摘要:
The invention relates to a process for the preparation of optically active amines of the formula (I*), in which R and m have the meanings given in the description. In the present process the preparation of said amines is such that (a) in a first stage, racemic amines of the formula (I) are reacted, in the presence of lipases from Candida antarctica and optionally in the presence of a diluent, with esters of the formula (II), in which R , R , X and n have the meanings given in the description; (b) in a second stage the resulting mixture of (S)-amine of the formula (I-S) and acylated (R)-amine of the formula (III) is separated.
摘要:
The invention concerns a novel process for preparing racemic phenethylamines of formula (I) in which R , R , R , R and R have the meanings given in the description. According to this process: a) in a first step, optically active phenethylamines of formula (I*) are reacted with acetophenone derivatives of formula (II), the optically active phenethylamine used and the acetophenone derivative used each being substituted in an identical manner in the phenyl part, optionally in the presence of a diluting agent and optionally in the presence of a catalyst; b) in a second step, the resultant optically active Schiff bases of formula (III*) are reacted with metallic hydroxides containing between 0.1 and 50 wt. % water; and c) in a third step, the resultant racemic Schiff bases are reacted with acids in the presence of water.
摘要:
The invention relates to new substituted 2,4-diamino-1,3,5-triazines of formula (I) in which R1 is, for example, H or C¿1?-C6-alkyl, R?2¿ is, for example, H, C¿1?-C6-alkyl or -CO-R?6, R3¿ is, for example, C¿1?-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl or C3-C6-cycloalkyl, R?4¿ is, for example, H, C¿1?-C6-alkyl, or C3-C6-cycloalkyl, R?5¿ stands for one of the groups (a) or (b), in which R6 is C1-C6-alkyl, C1-C6-alkoxy or C2-C6-alkenyl, R?7 to R12¿ are, for example, H or certain organic radicals and Q stands for O or S. The invention also relates to a method and new intermediaries for the production of these compounds, and their use as herbicides.
摘要:
The invention concerns novel methoximinomethyldioxazines of formula (I), a plurality of processes for their preparation, and their use as fungicides, as well as novel intermediate products and a process for their preparation.
摘要:
The invention relates to novel substituted 2-amino-4-alkylamino-1,3,5-triazines of formula (I), in which R1 stands for respectively optionally substituted alkyl with 2 to 6 carbon atoms or cycloalkyl with 3 to 6 carbon atoms, R2 stands for hydrogen or alkyl with 1 to 4 carbon atoms, A for oxygen or methylene, Ar for respectively optionally substituted phenyl, naphthyl or heterocycyl, and Z for hydrogen, for halogen or for respectively optionally substituted alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, alkenyl or alkinyl, methods and new intermediate products for their production and their use as herbicides.
摘要:
A new process is disclosed for preparing (R)-amines having the formula (I), in which R1, R2 and n have the meanings given in the description. For that purpose, racemic N-acyl-amines having the formula (II), in which R?1, R2, R3¿ and n have the meanings given in the description, are reacted with lipases capable of splitting the (R)-enantiomers of N-acyl-amines having the formula (II), in the presence of water and optionally in the presence of an organic diluting agent at a pH value from 3,0 to 10,0 and at temperatures from 0 °C to 80 °C.
摘要:
The disclosure concerns fluoromethoxyacrylic acid derivatives of formula (I), in which Ar stands for substituted aryl and Q for optionally substituted alkoxy, and the use of these compounds as pest-control agents. The disclosure also relates to a process for producing the compounds of formula (I) as well as novel intermediate products and a number of processes for producing them.