TRIAZOLOPYRIMIDIN-VERBINDUNGEN UND IHRE VERWENDUNG ZUR BEKÄMPFUNG VON SCHADPILZEN
    2.
    发明公开
    TRIAZOLOPYRIMIDIN-VERBINDUNGEN UND IHRE VERWENDUNG ZUR BEKÄMPFUNG VON SCHADPILZEN 审中-公开
    TRIAZOLOPYRIMIDIN-VERBINDUNGEN UND IHRE VERWENDUNG ZURBEKÄMPFUNGVON SCHADPILZEN

    公开(公告)号:EP1758457A1

    公开(公告)日:2007-03-07

    申请号:EP05753191.5

    申请日:2005-06-08

    CPC classification number: A01N43/90

    Abstract: The invention relates to the use of triazolopyrimidines of formula (I), wherein R1, R2 represent hydrogen, alkyl, alkyl halide, cycloalkyl, cycloalkyl halide, alkenyl, alkadienyl, alkenyl halide, cycloalkenyl, cycloalkenyl halide, alkinyl, alkinyl halide, C3-C6 cycloalkinyl, phenyl, naphthyl, or a five-membered or ten-membered saturated, partially unsaturated, or aromatic heterocycle containing one, two, three, or four heteroatoms from the group comprising O, N, or S. R1, R2 can be substituted as described in the description, or R1 and R2 form five-membered to eight-membered heterocyclyl or heteroaryl along with the nitrogen atom to which the same are bound, said heterocyclyl or heteroaryl being bound via N. Furthermore, R1, R2 contain one, two, or three additional heteroatoms from the group comprising O, N, and S as a ring member and/or can be substituted as defined in the description. Additionally, in formula (I), L independently represents halogen, alkyl, alkyl halide, alkoxy, alkoxy halide, alkenyloxy, cyano, C(=O)A1, S(=O)mA2, NRcRd, or NRc-(C=O)-Rd, A1, A2, Rc, Rd, and m being defined as indicated in the description; L1 represents halogen, alkyl, alkyl halide; L2 represents nitro, a -C(S)NR3R4 group, a -C(=N-OR5)(NR6R7) group, or a -C(=N-NR8R9)(NR10R11) group; X represents halogen, cyano, alkyl, alkoxy, alkyl halide, or alkoxy halide; R3, R4, R5, R6, R7, R8, R9, R10, and R11 are independently selected among hydrogen, alkyl, cycloalkyl, alkenyl, or alkinyl, the last four radicals mentioned being optionally substituted as defined in the description; R3 and R4, R6 and R7, R8 and R9, and/or R10 and R11 form a four-membered, five-membered, or six-membered saturated or partially unsaturated ring along with the nitrogen atom, said ring being optionally substituted as defined in the description; and n represents 0, 1, 2, or 3. Also disclosed are the agriculturally acceptable salts thereof, novel triazolopyrimidines, crop protection agents containing at least one compound of general formula (I) and at least one liquid or solid carrier substance, and a method for controlling plant-pathogenic harmful fungi.

    Abstract translation: 本发明涉及式(I)三唑并嘧啶的用途,其中R 1,R 2表示氢,烷基,烷基卤,环烷基,环烷基卤,链烯基,链二烯基,链烯基卤化物,环烯基,环烯基卤化物,炔基, C6环烷基,苯基,萘基或含有1,2,3或4个选自O,N或S的杂原子的五元或十元饱和,部分不饱和或芳族杂环。R1,R2可以是 如说明书中所述被取代,或者R 1和R 2与其所连接的氮原子一起形成五元至八元杂环基或杂芳基,所述杂环基或杂芳基通过N连接。此外,R 1,R 2含有一个 ,两个或三个另外的选自O,N和S的杂原子作为环成员和/或可以如说明书中所定义的那样被取代。 此外,在式(I)中,L独立地表示卤素,烷基,卤代烷基,烷氧基,烷氧基卤化物,烯氧基,氰基,C(= O)A1,S(= O)mA2,NRcRd或NRc-(C = O )-Rd,A1,A2,Rc,Rd和m如说明书中所示定义; L1代表卤素,烷基,烷基卤; L 2表示硝基,-C(S)NR 3 R 4基,-C(= N-OR 5)(NR 6 R 7)基或-C(= N-NR 8 R 9)(NR 10 R 11) X代表卤素,氰基,烷基,烷氧基,烷基卤或烷氧基卤; R3,R4,R5,R6,R7,R8,R9,R10和R11独立地选自氢,烷基,环烷基,烯基或炔基,所述最后四个基团任选如说明书中所定义的那样被取代; R 3和R 4,R 6和R 7,R 8和R 9和/或R 10和R 11与氮原子一起形成四元,五元或六元饱和或部分不饱和的环,所述环任选如定义 在描述中; 并且n代表0,1,2或3.还公开了其农业上可接受的盐,新的三唑并嘧啶,含有至少一种通式(I)的化合物和至少一种液体或固体载体物质的作物保护剂和 控制植物病原性有害真菌的方法。

