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    Cyclic hydrocarbon derivative and liquid crystal composition containing the same
    6.
    发明公开
    Cyclic hydrocarbon derivative and liquid crystal composition containing the same 失效
    Zyclisches Kohlenwasserstoffderivat sowie eine dieses enthaltendeFlüssigkristallzusammensetzung。

    公开(公告)号：EP0637623A1

    公开(公告)日：1995-02-08

    申请号：EP94111448.0

    申请日：1994-07-22

    申请人： DAINIPPON INK AND CHEMICALS, INC.

    发明人： Takatsu, Haruyoshi ,  Takehara, Sadao ,  Takeuchi, Kiyohumi ,  Osawa, Masashi ,  Ogawa, Shinji ,  Ishida, Norie

    IPC分类号： C09K19/04 ,  C09K19/30 ,  C07B59/00 ,  C07C255/50 ,  C07C43/20 ,  C07C25/18

    CPC分类号： C09K19/402 ,  C07B59/001 ,  C07C255/50 ,  C07C255/55 ,  C07C2601/14 ,  C09K19/3001 ,  C09K19/3003 ,  C09K19/3028 ,  C09K19/3059 ,  C09K2019/0444

    摘要： A novel cyclic hydrocarbon derivative is disclosed, which is represented by formula (I):

    wherein Y¹ and Y² each independently represent a fluorine atom, a chlorine atom, a cyano group, a cyanato group (OCN), a thiocyanato group (SCN), a trifluoromethoxy group (OCF₃), a difluoromethoxy group (OCF₂H), a 2,2,2-trifluoroethoxy group (OCH₂CF₃), a trifluoromethyl group (CF₃), R, -OR, -COOR or -OCOR, wherein R represents an alkyl group having from 1 to 20 carbon atoms, an alkenyl group having from 2 to 20 carbon atoms or an alkoxylalkyl group having from 2 to 20 carbon atoms, provided that at least one of Y¹ and Y² represents R, -OR, -COOR or -OCOR; Z, Z¹, Z², Z³, and Z⁴ each independently represent a single bond, -CH₂CH₂-, -CH=CH-, -C≡C-, -COO-, -OCO-, -CH₂O-, -OCH₂-, -(CH₂)₄-, -(CH₂)₃-O- or -O-(CH₂)₃-; ring A represents a group of formula (II):

    wherein X¹, X², X³, X⁴, X⁵, X⁶, X⁷, X⁸, X⁹, and X¹⁰ each independently represent a hydrogen atom (H) or a deuterium atom (D), provided that at least one of them represents a deuterium atom (D); rings K, L, J, M and N each independently represent a trans-1,4-cyclohexylene group, a 1,4-cyclohexenylene group, a trans-1,4-cyclohexylene group substituted with 1 to 4 substituents selected from a fluorine atom and a cyano group, a 1,4-phenylene group, a 1,4-phenylene group substituted with 1 to 4 substituents selected from a fluorine atom, a chlorine atom, a cyano group and a methyl group, a 1,3-dioxane-2,6-diyl group, a pyrimidine-2,5-diyl group, a pyridine-2,5-diyl group, a pyrazine-2,5-diyl group or a group of formula (III):

    wherein X¹¹, X¹², X¹³, X¹⁴, X¹⁵, X¹⁶, X¹⁷, X¹⁸, X¹⁹, and X²⁰ each independently represent a hydrogen atom (H) or a deuterium atom (D), provided that at least one of them represents a deuterium atom (D); in which the ring of formula (III) may be the same or different with ring A; and k, l, m, and n each independently represent 0 or 1, provided that the sum of k, l, m, and n is 0, 1 or 2. The compound of the present invention is useful as an electro-optic liquid crystal display material.

    摘要翻译： 公开了由式（I）表示的新型环状烃衍生物：其中Y 1和Y 2各自独立地表示氟原子，氯原子，氰基，氰基（OCN） ），硫氰酸酯基（SCN），三氟甲氧基（OCF 3），二氟甲氧基（OCF2H），2,2,2-三氟乙氧基（OCH 2 CF 3），三氟甲基（CF 3），R，-OR，-COOR 或-OCOR，其中R表示具有1至20个碳原子的烷基，具有2至20个碳原子的烯基或具有2至20个碳原子的烷氧基烷基，条件是Y 1， 并且Y 2表示R，-OR，-COOR或-OCOR; Z，Z 1，Z 2，Z 3和Z 4各自独立地表示单键，-CH 2 CH 2 - ， - CH = CH - ， - C 1 - C 1 -C 30 - OCO - ， - CH 2 O - ， - OCH 2 - ， - （CH 2）4 - ， - （CH 2）3 -O-或-O-（CH 2） 环A表示式（II）的基团：其中X 1，X 2，X 3，X 4，X 5，X 6，X 7， X 8，X 9和X 1各自独立地表示氢原子（H）或氘原子（D），条件是它们中的至少一个表示氘原子（D）。 环K，L，J，M和N各自独立地表示反式-1,4-亚环己基，1,4-亚环己烯基，被1〜4个选自氟的取代基取代的反式-1,4-亚环己基 原子和氰基，1,4-亚苯基，被1〜4个选自氟原子，氯原子，氰基和甲基的取代基取代的1,4-亚苯基， 二恶烷-2,6-二基，嘧啶-2,5-二基，吡啶-2,5-二基，吡嗪-2,5-二基或式（III）的基团： 其中X 1，X 1，X 1，X 1，X 4，X 1，X 1，X 6，X X 1，X 1，X 1，9和X 2各自独立地表示氢原子（H）或氘原子（D），条件是 其中至少一个表示氘原子（D）; 其中式（III）的环可以与环A相同或不同; 并且k，l，m和n各自独立地表示0或1，条件是k，l，m和n的和为0,1或2.本发明的化合物可用作电光液体 水晶显示材料。

