at least one metal of sub-group VIII of the periodic system as active metal, supported on a structured or monolithic support.
摘要翻译： 一种用于单环或多环芳族的氢化哪个可以是由至少一个aikyi组unsubstituiertem或substituiertem方法包括使芳族成在催化剂的存在下与含氢气体接触，其包括第VIII过渡族的至少一种金属 周期表中的作为活性金属适用于结构化的或整体式载体。
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5.发明公开VERFAHREN ZUR DESTILLATIVEN TRENNUNG VON TETRAHYDROFURAN, $G(G)-BUTYROLACTON UND/ODER 1,4-BUTANDIOL ENTHALTENDEN GEMISCHEN 无效PROCESS FOR蒸馏四氢呋喃，γ-丁内酯和/或1,4-含有丁二醇的混合物的分离
公开(公告)号：EP1280787A1
公开(公告)日：2003-02-05
申请号：EP01951476.9
申请日：2001-05-03
发明人： KAIBEL, Gerd , WECK, Alexander , RAHN, Ralf-Thomas
IPC分类号： C07D307/08 , C07D307/33 , C07C29/80
CPC分类号： C07D307/33 , B01D3/14 , B01D3/141 , B01D3/146 , C07C29/80 , C07D307/08 , Y10S203/09 , Y10S203/20 , C07C31/207
摘要： The invention relates to a method for continuos distillative separation of mixtures containing tetrahydrofuran, η-butyrolactone and/or 1,4-butanediol into at least three fractions, wherein separation is carried out in an array of distillation columns containing at least one dividing wall column or at least one array of thermally-coupled conventional distillation columns.
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公开(公告)号：EP1073620A1
公开(公告)日：2001-02-07
申请号：EP99920693.1
申请日：1999-04-16
发明人： FISCHER, Rolf , KAIBEL, Gerd , PINKOS, Rolf , RAHN, Ralf-Thomas
IPC分类号： C07C51/16 , C07C67/03 , C07C69/60 , C07C29/17 , C07D307/08 , C07D307/32
CPC分类号： C07D315/00 , C07C29/177 , C07D307/08 , C07C31/207
摘要： The invention relates to a method for producing 1,4-butanediol and possibly η-butyrolactone and tetrahydrofurane by oxidation of butane or benzol into a product flow containing maleic anhydride, absorption of maleic anhydride from the product flow by means of an inert, high-boiling solvent in an absorption stage, which yields a liquid absorption product, and esterification of said liquid absorption product with a C1-C5 esterification alcohol in an esterification step, yielding an esterification product containing the corresponding diester and high-boiling inert solvent. This is followed by hydrogenation of the esterification product, which results in an hydrogenation product containing the products 1,4-butanediol and optionally η-butyrolactone and tetrahydrofurane as well as the esterification alcohol. The hydrogenation product is separated by distillation into the products and the esterification alcohol and the esterification alcohol is returned to the esterification zone. Prior to hydrogenation the esterification product is separated by distillation under reduced pressured into the diester and the inert solvent, the inert solvent is returned to the absorption stage and the diester is hydrogenated in the liquid phase on a fixed-bed catalyst.
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7.发明公开VERFAHREN ZUR HYDRIERUNG VON AROMATISCHEN VERBINDUNGEN MIT RESTGAS ENTHALTENDEM WASSERSTOFF 有权PROCESS加氢芳香化合物与REST含氢气体的
公开(公告)号：EP1412310A1
公开(公告)日：2004-04-28
申请号：EP02764727.0
申请日：2002-07-18
发明人： BÖTTCHER, Arnd , SCHWAB, Ekkehard , KÄSTNER, Ralf , HENKELMANN, Jochem , KAIBEL, Gerd , LAIB, Heinrich
CPC分类号： C07C5/10 , C07C2521/04 , C07C2523/46 , C07C13/18
摘要： The invention relates to a method for hydrogenating substituted or 5 unsubstituted mononuclear or multinuclear aromatics to form corresponding cycloaliphatics, especially benzole to form cyclohexane, by bringing the aromatic into contact with a gas containing hydrogen in the presence of a catalyst, using hydrogen containing residual gases.
