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1.发明公开ALS KATALYSATOR FÜR DIE HYDROCYANIERUNG VON OLEFINISCH UNGESÄTTIGTEN VERBINDUNGEN GEEIGNETES SYSTEM 有权AS烯属不饱和化合物FIT系统的催化剂的氢氰化
公开(公告)号：EP1610893A1
公开(公告)日：2006-01-04
申请号：EP04722843.2
申请日：2004-03-24
发明人： BARTSCH, Michael , BAUMANN, Robert , HADERLEIN, Gerd , FLORES, Miguel Angel , JUNGKAMP, Tim , LUYKEN, Hermann , SCHEIDEL, Jens , SIEGEL, Wolfgang , MOLNAR, Ferenc
IPC分类号： B01J27/14
CPC分类号： B01J31/185 , B01J23/755 , B01J31/0212 , B01J31/143 , B01J31/1865 , B01J2231/32 , B01J2531/847 , C07C253/10 , C07C255/04
摘要： A system suitable for use as a catalyst for the hydrocyanation of olefinically unsaturated compounds, containing a) Ni(0), b) Ni(0) as a ligand complex-fixing compound containing trivalent phosphorus, c) a Lewis acid and d) a compound of formula MRn wherein M = AI or Ti, R= identical or different monovalent alkoxyl radicals, wherein several alkoxy radicals can be interbridged, also in the case where M = AI, R = identical or different alkyl radicals wherein several alkyl radicals can be interbridged or one or several alkyl radicals can be bridged by one or several of the above-mentioned alkoxy radicals, n = valency of M. The invention also relates to methods for the hydrocyanation of an olefinically unsaturationed compound in the presence of said system.
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2.发明授权ALS KATALYSATOR FÜR DIE HYDROCYANIERUNG VON OLEFINISCH UNGESÄTTIGTEN VERBINDUNGEN GEEIGNETES SYSTEM 有权AS烯属不饱和化合物FIT系统的催化剂的氢氰化
公开(公告)号：EP1610893B1
公开(公告)日：2007-03-07
申请号：EP04722843.2
申请日：2004-03-24
发明人： BARTSCH, Michael , BAUMANN, Robert , HADERLEIN, Gerd , FLORES, Miguel Angel , JUNGKAMP, Tim , LUYKEN, Hermann , SCHEIDEL, Jens , SIEGEL, Wolfgang , MOLNAR, Ferenc
IPC分类号： B01J27/14
CPC分类号： B01J31/185 , B01J23/755 , B01J31/0212 , B01J31/143 , B01J31/1865 , B01J2231/32 , B01J2531/847 , C07C253/10 , C07C255/04
摘要： A system suitable for use as a catalyst for the hydrocyanation of olefinically unsaturated compounds, containing a) Ni(0), b) Ni(0) as a ligand complex-fixing compound containing trivalent phosphorus, c) a Lewis acid and d) a compound of formula MRn wherein M = AI or Ti, R= identical or different monovalent alkoxyl radicals, wherein several alkoxy radicals can be interbridged, also in the case where M = AI, R = identical or different alkyl radicals wherein several alkyl radicals can be interbridged or one or several alkyl radicals can be bridged by one or several of the above-mentioned alkoxy radicals, n = valency of M. The invention also relates to methods for the hydrocyanation of an olefinically unsaturationed compound in the presence of said system.
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3.发明公开VERFAHREN ZUR ISOMERISIERUNG VON CIS-2-PENTENNITRIL ZU TRANS-3-PENTENNITRIL 有权方法CIS 2戊烯腈反式-3-戊烯腈的异构化
公开(公告)号：EP1622862A1
公开(公告)日：2006-02-08
申请号：EP04727882.5
申请日：2004-04-16
发明人： BARTSCH, Michael , BAUMANN, Robert , HADERLEIN, Gerd , FLORES, Miguel Angel , JUNGKAMP, Tim , LUYKEN, Hermann , SCHEIDEL, Jens , SIEGEL, Wolfgang , KUNSMANN-KEITEL, Dagmar, Pascale
IPC分类号： C07C253/30 , C07C255/07
CPC分类号： C07C253/30 , C07C255/07
摘要： The invention relates to a method for the isomerization of 2-pentenenitrile to form trans-3-pentenenitrile in the presence of aluminium oxide as a catalyst. The invention is characterised in that the BET surface of the aluminium oxide is at least 50 m2/g.
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公开(公告)号：EP1633691B1
公开(公告)日：2007-04-11
申请号：EP04739502.5
申请日：2004-06-02
发明人： FLORES, Miguel Angel , BARTSCH, Michael , BAUMANN, Robert , HADERLEIN, Gerd , JUNGKAMP, Tim , SCHEIDEL, Jens , LUYKEN, Hermann , SIEGEL, Wolfgang , MEYER, Christa , WIDMAIER, Ralf
摘要： The invention relates to a method for producing a 2,2'-dihydroxy-biphenyl by the oxidative coupling of two phenol molecules, which have a hydrogen atom in an o-position, using a peroxide in the presence of water at a temperature ranging from 0 DEG C to 100 DEG C. The invention is characterized in that the production is carried out in the presence of a water-insoluble polymer, containing; a) 0.1 to 99.9 % by weight of at least one vinyl heterocyclic compound; b) 0.1 to 10 % by weight of a bifunctional cross-linker constituent; c) 0 to 99.8 % by weight of styrene or of at least one monounsaturated styrene derivative or mixtures thereof, whereby the indicated percentages by weight of the individual constituents a), b) and c) total 100 %.