    FUNGIZIDE TRIAZOLOPYRIMIDINE, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG ZUR BEKÄMPFUNG VON SCHADPILZEN SOWIE SIE ENTHALTENDE MITTEL
    5.
    发明公开
    FUNGIZIDE TRIAZOLOPYRIMIDINE, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG ZUR BEKÄMPFUNG VON SCHADPILZEN SOWIE SIE ENTHALTENDE MITTEL 有权
    FUNGIZIDE TRIAZOLOPYRIMIDINE,VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG ZURBEKÄMPFUNGVON SCHADPILZEN SOWIE SIE ENTHALTENDE MITTEL

    公开(公告)号:EP1406903A2

    公开(公告)日:2004-04-14

    申请号:EP02758297.2

    申请日:2002-07-03

    CPC classification number: C07D487/04 A01N43/90

    Abstract: Triazolopyrimidines of formula (I), wherein the index and substituents have the following meaning: n = 0 or a whole number of 1 - 5; R = halogen, cyano, hydroxy, cyanate, alkyl, alkenyl, alkinyl, halogenalkyl, halogenalkenyl, alkoxy, alkenyloxy, alkinyloxy, halogenalkoxy, cycloalkyl, cycloalkenyl, cycloalkoxy, alkoxycarbonyl, alkenyloxycarbonyl, alkinyloxycarbonyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkoximinoalkyl, alkenyloximinocarbonyl, alkinyloximinoalkyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl, cycloalkylcarbonyl or a five to ten membered saturated, partially unsaturated or aromatic heterocycle, containing one to four heteroatoms from the group O, N or S; R1 = alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, phenyl, naphthyl or a five to ten membered saturated, partially unsaturated or aromatic heterocycle, containing one to four heteroatoms from the group O, N or S, R and/or R1 being able to be substituted according to the description; R2 = alkyl, alkenyl or alkinyl which can be substituted by halogen, cyano, nitro, alkoxy or alkoxycarbonyl. The invention also relates to a method for the production of said compounds, agents containing same, and the use thereof in controlling noxious fungi.

    Abstract translation: 式(I)的三唑并嘧啶,其中指数和取代基具有以下含义:n = 0或整数1-5; 卤素,烷基,烯基,炔基,卤代烷基,卤代烯基,烷氧基,烯氧基,炔氧基,卤代烷氧基,环烷基,环烯基,环烷氧基,烷氧基羰基,烯氧基羰基,炔氧基羰基,氨基羰基,烷基氨基羰基,二烷基氨基羰基,烷氧基亚氨基烷基, 烷氧基烷基,烷基羰基,链烯基羰基,炔基羰基,环烷基羰基或5至10元饱和,部分不饱和或芳族杂环,其含有1至4个选自O,N或S的杂原子; 含有1-4个选自O,N或S,R和/或R1的杂原子的烷基,链烯基,炔基,环烷基,环烯基,苯基,萘基或五至十元饱和,部分不饱和或芳香族杂环 根据描述进行替换; R2 =可被卤素,氰基,硝基,烷氧基或烷氧基羰基取代的烷基,烯基或炔基。 本发明还涉及生产所述化合物的方法,含有该化合物的试剂及其在防治有害真菌中的用途。

    3-AMINOCARBONYL/3-AMINOTHIOCARBONYL-SUBSTITUIERTE 2-BENZOYL- CYCLOHEXAN-1,3-DIONE MIT HERBIZIDER WIRKUNG
    6.
    发明授权
    3-AMINOCARBONYL/3-AMINOTHIOCARBONYL-SUBSTITUIERTE 2-BENZOYL- CYCLOHEXAN-1,3-DIONE MIT HERBIZIDER WIRKUNG 失效
    3-氨基羰基-3-氨基羰基替代物2-苯甲酰 - 环己烷-1,3-二酮麻醉剂治疗剂WIRKUNG

