公开(公告)号：EP2790827A4

公开(公告)日：2015-09-16

申请号：EP12857054

申请日：2012-07-13

Applicant: CHEVRON USA INC

Inventor： JOTHIMURUGESAN KANDASWAMY ,  SAXTON ROBERT J ,  LACHEEN HOWARD S ,  DAS TAPAN

IPC: B01J23/75 ,  B01J23/42 ,  B01J23/46 ,  B01J23/89 ,  B01J29/04 ,  B01J29/06 ,  B01J29/74 ,  B01J29/76 ,  B01J35/00 ,  B01J37/00 ,  B01J37/03 ,  C01B3/00 ,  C10G2/00

CPC classification number: B01J29/7669 ,  B01J23/8913 ,  B01J29/043 ,  B01J29/044 ,  B01J29/045 ,  B01J29/7469 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/035 ,  B01J2229/186 ,  B01J2229/42 ,  C10G2/334 ,  C10G2/341 ,  Y02E60/324

公开(公告)号：EP2720990A4

公开(公告)日：2014-12-24

申请号：EP12799829

申请日：2012-06-14

Applicant: UT BATTELLE LLC

Inventor： NARULA CHAITANYA K ,  DAVISON BRIAN H ,  KELLER MARTIN

IPC: C07C1/20 ,  B01J29/46 ,  B01J29/48 ,  C10G3/00 ,  C12P7/06 ,  C12P7/08 ,  C12P7/10

CPC classification number: C10G3/49 ,  B01J29/061 ,  B01J29/072 ,  B01J29/076 ,  B01J29/143 ,  B01J29/146 ,  B01J29/163 ,  B01J29/166 ,  B01J29/46 ,  B01J29/48 ,  B01J29/68 ,  B01J29/69 ,  B01J29/7615 ,  B01J29/7661 ,  B01J29/7669 ,  B01J29/7692 ,  B01J29/7815 ,  B01J29/7861 ,  B01J29/7869 ,  B01J29/7892 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0246 ,  B01J2229/183 ,  B01J2229/186 ,  C07C1/22 ,  C10G3/45 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/4006 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C12P7/06 ,  C12P7/08 ,  C12P7/10 ,  C12P7/16 ,  Y02E50/10 ,  Y02E50/16 ,  Y02E50/17 ,  Y02P30/20

Abstract: A method for converting an alcohol to a hydrocarbon, the method comprising contacting said alcohol with a metal-loaded zeolite catalyst at a temperature of at least 100° C. and up to 550° C., wherein said alcohol can be produced by a fermentation process, said metal is a positively-charged metal ion, and said metal-loaded zeolite catalyst is catalytically active for converting said alcohol to said hydrocarbon.

公开(公告)号：EP2501474A4

公开(公告)日：2012-12-05

申请号：EP10831987

申请日：2010-11-04

Applicant: CHEVRON USA INC

Inventor： KIBBY CHARLES L ,  JOTHIMURUGESAN KANDASWAMY ,  DAS TAPAN K ,  SAXTON ROBERT J ,  BURTON ALLEN W JR

IPC: B01J29/46 ,  C07C1/04 ,  C07C9/00

CPC classification number: B01J29/7469 ,  B01J29/7669 ,  B01J2229/42 ,  C07C1/0435 ,  C07C2529/46 ,  C10G2/332 ,  C10G2/334 ,  C10G2300/1022 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/703 ,  C07C9/00

公开(公告)号：EP2323761A1

公开(公告)日：2011-05-25

申请号：EP09772352.2

申请日：2009-06-24

Applicant: Shell Internationale Research Maatschappij B.V.

Inventor： BALLEGOY, Carolus Maria ,  CAPTAIN, Dinyar Khushroo ,  VAN GIEZEN, Joseph Cornelis ,  KEYZER, Lucas Petrus Simon ,  NENU, Nicoleta Cristina ,  VAN VEGCHEL, Ingrid Maria

IPC: B01J29/74 ,  C07C5/27

CPC classification number: B01J29/7469 ,  B01J29/7269 ,  B01J29/7669 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/42 ,  C07C5/2754 ,  C07C5/2791 ,  C07C2529/70 ,  C07C2529/72 ,  C07C2529/74 ,  C07C2529/76 ,  Y02P20/52 ,  C07C15/08

Abstract: An alkylaromatics isomerisation catalyst, which catalyst comprises at least 50 wt% of an inorganic binder; at least 0.01 wt% of a Group VIII metal and 1 - 9 wt % ZSM- 12 zeolite wherein the silica to alumina molar ratio (SAR) of the ZSM- 12 zeolite is in the range of from 60 to 200, and a process for the isomerisation of alkylaromatics to provide a reaction mixture, said process comprising contacting a hydrocarbon stream comprising alkylaromatics with such catalyst.

