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公开(公告)号：EP3431517B1
公开(公告)日：2020-11-04
申请号：EP17766751.6
申请日：2017-03-15
发明人： KAWABE, Rumi , FUKUMORI, Masaki , HARA, Ryosuke , MIYAHARA, Masahiro , MINAMI, Shinichi , YAMAMOTO, Ikuo , MITTA, Yasuhiro , MITAKE, Akifumi
IPC分类号： C08F20/12 , C08F14/06 , C08F14/08 , C08F259/02 , C08F259/06 , C09K3/18 , D06M15/263 , C08F214/06 , C08F214/08 , C09D133/06
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公开(公告)号：EP4116342A1
公开(公告)日：2023-01-11
申请号：EP21764613.2
申请日：2021-03-05
IPC分类号： C08F220/22 , C08K5/02 , C08L27/04 , C08L33/04 , C08L33/16 , D06M15/277
摘要： Provided is a dispersion having both product stability and water repellency and/or oil repellency, and comprising a fluorine-containing polymer and a liquid medium, wherein: the fluorine-containing polymer has a Q value of at least 2.0 and contains a repeating unit derived from a fluorine-containing monomer (a) containing a fluoroalkyl group, and a repeating unit derived from a chloride monomer (b), which is at least one selected from among vinyl chloride and vinylidene chloride; and the concentration of the unreacted chloride monomer (b) is at most 2.0 ppm.
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公开(公告)号：EP2331595B1
公开(公告)日：2016-05-18
申请号：EP09788070.2
申请日：2009-09-11
发明人： MINAMI, Shinichi , ENOMOTO, Takashi , MASUTANI, Tetsuya , MIYAHARA, Masahiro , USUGAYA, Mitsuhiro , TAKEUCHI, Rumi , YAMAMOTO, Ikuo , HUPFIELD, Peter Cheshire
IPC分类号： C08F283/12 , C08F290/06 , D06M15/356 , D06M15/643 , D06M15/277
CPC分类号： D06M15/6436 , C08F283/122 , C08F290/068 , D06M15/277 , D06M15/3568 , Y10T442/2172 , C08F220/24 , C08F220/68
摘要： A surface treatment agent, which can impart the excellent water- and oil-repellency, soil resistance and feeling to the substrate, is obtained from a fluorine-containing polymer which contains: (A) a monomer which comprises; (A1) a fluorine-containing monomer of the formula: CH2═C(—X)—C(═O)—Y—Z—Rf wherein X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is —O— or —NH—, Z is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 1 to 20 carbon atoms, and (A2) a (meth)acrylate monomer having a cyclic hydrocarbon group, and (B) at least one functional organopolysiloxane selected from the group consisting of a mercapto-functional organopolysiloxane, a vinyl-functional organopolysiloxane, a (meth)acrylamide-functional organopolysiloxane and a (meth)acrylate-functional group.
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公开(公告)号：EP2331595A1
公开(公告)日：2011-06-15
申请号：EP09788070.2
申请日：2009-09-11
发明人： MINAMI, Shinichi , ENOMOTO, Takashi , MASUTANI, Tetsuya , MIYAHARA, Masahiro , USUGAYA, Mitsuhiro , TAKEUCHI, Rumi , YAMAMOTO, Ikuo , HUPFIELD, Peter Cheshire
IPC分类号： C08F283/12 , C08F290/06 , D06M15/277 , D06M15/356
CPC分类号： D06M15/6436 , C08F283/122 , C08F290/068 , D06M15/277 , D06M15/3568 , Y10T442/2172 , C08F220/24 , C08F220/68
摘要： A surface treatment agent, which can impart the excellent water- and oil-repellency, soil resistance and feeling to the substrate, is obtained from a fluorine-containing polymer which contains: (A) a monomer which comprises; (A1) a fluorine-containing monomer of the formula: CH2═C(—X)—C(═O)—Y—Z—Rf wherein X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is —O— or —NH—, Z is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 1 to 20 carbon atoms, and (A2) a (meth)acrylate monomer having a cyclic hydrocarbon group, and (B) at least one functional organopolysiloxane selected from the group consisting of a mercapto-functional organopolysiloxane, a vinyl-functional organopolysiloxane, a (meth)acrylamide-functional organopolysiloxane and a (meth)acrylate-functional group.
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5.发明公开
公开(公告)号：EP4083078A1
公开(公告)日：2022-11-02
申请号：EP20905561.5
申请日：2020-12-21
发明人： KOUDA, Chikako , FUKUDA, Kazuyuki , NAKAMURA, Keisuke , NOGUCHI, Daisuke , MIYAHARA, Masahiro , KAWABE, Rumi , MINAMI, Shinichi
IPC分类号： C08F16/28 , C08F20/68 , C08F20/70 , C08L29/10 , C08L33/04 , C08L75/04 , C09K3/18 , C08G18/28 , C08G18/36 , D06M15/21 , D06M15/263 , D06M15/564 , D06M15/643
摘要： A water repellent composition includes a polyurethane resin compound, a non-fluorine water repellent compound, a surfactant, and a liquid medium. The polyurethane resin compound includes at least one kind selected from the group consisting of a first polyurethane resin compound, a second polyurethane resin compound, and a third polyurethane resin compound:
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公开(公告)号：EP3015480B1
公开(公告)日：2019-11-06
申请号：EP14817619.1
申请日：2014-06-18
IPC分类号： C08F220/22 , C09K3/18
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公开(公告)号：EP3015480A1
公开(公告)日：2016-05-04
申请号：EP14817619.1
申请日：2014-06-18
IPC分类号： C08F220/22 , C09K3/18
摘要： The present invention provides a fluorine-containing polymer having (a) a repeating unit derived from a fluorine-containing monomer indicated by the formula CH 2 =C(-X)-C(=O)-Y Z-Rf, (b) a repeating unit derived from a cyclic-hydrocarbon-group-containing acrylate ester monomer indicated by the formula CH 2 =CQ 11 -C(=O)-O-Q 12 , and (c) a repeating unit derived from an aliphatic-hydrocarbon-group-containing acrylate ester monomer indicated by the formula CH 2 =CQ 21 -C(=O)-O-Q 22 , wherein the fluorine-containing polymer is produced by polymerizing in the presence of one or both of (d) a silicon-containing monomer and a silicon-containing chain transfer agent. The fluorine-containing polymer provides a surface treatment agent that has superior water repellency and oil repellency, and that is such that the fluorine-containing polymer has superior solubility in the surface treatment agent.
