FLUORINATED CARBOXYLIC ACID SALT COMPOUND
    1.
    发明公开

    公开(公告)号:EP4212503A1

    公开(公告)日:2023-07-19

    申请号:EP21866696.4

    申请日:2021-09-06

    摘要: A method for producing a compound represented by formula (P1): (B 1f ) mp (A 1 ) np ,
    wherein
    B 1f is RfCOO,
    Rf is a hydrocarbon having one or more fluorine atoms,
    A 1 is a group excluding H,
    mp is (valence of A 1 ) x np and is 1 or 2,
    np is mp/(valence of A 1 ) and is 1,
    A 1 has a valence of 1 or 2,

    the method comprising step A of reacting
    a compound represented by formula (S1): (B 1f ) (R 1 ),
    wherein
    B 1f is as defined above, and
    R 1 is an organic group,
    and

    a compound represented by formula (S2) : (A 1 ) ms2 (B 2 ) ns2 ,
    wherein
    A 1 is as defined above,
    B 2 is OH, CO 3 , or HCO 3 ,
    ms2 is (valence of B 2 ) x ns2/ (valence of A 1 ) and is 1 or 2, and
    ns2 is (valence of A 1 ) x ms2/ (valence of B 2 ) and 1 or 2,
    or a hydrate thereof.


    Such a method is a novel production method of a fluorinated carboxylic acid salt compound (preferably a fluorinated carboxylic acid salt compound having a low water content).

    METHOD FOR MANUFACTURING FLUOROACETIC ACID ESTER

    公开(公告)号:EP4053098A1

    公开(公告)日:2022-09-07

    申请号:EP20880470.8

    申请日:2020-10-30

    IPC分类号: C07C67/307 C07C69/63

    摘要: An object of the present disclosure is to provide a method for producing a fluoroacetic acid ester with excellent economic efficiency, quality, and productivity.
    The object can be solved by a method for producing a compound represented by formula (1):

    wherein
    R is an organic group,
    the method comprising:
    the step of reacting a compound represented by formula (2):
    wherein
    X is a leaving group other than fluorine, and R is as defined above,
    with a compound represented by formula (3):

            MF n      (3)

    wherein
    M is a cation and n is an integer corresponding to the valence of the cation,
    wherein
    the compound represented by formula (3) is used in an amount of 0.9 moles or less per mole of the compound represented by formula (2) .

    PRODUCTION METHOD OF ACRYLIC ACID DERIVATIVE

    公开(公告)号:EP4212508A1

    公开(公告)日:2023-07-19

    申请号:EP21866851.5

    申请日:2021-09-10

    IPC分类号: C07C67/30 C07C69/653

    摘要: An object of the present disclosure is to provide a novel method for producing an acrylic acid derivative at a high conversion rate and a high yield.
    The object can be achieved by a method for producing an acrylic acid derivative represented by formula (1):

    wherein
    R 1 represents hydrogen or the like;
    R 3 represents hydrogen or the like; and
    X represents hydrogen or the like,
    the method comprising step B of bringing an organic metal compound represented by formula (A3A):
    wherein
    R 2 , in each occurrence, is the same or different and represents hydrogen or like;
    R 3 represents hydrogen or the like;
    X represents hydrogen or the like; and
    M represents hydrogen or the like, or
    an organic metal compound represented by formula (A3B):
    wherein the symbols are as defined above, or
    a combination thereof, into contact with a proton donor and an aldehyde compound to obtain a compound represented by formula (1).

    METHOD FOR PRODUCING PROPIONIC ACID DERIVATIVE

    公开(公告)号:EP4039673A1

    公开(公告)日:2022-08-10

    申请号:EP20871963.3

    申请日:2020-09-29

    摘要: An object of the present invention is to provide a method for producing a propionic acid derivative with high productivity. The object can be achieved by a method for producing a compound represented by formula (1):

    wherein R 1 is a halogen atom or the like, R 2 and R 3 are each independently a hydrogen atom, a halogen atom, or an organic group, X is an oxygen atom or a sulfur atom, R 4 and R 5 are each independently a hydrogen atom, a halogen atom, or a hydrocarbon group optionally having one or more substituents, R 6 is a hydrocarbon group optionally having one or more substituents; the method comprising step A of reacting a compound represented by formula (2):

    with a compound represented by formula (3):
    M(R 1 ) n , wherein M is a cation, n is an integer corresponding to the valence of M, and a compound represented by formula (4):

            R 6 -X-H;

    and
    step B of separating, by filtration, the compound represented by formula (5): MF n from the mixture obtained by the above reaction.