公开(公告)号：EP3114101A4

公开(公告)日：2017-03-29

申请号：EP14884331

申请日：2014-08-11

Applicant: EXXONMOBIL CHEMICAL PATENTS INC

Inventor： DAKKA JIHAD M ,  DECAUL LORENZO C ,  DE SMIT EMIEL ,  HELTON TERRY E ,  SALCICCIOLI MICHAEL ,  SANGAR NEERAJ ,  WEIGEL SCOTT J

IPC: C07C2/02 ,  B01J29/08 ,  B01J29/10 ,  B01J29/12 ,  B01J29/14 ,  B01J29/18 ,  B01J29/22 ,  B01J29/24 ,  B01J29/70 ,  B01J29/74 ,  B01J29/76 ,  C07C2/74 ,  C07C5/367 ,  C07C7/20 ,  C07C51/16 ,  C07C51/265 ,  C07C51/50 ,  C07C67/08

CPC classification number: C07C2/74 ,  B01J29/088 ,  B01J29/106 ,  B01J29/12 ,  B01J29/126 ,  B01J29/146 ,  B01J29/185 ,  B01J29/22 ,  B01J29/24 ,  B01J29/7057 ,  B01J29/7084 ,  B01J29/7415 ,  B01J29/7469 ,  B01J29/7615 ,  B01J29/7669 ,  B01J35/023 ,  B01J35/026 ,  B01J2029/081 ,  B01J2229/186 ,  B01J2229/42 ,  C07C5/367 ,  C07C51/265 ,  C07C67/08 ,  C07C2521/12 ,  C07C2529/08 ,  C07C2529/12 ,  C07C2529/22 ,  C07C2529/74 ,  C07C2529/80 ,  Y02P20/52 ,  C07C63/331 ,  C07C69/76 ,  C07C13/28 ,  C07C15/14

Abstract: This invention relates to process for producing biphenyl esters, the process comprising: (a) contacting a feed comprising toluene, xylene or mixtures thereof with hydrogen in the presence of a hydroalkylation catalyst to produce a hydroalkylation reaction product comprising (methylcyclohexyl)toluene, wherein the hydroalkylation catalyst comprises: 1) binder present at 40 wt % or less (based upon weight of final catalyst composition), 2) a hydrogenation component present at 0.2 wt % or less (based upon weight of final catalyst composition), and 3) an acidic component comprising a molecular sieve having a twelve membered (or larger) ring pore opening, channel or pocket and a largest pore dimension of 6.0 angstroms or more present at 60 wt % or more, (based upon weight of final catalyst composition); (b) dehydrogenating the hydroalkylation reaction product using a dehydrogenation catalyst to produce a dehydrogenation reaction product comprising a mixture of methyl-substituted biphenyl compounds; (c) contacting at the dehydrogenation reaction product with an oxidizing gas to convert the methyl-substituted biphenyl compounds to biphenyl carboxylic acids; and (d) reacting the biphenyl carboxylic acids with one or more C1 to C14 alcohols to produce biphenyl esters.

Abstract translation: 本发明涉及生产联苯酯的方法，该方法包括：（a）使包含甲苯，二甲苯或其混合物的进料与氢气在加氢烷基化催化剂存在下接触以产生包含（甲基环己基）甲苯的加氢烷基化反应产物，其中 加氢烷基化催化剂包含：1）以40wt％或更低（基于最终催化剂组合物的重量计）存在的粘合剂，2）以0.2wt％或更低（基于最终催化剂组合物的重量计）存在的氢化组分，和3） 酸性组分，其包含具有十二元（或更大）环孔开口，通道或袋并且以60重量％或更多存在的6.0埃或更大的最大孔尺寸（基于最终催化剂组合物的重量）的分子筛; （b）使用脱氢催化剂使加氢烷基化反应产物脱氢以产生包含甲基取代的联苯化合物的混合物的脱氢反应产物; （c）在脱氢反应产物与氧化气体接触以将甲基取代的联苯化合物转化为联苯羧酸; 和（d）使联苯羧酸与一种或多种C1-C14醇反应以生产联苯酯。

公开(公告)号：EP3135373A1

公开(公告)日：2017-03-01

申请号：EP16183488.2

申请日：2016-08-10

Applicant: INDIAN OIL CORPORATION Ltd.

