VERFAHREN ZUR HERSTELLUNG VON MONOETHYLENGLYKOL

    公开(公告)号:EP3328820A1

    公开(公告)日:2018-06-06

    申请号:EP16744365.4

    申请日:2016-07-26

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing monoethylene glycol (MEG) via the metal-catalysed reaction of an oxalic acid dialkyl ester of formula (I), in which R
    1 and R
    2 each independently of one another represent methyl, ethyl, n-propyl or iso-propyl groups, with hydrogen (H
    2 ), wherein the oxalic acid dialkyl ester (I) is used in the form of a melt or dissolved in a solvent, oxalic acid dialkyl ester (I) and H
    2 are used in a molar ratio of H
    2 :oxalic acid dialkyl ester (I) in the region of 4.0 to 30, and the reaction is carried out continuously in a reactor at a sectional density of ≥ 10 m/s, a temperature in the region of 150 to 270°C, a pressure in the region of 150 to 390 bar and in the presence of a chrome-free, heterogeneous, copper-containing catalyst.

    VERWENDUNG STRUKTURIERTER KATALYSATORBETTEN ZUR HERSTELLUNG VON ETHYLENOXID
    8.
    发明公开
    VERWENDUNG STRUKTURIERTER KATALYSATORBETTEN ZUR HERSTELLUNG VON ETHYLENOXID 无效
    结构化催化剂的使用床环氧乙烷生产

    公开(公告)号:EP2440538A1

    公开(公告)日:2012-04-18

    申请号:EP10724836.1

    申请日:2010-06-09

    Applicant: BASF SE

    CPC classification number: C07D301/10

    Abstract: The present invention relates to a method for producing ethylene oxide by reacting ethylene with oxygen in the presence of at least one catalyst containing silver, wherein the reaction occurs in a reactor that has a catalyst packing having at least two layers (i) and (ii), and the silver content of the catalyst in the layer (i) is lower than the silver content of the catalyst in the layer (ii). The catalyst packing preferably comprises a further layer (a), with which the reaction mixture comes in contact prior to layers (i) and (ii). According to the invention, the silver content of the catalyst in the layer (a) is higher than the silver content of the catalyst in the layer (i).

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