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8.发明公开VERFAHREN ZUR HERSTELLUNG VON CYCLOHEXANDICARBONSÄUREN UND DEREN DERIVATEN 有权VERFAHREN ZUR HERSTELLUNG VONCYCLOHEXANDICARBONSÄURENUND DEREN DERIVATEN
公开(公告)号：EP1363868A1
公开(公告)日：2003-11-26
申请号：EP02701282.2
申请日：2002-02-15
发明人： NOE, Ralf , HIBST, Hartmut , HALBRITTER, Klaus , MAAS-BRUNNER, Melanie , BREITSCHEIDEL, Boris , KAIBEL, Gerd , MASSONNE, Klemens , SALDEN, Axel , EBEL, Klaus , BERGNER, Eike, Johannes , HAESE, Frank
IPC分类号： C07C51/567 , C07C67/303 , C07C67/08 , C08K5/09
CPC分类号： C08K5/12 , C07C67/08 , C07C2601/14 , C07C69/75
摘要： The invention relates to a method for producing cyclohexane dicarboxylic acids or derivatives thereof, e.g esters and anhydrides, wherein diene maleic acid anhydride mixtures, especially mixtures of butadiene maleic acid anhydrides or mixtures of maleic acid anhydride and C5 dienes, are reacted to form alkyl substituted or unsubstituted cyclohexene dicarboxylic acid anhydrides in a condensed phase; esters are formed and hydrogenation is carried out to obtain a corresponding cyclohexane dicarboxylic acid derivative. The invention also relates to the use of cyclohexane dicarboxylic acids or derivatives produced according to the inventive method as softeners for plastics. .
摘要翻译： 本发明涉及一种制备环己烷二羧酸或其衍生物的方法，例如酯和/或酸酐，其包括二烯/马来酸酐混合物，特别是丁二烯/马来酸酐混合物或马来酸酐混合物的反应和 C5-二烯，在缩合相中得到烷基取代或未取代的环己烯二羧酸酐，酯形成，然后氢化得到相应的环己烷二羧酸衍生物，以及使用根据本发明制备的环己烷二羧酸或其衍生物作为 塑料增塑剂
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公开(公告)号：EP1242345A1
公开(公告)日：2002-09-25
申请号：EP00990689.2
申请日：2000-12-08
发明人： GUTH, Josef , FRIEDRICH, Holger , STERZEL, Hans-Josef , KAIBEL, Gerd , BURKART, Kirsten , HOFFMANN, Elke
CPC分类号： B01D3/141 , B01D1/2856 , C07C29/70 , C07C31/30
摘要： The invention relates to a method for producing alkali methylates from an aqueous alkaline lye that is optionally mixed with methanol and methanol in a reaction column, said column comprising at least 5, preferably 15 to 30 theoretical trays between the inlet of the alkaline lye and the site of addition of the methanol. According to the inventive method, the vapor methanol-water mixture formed during the reaction is separated in a reaction column. According to an embodiment of the invention, the reaction column that is configured as a bubble-tray, valve-tray or sieve-plate column is provided with trays, each letting through maximally 5 %, preferably ≤ 1 % of the liquid. In another embodiment of the invention, the reaction column that is provided with a double jacket is configured as a column that is filled with fillers or oriented packings at a temperature in the double jacket that is 3 to 10 °C higher than the temperature in the inner of the column. In all sections of the column diameter that correspond to more than 2 % of the total column diameter, the average ratio of the liquid flow to the vapor flow with respect to the liquid is not exceeded by more than 15 %, preferably by not more than 3 %.
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10.发明授权VERFAHREN ZUR OXIDATION EINER MINDESTENS EINE C-C-DOPPELBINDUNG AUFWEISENDEN ORGANISCHEN VERBINDUNG 失效过程对于至少一个C-C双键氧化在含有有机化合物
公开(公告)号：EP0986526B1
公开(公告)日：2002-01-30
申请号：EP98929426.9
申请日：1998-06-05
发明人： GROSCH, Georg, Heinrich , MÜLLER, Ulrich , WALCH, Andreas , RIEBER, Norbert , FISCHER, Martin , QUAISER, Stefan , HARDER, Wolfgang , ELLER, Karsten , BASSLER, Peter , WENZEL, Anne , KAIBEL, Gerd , STAMMER, Achim , HENKELMANN, Jochem , BÖTTCHER, Arnd , TELES, Joaquim, Henrique , SCHULZ, Michael , TREIBER, Gert
IPC分类号： C07B41/00 , C07D301/12 , C07D301/19
CPC分类号： C07D301/19 , B01J29/90 , B01J38/14 , C07B41/00 , C07D301/12 , Y02P20/584
摘要： The invention relates to a method for oxidizing an organic compound containing at least one C-C double bond or a mixture of two or more thereof, comprising the following steps: (I) production of a hydroperoxide; (II) reaction of an organic compound containing at least one C-C double bond or a mixture of two or more thereof with the hydroperoxide produced in step (I) in the presence of a zeolitic catalyst; (III) regeneration of the at least partially deactivated zeolitic catalyst used in step (II) and (IV) reaction according to step (II) using a zeolitic catalyst which contains the regenerated catalyst from step (III).
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