MECHANICALLY STABILIZED POLYAZOLES
    6.
    发明公开
    MECHANICALLY STABILIZED POLYAZOLES 审中-公开
    机械稳定的聚合物

    公开(公告)号:EP2576670A1

    公开(公告)日:2013-04-10

    申请号:EP11789338.8

    申请日:2011-05-30

    Applicant: BASF SE

    Abstract: A process for preparing mechanically stabilized polyazoles, comprising the following steps: I) treating at least one polyazole having at least one amino group in a repeat unit with a solution comprising (i) at least one strong acid and (ii) at least one stabilizing reagent, the total content of stabilizing reagents in the solution being in the range from 0.01 to 30% by weight, II) performing the stabilization reaction directly and/or in a subsequent processing step by heating to a temperature greater than 25°C, using at least one high-functionality polyether as the stabilizing reagent. The polyazoles thus obtainable are notable especially for a high conductivity and a very good mechanical stability. They are therefore especially suitable for applications in fuel cells.

    Abstract translation: 一种制备机械稳定的聚唑的方法,其包括以下步骤:I)用包含(i)至少一种强酸和(ii)至少一种稳定剂的溶液处理重复单元中具有至少一个氨基的至少一种聚唑 试剂中,溶液中稳定剂的总含量为0.01-30重量%,II)直接和/或在随后的加工步骤中通过加热至高于25℃的温度进行稳定化反应,使用 至少一种高官能度聚醚作为稳定剂。 由此获得的聚唑特别对于高导电性和非常好的机械稳定性而言是显着的。 因此它们特别适用于燃料电池的应用。

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