    Novel lactic acid derivatives and liquid crystal compositions containing the same
    7.
    发明公开
    Novel lactic acid derivatives and liquid crystal compositions containing the same 失效
    MilchsäurederivatundFlüssigkristallzusammensetzungmit diesem Derivat。

    公开(公告)号：EP0329153A2

    公开(公告)日：1989-08-23

    申请号：EP89102756.7

    申请日：1989-02-17

    申请人： DAINIPPON INK AND CHEMICALS, INC. ,  KAWAMURA INSTITUTE OF CHEMICAL RESEARCH

    发明人： Takehara, Sadao ,  Shoji, Tadao ,  Ogawa, Hiroshi ,  Fujisawa, Toru ,  Osawa, Masashi

    IPC分类号： C09K19/12 ,  C09K19/20 ,  C07C69/90 ,  C07C69/732

    CPC分类号： C09K19/126 ,  C09K19/2021

    摘要： compound represented by formula (I):
    wherein R 1 represents an alkyl group having from 1 to 18 carbon atoms; R 2 represents an alkyl group having from 2 to 16 carbon atoms; rings A, B, C, and D each represents a 1,4-phenylene group or a 1,4-phenylene group having one or two halogen atoms; Y represents a single bond,
    m and n each represents 0 or 1; p represents 0, 1, or 2; q represents 0 or an integer of from 1 to 6; and C * and C" each represents an asymmetric carbon atom in an (S)- or (R)-configuration, and a liquid crystal composition containing the compound of formula (I). The compound of formula (I) is a chiral liquid crystal compound exhibiting large spontaneous polarization, a long helical pitch, an SC * phase in a broad temperature range including room temperature, satisfactory orientation, and a high rate of response.

    摘要翻译： 由式（I）表示的化合物：其中R 1表示具有1至18个碳原子的烷基; R2表示具有2至16个碳原子的烷基; 环A，B，C和D各自表示具有一个或两个卤素原子的1,4-亚苯基或1,4-亚苯基; Y表示单键， - @ -O-或-O- m和n各自表示0或1; p表示0,1或2; q表示0或1至6的整数; 和C *和C **分别表示（S） - 或（R） - 构型中的不对称碳原子，和含有式（I）化合物的液晶组合物。 式（I）化合物是在包括室温，令人满意的取向和高反应率的宽温度范围内表现出大的自发极化，长螺距，SC *相的手性液晶化合物。

    Naphthalene derivative and liquid crystal composition comprising the same
    8.
    发明公开
    Naphthalene derivative and liquid crystal composition comprising the same 有权
    Naphthalin-Derivat und dieses enthaltendeflüssigkristallineZusammensetzung

    公开(公告)号：EP1452514A1

    公开(公告)日：2004-09-01

    申请号：EP02024918.1

    申请日：1999-04-22

    申请人： DAINIPPON INK AND CHEMICALS, INC.

    发明人： Takehara, Sadao ,  Osawa, Masashi ,  Takatsu, Haruyoshi ,  Negishi, Makoto

    IPC分类号： C07C25/22 ,  C09K19/32 ,  C07C25/24 ,  C07C43/225 ,  C07C43/257 ,  C07C255/50 ,  C07C17/26 ,  C07C17/354

    CPC分类号： C07C17/2637 ,  C07C17/263 ,  C07C17/2632 ,  C07C17/2635 ,  C07C17/269 ,  C07C17/354 ,  C07C25/18 ,  C07C25/22 ,  C07C25/24 ,  C07C255/50 ,  C07C2601/14 ,  C07C2602/28 ,  C09K19/322 ,  Y10T428/10

