VERFAHREN ZUR HERSTELLUNG VON PERYLEN-3,4:9,10-TETRACARBONSÄUREDIIMIDEN UND PERYLEN-3,4:9,10-TETRACARBONSÄUREDIANHYDRID SOWIE VON NAPHTHALIN-1,8-DICARBONSÄUREIMIDEN
    1.
    发明授权

    公开(公告)号:EP1501897B1

    公开(公告)日:2012-03-14

    申请号:EP03717301.0

    申请日:2003-04-15

    Applicant: BASF SE

    CPC classification number: C09B5/62 C09B57/08

    Abstract: Production of perylen-3,4:9,10-tetracarboxylic acid diimides of general formula (I), where R = C1-C30 alkyl, the carbon chain of which may be interrupted by one or several -O- groups and/or is substituted with C5-C8 cycloalkyl, which can be mono- or multiply-substituted by C1-C6 alkyl, phenyl or phenyl-C1-C6 alkyl, which can each be mono- or multiply-substituted with C1-C18 alkyl and/or C1-C6 alkoxy, and mono- or multiply-substituted by -OCOR1, -N(R1)2, -SO2NH2, -SO2N(R1)2, -CON(R1)2 and/or -COOR1; C5-C8 cycloalkyl, the carbon skeleton of which may be interrupted by one or more -O-, -S- and/or -NR2- groups and/or mono- or multiply-substituted with C1-C6 alkyl; phenyl, phenyl-C1-C6 alkyl, naphthyl or heteroaryl, which may be mono- or multiply-substituted with C1-C18 alkyl, C1-C6 alkoxy, phenylazo, naphthylazo, pyridylazo, pyrimidylazo, cyano, -N(R1)2, -CON(R1)2 and/ or -COOR1; R1 = C1-C6 alkyl, C5-C8 cycloalkyl, phenyl or phenyl-C1-C6 alkyl; R2 = C1-C6 alkyl, phenyl or phenyl-C1-C6 alkyl, by dimerisation of a naphthalene-1,8-dicarboximide of formula (II), whereby the dimerisation is carried out in a reaction medium essentially comprising a non-polar aprotic organic solvent and a base comprising an alkali metal and the leuco form of the perylen-3,4:9,10-tetracarboxylic acid diimide precipitating as the alkali metal salt then reoxidised in the presence of a polar solvent. The invention also relates to the production of perylen-3,4:9,10-tetracarboxylic acid anhydride and naphthalene-1,8-dicarboximides.

    THERMOPLASTISCHE FORMMASSEN ENTHALTEND ORGANISCHE SCHWARZPIGMENTE
    5.
    发明公开
    THERMOPLASTISCHE FORMMASSEN ENTHALTEND ORGANISCHE SCHWARZPIGMENTE 有权
    热塑性模塑化合物含的有机黑色颜料

    公开(公告)号:EP2162489A1

    公开(公告)日:2010-03-17

    申请号:EP08761326.1

    申请日:2008-06-24

    Applicant: BASF SE

    CPC classification number: C08K5/0041 C08K5/3447 C09B5/62 F21V7/22

    Abstract: The invention relates to thermoplastic molding materials comprising (A) from 34 to 99.99% by weight of at least one thermoplastic polymer selected from (i) polyarylene ethers, (ii) polyetherimides, (iii) polyarylene sulfides and (iv) polycarbonates having a glass transition temperature of at least 145°C, and to copolymers of the aforementioned polymers (i) to (iv), (B) from 0.01 to 10% by weight of at least one organic black pigment which is transparent in the range from 1000 nm to 1600 nm and has a thermal stability under DIN EN 12877-1 of at least 300°C, (C) from 0 to 6% by weight of at least one demolding agent selected from fatty acids, esters and amides, (D) from 0 to 50% by weight of one or more additives, where the sum of the percentages by weight of (A), (B), (C) and (D) adds up to 100% by weight. The invention further relates to a process for preparing the thermoplastic molding materials and to the moldings obtainable therefrom. The invention finally relates to the use of the thermoplastic molding materials for reducing the accumulation of heat in plastic components, moldings, films or membranes.