    公开(公告)号:EP0960095B1

    公开(公告)日:2003-10-01

    申请号:EP97954746.0

    申请日:1997-12-19

    Abstract: The invention concerns 2-benzoyl-cyclohexan-1,3-diones of formula (I), in which R1, R2 stand for hydrogen, nitro, halogen, cyano, rhodano, alkyl, halogen alkyl, alkoxyalkyl, alkenyl, alkinyl, -OR?5, -OCOR6¿, -OSO¿2R?6, -SH, -S(O)¿n?R?7, -SO¿2OR5, -SO2NR?5R8, -NR8SO¿2R?6 or -NR8COR6; R3¿ stands for hydrogen, alkyl, halogen alkyl or alkinyl; R4 stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkinyl, -COR9, -CO2R?9, -COSR9¿ or -CONR8R9; X stands for oxygen or sulphur; m equals 0 or 1; n equals 0, 1 or 2; R5 stands for hydrogen, alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R6 stands for alkyl or halogen alkyl; R7 stands for alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R8 stands for hydrogen or alkyl; R9 stands for alkyl, alkenyl, alkinyl, phenyl or benzyl; R10 stands for alkyl, halogen alkyl, alkenyl or alkinyl; Q stands for optionally substituted cyclohexan-1,3-dione ring linked in position 2, whereas m equals 1 when R3 stands for hydrogen. Also disclosed are the salts of these compounds useful in agriculture; processes and intermediate products for preparing the compounds of formula (I), agents containing the same and the use of these derivatives or agents containing the same for controlling undesirable plants.

    Abstract translation: 本发明涉及式I的2-苯甲酰基环己烷-1,3-二酮,其中R 1,R 2为氢,硝基,卤素,氰基,氰硫基,烷基,卤代烷基,烷氧基烷基,烯基,炔基,-OR 5,-OCOR 6,-OSO 2 R 6 - SH,-S(O)nR7,-SO2OR5,-SO2NR5R8,-NR8SO2R6或-NR8COR6; R3是氢,烷基,卤代烷基,烯基或炔基; R4是氢,未取代或取代的烷基,环烷基,烯基,环烯基,炔基, -COR 9,-CO 2 R 9,-COSR 9或-CONR 8 R 9; X为氧或硫; Z为氧或NR 8; m为0或1; n为0,1或2; R 5为氢,烷基,卤代烷基,烷氧基烷基, 炔基; R 6是烷基,卤代烷基,烯基或炔基; R 8是氢或烷基; R 9是烷基,烯基,炔基,苯基或苄基; 在2-位连接的未取代或取代的环己烷-1,3-二酮环;如果R3是氢,其中m为1;其农业上有用的盐;制备的方法和中间体o f式I化合物; 包含它们的组合物; 以及包含它们的这些衍生物或组合物用于防治不需要的植物的用途。

    VERFAHREN ZUR HERSTELLUNG VON 1-SUBSTITUIERTEN 5-HYDROXYPYRAZOLEN
    10.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON 1-SUBSTITUIERTEN 5-HYDROXYPYRAZOLEN 有权
    VERFAHREN ZUR HERSTELLUNG VON 1-SUBSTITUIERTEN 5-HYDROXYRAZOLEN

    公开(公告)号:EP1127050A1

    公开(公告)日:2001-08-29

    申请号:EP99955919.8

    申请日:1999-10-30

    CPC classification number: C07C243/30 C07D231/20

    Abstract: The invention relates to a method for producing substituted hydroxypyrazoles and new intermediate products. It relates in particular to a method for producing compounds of formula (I) in which R1 is hydrogen, an aliphatic group with between 1 and 8 carbon atoms, C¿1?-C6-alkoxycarbonyl, C1-C6-alkyl thiocarbonyl or a cyclic ring system with between 3 and 14 ring atoms; R?2¿ is hydrogen, an aliphatic group with between 1 and 8 carbon atoms; or R?1 and R2¿ together with the carbon atom to which they are bound are a cyclic or bicyclic ring system with between 3 and 14 ring atoms. Said method comprises the production, as starting or intermediate products, of compounds of formula (II) in which R?3 and R4¿ are readily cleavable groups and R?1 and R2¿ have the meanings given above. Said compounds are cyclized under suitable reaction conditions to yield compounds of formula (I).

    Abstract translation: 本发明涉及一种制备取代的羟基吡唑和新的中间产物的方法。 本发明特别涉及制备式(I)化合物的方法,其中R 1为氢,具有1至8个碳原子的脂族基团,C 1 -C 6烷氧基羰基,C 1 -C 6烷基硫代羰基或环 具有3至14个环原子的环系; R 2是氢,一个有1到8个碳原子的脂族基团; 或R 1和R 2与它们所键合的碳原子一起是具有3-14个环原子的环状或双环环系。 所述方法包括生产式(II)化合物作为起始或中间产物,其中R 3和R 4是易裂解基团且R 1和R 2具有上述含义。 所述化合物在合适的反应条件下环化生成式(I)的化合物。

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