    摘要： Disclosed is a novel liquid-crystalline compound which is a naphthalene derivative useful as an electro-optical liquid crystal display material, a liquid crystal composition containing such naphthalene derivatives and a liquid crystal display device comprising the same. The naphthalene derivative provided by the present invention exhibits an excellent liquid-crystallinity and miscibility with currently widely used liquid crystal compositions or compositions. The addition of the naphthalene derivative makes it possible to drastically lower the threshold voltage of the liquid crystal composition while maintaining its high response. The naphthalene derivative of the present invention is characterized by a large birefringence index. Further, most of the naphthalene derivative of the present invention has no strongly polar group in its molecule and thus can also be used for active matrix driving. Moreover, as shown in the foregoing examples, the naphthalene derivative of the present invention can be easily produced and is colorless and chemically stable. Accoardingly, the liquid crystal composition comprising the naphthalene derivative of the present invention is extremely useful as a practical liquid crystal camposition, particularly a liquid crystal composition which can operate within a wide temperature range and requires a high speed response and a low voltage driving.

    摘要翻译： 公开了一种新颖的液晶化合物，它是一种可用作电光液晶显示材料的萘衍生物，含有该衍生物的液晶组合物和包含该衍生物的液晶显示装置。 由本发明提供的萘衍生物与当前广泛使用的液晶组合物或组合物显示出优异的液晶性和混溶性。 通过添加萘衍生物，可以使液晶组合物的阈值电压急剧降低，同时保持其高响应性。 本发明的萘衍生物的特征在于双折射率大。 此外，本发明的大部分萘衍生物在其分子中没有强极性基团，因此也可用于有源矩阵驱动。 此外，如前述实施例所示，本发明的萘衍生物可以容易地制备，并且是无色和化学稳定的。 特别是含有本发明的萘衍生物的液晶组合物作为实用的液晶位置，特别是能够在宽温度范围内工作并需要高速响应和低电压驱动的液晶组合物是非常有用的。

    Naphthalene derivative and liquid crystal composition comprising the same
    9.
    发明公开
    Naphthalene derivative and liquid crystal composition comprising the same 有权
    in in ung ung ung ung ung ung ung ung ung ung ung ung ung ung ung ung ung

    公开(公告)号：EP1273562A1

    公开(公告)日：2003-01-08

    申请号：EP02022912.6

    申请日：1999-04-22

    申请人： DAINIPPON INK AND CHEMICALS, INC.

    发明人： Takehara, Sadao ,  Osawa, Masashi ,  Takatsu, Haruyoshi ,  Negishi, Makoto

    IPC分类号： C07C25/22 ,  C09K19/32 ,  C07C25/24 ,  C07C43/225 ,  C07C43/257 ,  C07C255/50 ,  C07C17/26 ,  C07C17/354

    CPC分类号： C07C17/2637 ,  C07C17/263 ,  C07C17/2632 ,  C07C17/2635 ,  C07C17/269 ,  C07C17/354 ,  C07C25/18 ,  C07C25/22 ,  C07C25/24 ,  C07C255/50 ,  C07C2601/14 ,  C07C2602/28 ,  C09K19/322 ,  Y10T428/10

    摘要： Disclosed is a novel liquid-crystalline compound which is a naphthalene derivative useful as an electro-optical liquid crystal display material, a liquid crystal composition containing such naphthalene derivatives and a liquid crystal display device comprising the same. The naphthalene derivative provided by the present invention exhibits an excellent liquid-crystallinity and miscibility with currently widely used liquid crystal compositions or compositions. The addition of the naphthalene derivative makes it possible to drastically lower the threshold voltage of the liquid crystal composition while maintaining its high response. The naphthalene derivative of the present invention is characterized by a large birefringence index. Further, most of the naphthalene derivative of the present invention has no strongly polar group in its molecule and thus can also be used for active matrix driving. Moreover, as shown in the foregoing examples, the naphthalene derivative of the present invention can be easily produced and is colorless and chemically stable. Accordingly, the liquid crystal composition comprising the naphthalene derivative of the present invention is extremely useful as a practical liquid crystal composition, particularly a liquid crystal composition which can operate within a wide temperature range and requires a high speed response and a low voltage driving.

    摘要翻译： 公开了一种新颖的液晶化合物，它是一种可用作电光液晶显示材料的萘衍生物，含有该衍生物的液晶组合物和包含该衍生物的液晶显示装置。 由本发明提供的萘衍生物与当前广泛使用的液晶组合物或组合物显示出优异的液晶性和混溶性。 通过添加萘衍生物，可以使液晶组合物的阈值电压急剧降低，同时保持其高响应性。 本发明的萘衍生物的特征在于双折射率大。 此外，本发明的大部分萘衍生物在其分子中没有强极性基团，因此也可用于有源矩阵驱动。 此外，如前述实施例所示，本发明的萘衍生物可以容易地制备，并且是无色和化学稳定的。 因此，包含本发明的萘衍生物的液晶组合物作为实用的液晶组合物，特别是能够在宽温度范围内工作并需要高速响应和低电压驱动的液晶组合物是非常有用的。