摘要翻译： 本发明提供具有（a）由式CH 2 = C（-X）-C（= O）-Y Z-Rf表示的含氟单体衍生的重复单元的含氟聚合物，（b） 由式CH 2 = CQ 11 -C（= O）-OQ 12表示的含环状烃基的丙烯酸酯单体的重复单元，（c）衍生自脂肪族烃基的重复单元 由式CH 2 = CQ 21 -C（= O）-OQ 22表示的丙烯酸酯单体，其中所述含氟聚合物通过在（d）含硅单体中的一种或两种的存在下聚合来制备， 和含硅链转移剂。 含氟聚合物提供了具有优异的拒水性和拒油性的表面处理剂，并且使得含氟聚合物在表面处理剂中具有优异的溶解性。
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公开(公告)号：EP3564335A1
公开(公告)日：2019-11-06
申请号：EP17885782.7
申请日：2017-12-20
IPC分类号： C09K3/18 , C08F220/10 , D06M15/27
摘要： Provided is a water- and oil-repellent agent that is an aqueous dispersion containing (A) a non-fluoropolymer having repeating units derived from a non-fluorine (meth)acrylic acid ester monomer, (B) a wax, (C) an aqueous medium, and (D) an emulsifier, wherein said water- and oil-repellent agent exhibits exceptional water- and oil-repellent processing stability without using a fluoromonomer, or in particular, a fluoroalkyl-group-containing monomer, by using a water- and oil-repellent agent, in which the non-fluorine (meth)acrylic acid ester monomer is a compound represented by the formula CH 2 =CA 11 -C(=O)-O-A 12 (where A 11 is a hydrogen atom or a methyl group and A 12 is a linear or branched C 18-30 hydrocarbon group).
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公开(公告)号：EP2829572A1
公开(公告)日：2015-01-28
申请号：EP13764577.6
申请日：2013-03-19
发明人： KAWABE, Rumi , HARA, Ryousuke , MIYAHARA, Masahiro , FUKUMORI, Masaki , KUBOTA, Kouji , MOHARA, Kensuke , ENOMOTO, Takashi
IPC分类号： C08L33/16 , B01F17/16 , B01F17/22 , B01F17/42 , C08K5/20 , C08L71/02 , C09K3/18 , D06M15/256
CPC分类号： C09K3/18 , B01F17/0028 , B01F17/0035 , B01F17/0042 , B01F17/0085 , C08G65/2609 , C08K5/06 , C08K5/101 , C08K5/20 , C08L33/16 , C08L71/02 , C08L2201/54 , C09D5/16 , C09D133/16 , D06M13/325 , D06M13/402 , D06M15/277 , D06M15/53 , D06M2200/01 , D06M2200/11 , D06M2200/12
摘要： Provided is an aqueous emulsion composition which has excellent chemical stability (stability with respect to impurities) and excellent mechanical stability. Disclosed is an aqueous emulsion composition which contains: (A) a polymer that contains a fluoroalkyl group; and (B) a surfactant that contains (B1) an amidoamine surfactant having an amide group and an amino group, and (B2) a nonionic surfactant. It is preferable that the surfactant does not contain a monool having an unsaturated triple bond or an alkylene oxide addition product of a polyol.
摘要翻译： 本发明提供了具有优异的化学稳定性（相对于杂质的稳定性）和优异的机械稳定性的水性乳液组合物。 公开了一种水性乳液组合物，其含有：（A）含有氟代烷基的聚合物; 和（B）含有（B1）具有酰胺基和氨基的酰氨基胺表面活性剂和（B2）非离子表面活性剂的表面活性剂。 优选表面活性剂不含具有不饱和三键的一元醇或多元醇的烯化氧加成产物。
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公开(公告)号：EP1600481B1
公开(公告)日：2011-11-09
申请号：EP04708470.2
申请日：2004-02-05
CPC分类号： C08K5/06 , C08G2650/48 , C08G2650/58 , C08L71/02 , Y10T442/2566 , C08L33/16 , C08L2666/04
摘要： An aqueous emulsion composition excellent in stabilities to impurities and mechanical action, which is obtained by adding (B) a surfactant represented by the general formula: R1O-(CH2CH2O)p-(R2O)q-R3 [wherein R1 is alkyl or alkenyl; R2 is alkylene; R3 is hydrogen, alkyl, or alkenyl; and p is a number of 2 or above and q is a number of 1 or above with the proviso that p and q must be numbers which give a polyoxyethylene block content of 5 to 80 wt% based on the whole of the molecule] to (A) an aqueous resin emulsion containing a fluoropolymer.
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