公开(公告)号：EP1988998A1

公开(公告)日：2008-11-12

申请号：EP07704548.2

申请日：2007-02-13

Applicant: BASF SE

Inventor： HADERLEIN, Gerd ,  AECHTNER, Tobias ,  LEITNER, Andreas ,  PFAB, Peter ,  LUYKEN, Hermann ,  SCHEIDEL, Jens

IPC: B01J31/24 ,  B01J31/18

CPC classification number: B01J31/1845 ,  B01J31/24 ,  B01J2231/32 ,  B01J2531/847

Abstract: Process for producing nickel(0)-phosphorus ligand complexes containing at least one nickel(0) central atom and at least one phosphorus-containing ligand, by reacting a nickel(II) compound with a reducing agent in the presence of the ligand to give a reaction mixture, characterized in that, a) in the reaction the molar ratio of reducing agent:nickel(II) compound is 1:1 to 1000:1, calculated as molar ratio of redox equivalents, b) in the reaction the molar ratio of phosphorus-containing ligand:nickel(II) compound is at most 30:1, calculated as molar ratio of P atoms:Ni atoms, c) in the resultant reaction mixture the nickel(0) content is at most 1.3% by weight, and d) the resultant reaction mixture is extracted by adding at least one dinitrile and at least one hydrocarbon, at least two immiscible phases forming.

公开(公告)号：EP2556050A1

公开(公告)日：2013-02-13

申请号：EP11714959.1

申请日：2011-04-06

Applicant: BASF SE

Inventor： LUYKEN, Hermann ,  PFAB, Peter ,  BAUMANN, Robert ,  LEITNER, Andreas ,  AECHTNER, Tobias

IPC: C07C253/30

CPC classification number: C07C253/30 ,  C07C255/07

Abstract: The invention relates to a method for isomerizing cis-2-pentene nitrile to form 3-pentene nitriles by isomerizing cis-2-pentene nitrile with amidines, tertiary amines or the mixtures thereof as a catalyst at temperatures of 80 to 200ºC and a pressure of 0.01 to 50 bar.

公开(公告)号：EP1988998B1

公开(公告)日：2011-06-15

申请号：EP07704548.2

申请日：2007-02-13

Applicant: BASF SE

Inventor： HADERLEIN, Gerd ,  AECHTNER, Tobias ,  LEITNER, Andreas ,  PFAB, Peter ,  LUYKEN, Hermann ,  SCHEIDEL, Jens

IPC: B01J31/24 ,  B01J31/18

CPC classification number: B01J31/1845 ,  B01J31/24 ,  B01J2231/32 ,  B01J2531/847

Abstract: Process for producing nickel(0)-phosphorus ligand complexes containing at least one nickel(0) central atom and at least one phosphorus-containing ligand, by reacting a nickel(II) compound with a reducing agent in the presence of the ligand to give a reaction mixture, characterized in that, a) in the reaction the molar ratio of reducing agent:nickel(II) compound is 1:1 to 1000:1, calculated as molar ratio of redox equivalents, b) in the reaction the molar ratio of phosphorus-containing ligand:nickel(II) compound is at most 30:1, calculated as molar ratio of P atoms:Ni atoms, c) in the resultant reaction mixture the nickel(0) content is at most 1.3% by weight, and d) the resultant reaction mixture is extracted by adding at least one dinitrile and at least one hydrocarbon, at least two immiscible phases forming.

公开(公告)号：EP2044092A1

公开(公告)日：2009-04-08

申请号：EP07787009.5

申请日：2007-07-03

Applicant: BASF SE

Inventor： BAUMANN, Robert ,  AECHTNER, Tobias ,  SIEGEL, Wolfgang ,  LUYKEN, Hermann ,  PFAB, Peter ,  SCHEIDEL, Jens ,  LEITNER, Andreas ,  GLASS, Andreas

IPC: C07F9/48

CPC classification number: C07F9/4891 ,  C07F9/4875

Abstract: The invention relates to a method for producing compounds of general formula XPR2(OR1) (Ia), wherein X represents chlorine, bromine or iodine and R1 represents an organic radical, by reacting compounds of general formula X2PR2 (II), wherein X has the above-mentioned meaning and R2 represents an organic radical, with compounds of general formula R1OH (III), wherein R1 has the above-mentioned meaning, to form a mixture IV, wherein a) the secondary reaction is carried out at a temperature of between 50 to 240°C and at a pressure of 0,001 to 0,9 bar, b) from the mixture IV, the compounds (Ia) are separated from the compounds PR2(OR1)2 (Ib) and optionally from the compounds II and c) compounds (Ib) and optionally non-reacted compounds II are guided back to the synthesis step.