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5.发明授权VERFAHREN ZUR ABTRENNUNG VON SÄUREN AUS CHEMISCHEN REAKTIONSGEMISCHEN MIT HILFE VON IONISCHEN FLÜSSIGKEITEN 有权方法用于分离氨基酸而化学反应混合物中使用离子液体
公开(公告)号：EP1470136B1
公开(公告)日：2007-03-28
申请号：EP03704443.5
申请日：2003-01-21
发明人： VOLLAND, Martin , SEITZ, Verena , MAASE, Matthias , FLORES, Miguel Angel , PAPP, Rainer , MASSONNE, Klemens , STEGMANN, Veit , HALBRITTER, Klaus , NOE, Ralf , BARTSCH, Michael , SIEGEL, Wolfgang , BECKER, Michael , HUTTENLOCH, Oliver
CPC分类号： C07C403/12 , C07C1/30 , C07C45/50 , C07C51/412 , C07C51/58 , C07C67/14 , C07C2531/02 , C07C2601/16 , C07D295/185 , C07D317/36 , C07F9/142 , C07F9/145 , C07F9/46 , C07F9/4841 , C07F9/52 , C07F9/5721 , C07F9/5728 , C07F9/65038 , C07F9/65746 , C07F9/65848 , C07C47/02 , C07C13/23 , C07C69/78 , C07C69/24 , C07C69/14 , C07C53/10
摘要： Disclosed is a method for producing aminodihalophosphines, diaminohalophosphines, triaminophosphines, phosphite diamides, aminophosphines, diaminophosphines, phosphite amide halogenides, and aminophosphine halogenides by separating an acid in the presence of an auxiliary base. Said auxiliary base b) forms a salt with an acid, which is liquid at temperatures at which the valuable product is not significantly decomposed during separation of the liquid salt, and c) the salt of the auxiliary base and the valuable product or the solution of the valuable product form two immiscible phases in a suitable solvent.
摘要翻译： 一种用于使用辅助碱的除去从反应混合物中的酸处理，其中，所述辅助碱：与酸结合形成盐的所有其处的，其值的产品不除去液体盐的过程中显着分解温度下为液体， 与有价值的产物或值在合适的溶剂中的产物的溶液中的辅助碱的盐形成两个不混溶的液相。
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6.发明公开STERISCH ANSPRUCHSVOLLE CHELATPHOSPHINITPHOSPHITLIGANDEN, KATALYSATOR, UMFASSEND WENIGSTENS EINEN NICKEL(0)KOMPLEX STABILISIERT DURCH DIESEN LIGANDEN SOWIE EIN VERFAHREN ZUR HERSTELLUNG VON NITRILEN 有权大件CHELATPHOSPHINITPHOSPHITLIGANDEN，催化剂，含有稳定化通过一种用于制造NITRILES这些配体和方法至少一种镍（0）络合物
公开(公告)号：EP1682559A1
公开(公告)日：2006-07-26
申请号：EP04790949.4
申请日：2004-10-28
发明人： BARTSCH, Michael , BAUMANN, Robert , HADERLEIN, Gerd , FLORES, Miguel Angel , JUNGKAMP, Tim , LUYKEN, Hermann , SCHEIDEL, Jens , SIEGEL, Wolfgang
CPC分类号： B01J31/1885 , B01J31/185 , B01J31/1875 , B01J2231/323 , B01J2231/52 , B01J2531/847 , C07C253/10 , C07C253/30 , C07F9/4875 , C07F9/65744 , C07C255/07 , C07C255/09
摘要： The invention relates to phosphinite phosphites I of formula 1, 2, 3, 4, 5 or 6 and mixtures thereof, wherein R1, R2, R4 independently represent an alkyl or alkylene group with 1 to 8 carbon atoms, provided that at least one of the groups R1, R2, R4 is different from H; R5 to R22 independently represent H, an alkyl or alkylene group with 1 to 8 carbon atoms; R3 is H, methyl or ethyl; X is F, Cl or CF3, if n = 1 or 2 and X is H, if n = 0.
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公开(公告)号：EP1633691A1
公开(公告)日：2006-03-15
申请号：EP04739502.5
申请日：2004-06-02
发明人： FLORES, Miguel Angel , BARTSCH, Michael , BAUMANN, Robert , HADERLEIN, Gerd , JUNGKAMP, Tim , SCHEIDEL, Jens , LUYKEN, Hermann , SIEGEL, Wolfgang , MEYER, Christa , WIDMAIER, Ralf
摘要： The invention relates to a method for producing a 2,2'-dihydroxy-biphenyl by the oxidative coupling of two phenol molecules, which have a hydrogen atom in an o-position, using a peroxide in the presence of water at a temperature ranging from 0 °C to 100 °C. The invention is characterized in that the production is carried out in the presence of a water-insoluble polymer, containing; a) 0.1 to 99.9 % by weight of at least one vinyl heterocyclic compound; b) 0.1 to 10 % by weight of a bifunctional cross-linker constituent; c) 0 to 99.8 % by weight of styrene or of at least one monounsaturated styrene derivative or mixtures thereof, whereby the indicated percentages by weight of the individual constituents a), b) and c) total 100 %.
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