    PHOTOVOLTAIC MODULES WITH IMPROVED QUANTUM EFFICIENCY
    6.
    发明公开
    PHOTOVOLTAIC MODULES WITH IMPROVED QUANTUM EFFICIENCY 审中-公开
    FOTOVOLTISCHE MODULE MIT VERBESSERTER QUANTENEFFIZIENZ

    公开(公告)号:EP2130233A1

    公开(公告)日:2009-12-09

    申请号:EP08717658.2

    申请日:2008-03-12

    Applicant: BASF SE

    Abstract: A photovoltaic module (110) is disclosed, which is suited for conversion of incident electromagnetic radiation (112) into electric energy. The photovoltaic module (110) comprises in order: a transparent cover sheet (114); and -at least one photovoltaic cell (116), wherein the at least one photovoltaic cell (116) is adapted to convert electromagnetic radiation (112) passing through the transparent cover sheet (114) into electric energy and wherein the photovoltaic cell (116) is accommodated within at least one encapsulation element (118) providing protection from environmental influence. The encapsulation element (118) comprises at least one luminescence downshifting material, which is adapted for at least partially absorbing the incident radiation (112) and for re-emitting radiation (112) at a longer wavelength.

    Abstract translation: 公开了一种适于将入射电磁辐射(112)转换成电能的光伏模块(110)。 光伏模块(110)依次包括:透明盖板(114); 和至少一个光伏电池(116),其中所述至少一个光伏电池(116)适于将通过所述透明覆盖片(114)的电磁辐射(112)转换成电能,并且其中所述光伏电池(116) 容纳在至少一个封装元件(118)中,提供防止环境影响的保护。 封装元件(118)包括至少一个发光降速材料,其适于至少部分地吸收入射辐射(112)并且用于在较长波长处重新发射辐射(112)。

    1,6,9,14-TETRASUBSTITUIERTE TERRYLENTETRACARBONS UREDIIMIDE
    10.
    发明授权

    公开(公告)号:EP1513841B1

    公开(公告)日:2008-05-14

    申请号:EP03735536.9

    申请日:2003-06-04

    CPC classification number: C07D471/06 C09B5/62

    Abstract: The invention relates to 1,6,9,14-tetrasubstituted terrylene tetracarboxylic acid diimides of general formula (I), in which the variables are defined as follows: X, Y independently of one another represent bromium; cyano; aryloxy, arylthio, hetaryloxy or hetarylthio, which can respectively be mono- or polysubstituted by C1-C12 alkyl, C1-C12 alkoxy, -COOR , -SO3R , halogen, hydroxy, carboxy, cyano, -CONHR and/or -NHCOR ; a group of formula -L-R ; a group of formula -NR 2; R, R' independently of one another represent hydrogen; C1-C30 alkyl, whose carbon chain can be interrupted by one or more groupings -O-, -S-, -NR1-, -CO- and/or -SO2- and which can be mono- or polysubstituted by cyano, C1-C6 alkoxy, aryl, which may be substituted by C1-C18 alkyl or C1-C6 alkoxy and/or a 5- to 7-membered heterocyclic group that is bonded by means of a nitrogen atom and that can contain additional heteroatoms and be aromatic; C5-C8 cycloalkyl, whose carbon skeleton can be interrupted by one or more groupings -O-, -S- and/or -NR - and/or which can be mono- or polysubstituted by C1-C6 alkyl; aryl or hetaryl, which can be mono- or polysubstituted by C1-C18 alkyl, C1-C6 alkoxy, cyano, -CONHR , -NHCOR and/or aryl- or hetarylazo, which can be respectively substituted by C1-C10 alkyl, C1-C6 alkoxy or cyano; and L represents 1,2-ethylene, 1,2-ethenylene or 1,2-ethynylene.

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