摘要:
The present invention provides a process for producing molded articles of a polyimide precursor by the use of a usual extrusion technique, and physical properties of polyimide products prepared by the heat treatment of the molded articles of the polyimide precursor at 400°C are excellent. This process is characterized by drying a solid obtained by pouring a dilute solution of a polyimide precursor comprising an aromatic tetracarboxylic acid component and an aromatic diamine component in a bad solvent to obtain a dry solid having a polyimide precursor concentration of 50-70% by weight, and then extruding this dry solid at 80-130°C.
摘要:
In a process for producing a flexible printed base by directly coating a copper foil with a polyimide precursor, followed by heating, drying and curing the precursor; the curing is effected under an inert gas, under a tension of 0.02 to 0.2 Kg/cm, and at a temperature of 200°C to 450°C.
摘要:
A printing ink composition comprises (i) a polyamide-acid (A); (ii) a partially imidized polyamide-acid (B) containing repeating units of the formulae (I), (II) and (III);
(in which R¹ is a tetravalent organic group and R² a divalent organic group); and (iii) a solvent; in which composition (a) the weight ratio of the polyamide-acid (A) to the partially imidized polyamide-acid (B) [(A)/(B)] is from 0/1 to 100/1; and (b) the total amount of the polyamide-acid (A) and the partially imidized polyamide-acid (B) is 5-50% by weight of the total amount of the polyamide-acid (A), the partially imidized polyamide-acid (B) and the solvent.
摘要:
A solvent-soluble polyimide having a low elastic modulus comprises from 60 to 99 mol % of repeating units of the formula: (in which Ar is a tetravalent aromatic group; the groups X and Y are each independently a C₁-C₄ alkyl group, a halogen atom, a carbonyl group or a hydroxyl group; and ℓ and m are each 0, 1, 2 and 3); and from 1 to 40 mol % of repeating units of formula: (in which R¹ is a C₃-C₅ alkylene group or a phenylene group; R² is a C₁-C₄ alkyl group or a phenyl group; and n is an integer of 20 to 300). The polyimide is produced by reacting an appropriate aromatic diamine, silicone diamine and aromatic tetracarboxylic acid dianhydride in an organic polar solvent at 20 to 250°C.
摘要:
Terpolymers of propylene (as a main monomer), ethylene and another a-olefin having superior and well-balanced physical properties, are produced substantially without forming soluble polymer by preliminarily activating a catalyst consisting of a titanium trichloride component and a specified organoaluminium halide, with a small amount of an a-olefin of 2 to 12 carbon atoms, a trialkylaluminium and an aromatic ester, and copolymerizing specified amounts of propylene, ethylene and an α-olefin of 4 to 12 carbon atoms in the presence of the preliminarily activated catalyst.