摘要:
An object of the present invention is to provide a dispersion assistant that, when used for suspension polymerization of a vinyl-based compound, achieves stable production of a good polymer (vinyl-based resin) without much scale adhesion on the polymerization tank even in the cases where used in a large amount. Provided is a dispersion assistant for suspension polymerization, which comprises a polyvinyl alcohol-based polymer (A) having an acetal group (a) having an olefinic unsaturated double bond, the polymer having a saponification degree of 60 mol% or less.
摘要:
A stable aqueous film forming dispersion comprising: a polymer selected from the group consisting of: polyvinyl butyral, polyvinyl acetyl, ethylene vinyl acetate, vinyl acetate and mixtures thereof: a plasticiser; an emulsifier; and a water soluble organometallic crosslinking agent.
摘要:
A polyvinylacetal resin powder with a low metal content, being excellent in transparency, moisture resistance and electrical insulating properties and having a large specific surface area, and a process for its production, are presented. A polyvinylacetal resin powder obtained by reacting polyvinyl alcohol and an aldehyde in the presence of an acid catalyst, which has an acetalization degree of at least 60 mol%, a specific surface area of from 1.50 to 3.50 m /g, a bulk density of from 0.12 to 0.19 g/cm , an average particle diameter of from 0.5 to 2,5 mu m and a metal content of at most 80 ppm. It is produced, for example, by feeding a reaction fluid containing polyvinyl alcohol, an aldehyde and an acid catalyst into a first reactor, to carry out an acetalization reaction, discharging the reaction fluid wherein the acetalization degree has reached from 10 to 60 mol%, and feeding the same into a second reactor to carry out a further reaction to bring the acetalization degree of polyvinylacetal to at least 65 mol%.
摘要:
An object of the present disclosure is to provide a method for producing a fluorine-containing polymer and a composition containing the fluorine-containing polymer. The present disclosure provides a composition comprising (A) a fluorine-containing polymer comprising as a main component a structural unit containing a fluorine-containing aliphatic ring, and (B) an aprotic solvent, wherein the fluorine-containing aliphatic ring of the fluorine-containing polymer (A) contains one, two, or three etheric oxygen atoms as a ring-constituting atom; when the fluorine-containing aliphatic ring contains a plurality of etheric oxygen atoms, the etheric oxygen atoms are not adjacent to each other; and the fluorine-containing polymer (A) is present in an amount of 20 mass% or more based on the mass of the composition.
摘要:
The present invention provides an intermediate film for laminated glass which can improve the sound-insulating property. The intermediate film for laminated glass according to the present invention has a layered structure including at least two layers, comprising: a first layer containing a polyvinyl acetal resin and a plasticizer; and a second layer positioned on a first surface of the first layer. In a phase diagram of three values including a degree of acetalization, a degree of acetylation, and a hydroxy group content of the polyvinyl acetal resin contained in the first layer, the values of the degree of acetalization, the degree of acetylation, and the hydroxy group content each fall within a region surrounded by a line including four straight lines connecting a first coordinate (degree of acetalization:degree of acetylation:hydroxy group content = 70 mol%: 30 mol%: 0 mol%), a second coordinate (degree of acetalization:degree of acetylation:hydroxy group content = 34 mol%:30 mol%:36 mol%), a third coordinate (degree of acetalization:degree of acetylation:hydroxy group content = 94 mol%: 0 mol%:6 mol%), and a fourth coordinate (degree of acetalization:degree of acetylation:hydroxy group content = 100 mol%: 0 mol%: 0 mol%) in the stated order.
摘要:
Polymer particles including a covalently bonded chemical species, as well as related compositions and methods are disclosed. In one aspect, the invention features a particle that includes a polymer a chemical species covalently bonded to the polymer. The polymer includes vinyl alcohol monomer units, and the chemical species is selected from polymers, oligomers and monomers. The particle has a maximum dimension of 5,000 microns or less. In another aspect, the invention features a particle that includes a polymer, a chemical species covalently bonded to the polymer and a therapeutic agent. The polymer includes at least five weight percent vinyl alcohol monomer units and at least five weight percent vinyl formal monomer units. The chemical species is selected from polymers, oligomers and monomers and the particle has a maximum dimension of 5,000 microns or less.
摘要:
The pressure-sensitive adhesive film of the present invention comprises a thermoplastic resin and has a thickness of 150 µm or more and 2000 µm or less, in which an amount of change in thickness of a test sample A in a predetermined compression creep test performed is 50 µm or more and 325 µm or less, and an adhesive force to a polycarbonate base material, as measured by a predetermined pressure-sensitive adhesive force measurement method, is 100 N or more. The laminate of the present invention comprises the pressure-sensitive adhesive film of the present invention, a first organic material substrate, and at least one base material of second organic material substrate and inorganic material substrate. The liquid crystal display of the present invention and the laminated glass of the present invention each comprises the laminate of the present invention. According to the present invention, there can be provided a pressure-sensitive adhesive film, a laminate comprising the pressure-sensitive adhesive film, and a liquid crystal display and a laminated glass each comprising the laminate, in which a transparency in low-temperature sticking is favorable, foaming in an end portion in low-temperature sticking is small, and adhesiveness to a resin material such as a polarization film is favorable.
摘要:
There is provided a binder for ceramic formation or a conductive paste, comprising polyvinyl acetal having a degree of acetalization of from 50 to 85 mol%, a content of vinyl ester monomer unit of from 0.1 to 20 mol%, and having a viscosity-average degree of polymerization of from 200 to 5000, wherein a peak-top molecular weight (A) as measured by a differential refractive index detector and a peak-top molecular weight (B) as measured by an absorptiometer (measurement wavelength: 280 nm) in gel permeation chromatographic measurement of the polyvinyl acetal heated at 230°C for 3 hours satisfy a formula (1) (A-B)/A -3 to 1.00 × 10 -2 .
摘要翻译:提供了一种用于陶瓷的形成或导电膏的粘合剂,其包括具有一定程度的为50〜85摩尔%,从0.1至20摩尔%的醋酸乙烯酯单体单元的含量,缩醛化的聚乙烯醇缩醛和具有的粘均 (:280nm处测定波长)作为在吸光光度计的测量通过在200至5000的聚合,worin作为测量通过使用差示折射率检测器和峰顶分子量(B)一个峰顶分子量(A)的程度 在230℃下加热3小时,聚乙烯醇缩醛的凝胶渗透色谱测量满足式(1)(AB)/ A <0.60和聚乙烯醇缩醛具有从0:50×在的峰顶分子量(B)与吸光度 10 -3〜1点×10 -2。
摘要:
There is provided a binder for ceramic formation or a conductive paste, comprising polyvinyl acetal having a degree of acetalization of from 50 to 85 mol%, a content of vinyl ester monomer unit of from 0.1 to 20 mol%, and having a viscosity-average degree of polymerization of from 200 to 5000, wherein a peak-top molecular weight (A) as measured by a differential refractive index detector and a peak-top molecular weight (B) as measured by an absorptiometer (measurement wavelength: 280 nm) in gel permeation chromatographic measurement of the polyvinyl acetal heated at 230°C for 3 hours satisfy a formula (1) (A-B)/A -3 to 1.00 × 10 -2 .
摘要:
An in situ method of preparing modified polyvinyl acetals is described with the aim of improving the alcohol tolerance while retaining barrier properties of the base polymer.