公开(公告)号：EP1868975B1

公开(公告)日：2012-06-13

申请号：EP06725582.8

申请日：2006-04-05

Applicant: BASF SE

Inventor： BARTSCH, Michael ,  HADERLEIN, Gerd ,  AECHTNER, Tobias ,  SCHEIDEL, Jens ,  DIENES, Christian ,  TEMPEL, Alexandre ,  HOFRICHTER, Thorsten ,  WEINLE, Werner

IPC: C07C37/11 ,  C07C39/15 ,  C07F9/02

CPC classification number: C07C37/11 ,  C07C39/15

Abstract: The invention relates to a method for producing biphenols of general formula (I) by reacting monophenols of general formula (II), wherein the radicals R1, R2 and R3 independently represent hydrogen, alkyl, aryl or arylalkyl, with 1 - 10 C-atoms, in the presence of an oxidation agent in a reactor. Said method is characterised in that a) the reactor does not contain any stationary integrated components which act as a current agitator, b) a maximum of 0,6 mol of oxidation agents are used per mol of monophenol, and c) the oxidation agent is added in a continuous or discontinuous manner in a plurality of portions within a time span of between 10 min - 24 hours, whereby the amount of oxidation agent which is added per time unit is not constant over the entire tine span, but is varied.

公开(公告)号：EP1799697B1

公开(公告)日：2012-03-14

申请号：EP05796041.1

申请日：2005-09-30

Applicant: BASF SE

Inventor： BARTSCH, Michael ,  BAUMANN, Robert ,  HADERLEIN, Gerd ,  AECHTNER, Tobias ,  SCHEIDEL, Jens ,  LUYKEN, Hermann ,  PFAB, Peter ,  SIEGEL, Wolfgang ,  WEISKOPF, Verena

IPC: C07F9/6574 ,  B01D11/00

CPC classification number: B01D11/0492 ,  C07F9/025 ,  C07F9/145

Abstract: The invention relates to a method for purifying chelate ligands containing phosphorus by extraction by means of polar extraction agents.

公开(公告)号：EP2007491A2

公开(公告)日：2008-12-31

申请号：EP07727428.0

申请日：2007-03-28

Applicant: BASF SE

Inventor： HADERLEIN, Gerd ,  AECHTNER, Tobias ,  BARTSCH, Michael ,  LUYKEN, Hermann ,  PFAB, Peter ,  SCHEIDEL, Jens ,  LEITNER, Andreas

IPC: B01D11/04 ,  B01J31/18 ,  B01J31/24 ,  B01J31/40 ,  C07C253/10 ,  C07C253/32

CPC classification number: B01J31/403 ,  B01D11/0426 ,  B01D11/0457 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/1865 ,  B01J31/24 ,  B01J31/4053 ,  C07C253/34 ,  C07D333/48 ,  Y02P20/584 ,  C07C255/09

Abstract: The invention relates to a method for extractive separation of nickel (0) complexes with phosphorous ligands, from a reaction product of a hydrocyanation of unsaturated mononitriles to give dinitriles, by means of extraction with a hydrocarbon, wherein a phase separation of the hydrocarbon and the nitrile-containing solution into two phases occurs, by addition of a polar additive to the reaction product (feed stream) and/or the extraction stage.

公开(公告)号：EP1817108B1

公开(公告)日：2008-06-04

申请号：EP05798767.9

申请日：2005-10-12

Applicant: BASF SE

Inventor： DECKERT, Petra ,  BASSLER, Peter ,  BARTSCH, Michael ,  HADERLEIN, Gerd ,  LUYKEN, Hermann ,  SCHEIDEL, Jens ,  PFAB, Peter ,  AECHTNER, Tobias ,  SIEGEL, Wolfgang

IPC: B01J31/40 ,  B01J38/56 ,  B01D11/04 ,  C07C253/10 ,  C07C253/32 ,  B01J31/18 ,  B01J31/24

CPC classification number: B01J31/4053 ,  B01D11/0434 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/24 ,  B01J31/403 ,  B01J2231/323 ,  B01J2531/847 ,  C07C253/10 ,  C07C253/32 ,  Y02P20/584 ,  C07C255/04

Abstract: The invention relates to a method for the extractive separation of homogeneously dissolved catalysts from a reaction product from a hydrocyanation of unsaturated mononitriles to dinitriles, by extraction with a carbon material (K), characterised in that a) a non-polar aprotic liquid (F) is added to the reaction product to give a stream (I) and b) the stream (I) is extracted with a carbon material (K) at a temperature (T), to give a stream (II), containing the carbon material (K), enriched with the catalyst and a stream (III), stripped of catalyst.

公开(公告)号：EP2556050B2

公开(公告)日：2017-09-06

申请号：EP11714959.1

申请日：2011-04-06

Applicant: BASF SE

Inventor： LUYKEN, Hermann ,  PFAB, Peter ,  BAUMANN, Robert ,  LEITNER, Andreas ,  AECHTNER, Tobias

IPC: C07C253/30

CPC classification number: C07C253/30 ,  C07C255/07

公开(公告)号：EP2556050B1

公开(公告)日：2014-05-14

申请号：EP11714959.1

申请日：2011-04-06

Applicant: BASF SE

Inventor： LUYKEN, Hermann ,  PFAB, Peter ,  BAUMANN, Robert ,  LEITNER, Andreas ,  AECHTNER, Tobias

IPC: C07C253/30

CPC classification number: C07C253/30 ,  C07C255/07