Inventor： KUVETTU, Mohan Prabhu ,  KADGAONKAR, Mahesh ,  SARKAR, Biswanath ,  CHIDAMBARAM, Velusamy ,  KARTHIKEYANI, Arumugam Velayutham ,  PULIKOTTIL, Alex ,  CHRISTOPHER, Jayaraj ,  KUMAR, Brijesh ,  DAS, Biswapriya

IPC: B01J29/46 ,  B01J37/06 ,  B01J37/02 ,  B01J29/24 ,  B01J29/68 ,  B01J29/76 ,  B01J29/80 ,  C10G11/05 ,  C10G11/18 ,  B01J37/28 ,  B01J29/06 ,  B01J29/08 ,  B01J35/00 ,  B01J37/00

CPC classification number: B01J29/40 ,  B01J29/06 ,  B01J29/084 ,  B01J29/24 ,  B01J29/46 ,  B01J29/68 ,  B01J29/7615 ,  B01J29/7653 ,  B01J29/7661 ,  B01J29/7669 ,  B01J29/7692 ,  B01J29/80 ,  B01J35/002 ,  B01J35/0026 ,  B01J37/0045 ,  B01J37/009 ,  B01J37/06 ,  B01J37/08 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/38 ,  B01J2229/42 ,  B01J2523/00 ,  C10G11/05 ,  C10G11/18 ,  C10G2400/02 ,  C10G2400/20 ,  B01J2523/22 ,  B01J2523/55 ,  B01J2523/847 ,  B01J2523/23 ,  B01J2523/17

Abstract: The present invention relates to a catalyst product for cracking of heavy hydrocarbon feed stocks predominantly into light olefins and processes for preparing the catalyst. More specifically the present invention relates to a process of preparing a Fluid Catalytic Cracking (FCC) catalyst additive composition. The FCC catalyst additive composition of the present invention is a LPG selective catalyst particles comprising a medium pore size zeolite bound by a clay-phosphate-silica-alumina binder with lowered soluble phosphate content. The catalyst of the present invention exhibits improved selectivity towards high value components like propylene and gasoline and suppressing low value components like dry gas and bottoms.
The preparation comprises washing an FCC catalyst additive comprising a zeolite and phosphate with demineralised water for 30 min to 2 h to remove water soluble phosphate before drying and calcining, and subsequent ion exchange with a bivalent metal ion selected from IUPAC groups 2 and 11, filtering, drying and calcining.

Abstract translation: 本发明涉及一种催化剂产品，用于重质烃原料裂化主要成轻烯烃和用于制备所述催化剂的方法。 更具体地说，本发明涉及一种制备流化催化裂化（FCC）催化剂的添加剂组合物的方法。 本发明的流化催化裂化催化剂的添加剂组合物是包含由具有降低的可溶性磷酸盐含量粘土 - 磷酸盐 - 二氧化硅 - 氧化铝粘合剂结合的中等孔径沸石一个LPG选择性的催化剂颗粒。 本发明表现出的改善的催化剂选择性朝向像丙烯和汽油和抑制低价值组件如干燥气体和塔底高值分量。 该制剂包含的FCC添加剂洗涤催化剂，其包含沸石和磷酸盐用软化水进行30分钟至2小时，以与来自IUPAC组2和11中选出的二价金属离子干燥和煅烧，和随后的离子交换之前，除去水溶性磷酸盐，过滤 ，干燥和煅烧。

公开(公告)号：EP2970045A1

公开(公告)日：2016-01-20

申请号：EP14775804.9

申请日：2014-03-07

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： DAKKA, Jihad, M. ,  DECAUL, Lorenzo, C. ,  DEFLORIO, Victor

IPC: C07C2/64 ,  C07C13/28

CPC classification number: C07C5/367 ,  B01J29/0325 ,  B01J29/085 ,  B01J29/12 ,  B01J29/14 ,  B01J29/7057 ,  B01J29/7084 ,  B01J29/7415 ,  B01J29/7469 ,  B01J29/7615 ,  B01J29/7669 ,  C07C2/74 ,  C07C51/265 ,  C07C67/08 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2529/70 ,  C07C2529/74 ,  C07C2601/14 ,  Y02P20/52 ,  C07C13/28 ,  C07C15/14 ,  C07C63/331 ,  C07C69/76

Abstract: In a process for producing methyl-substituted biphenyl compounds, a feed comprising at least one aromatic hydrocarbon selected from the group consisting of toluene, xylene and mixtures thereof is contacted with hydrogen in the presence of a hydroalkylation catalyst under conditions effective to produce a hydroalkylation reaction product comprising (methylcyclohexyl)toluenes and/or (dimethylcyclohexyl)xylenes together with dialkylated C
21 + compounds. At least part of the dialkylated C
21 + compounds is then removed from the hydroalkylation reaction product to produce a dehydrogenation feed; and at least part of the dehydrogenation feed is dehydrogenated in the presence of a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising a mixture of methyl-substituted biphenyl compounds.

Abstract translation: 在用于生产甲基substituiertem联苯化合物的方法中，包括至少一个芳族烃基选自甲苯，二甲苯和它们的混合物与氢气在加氢烷基化催化剂的存在下在有效产生加氢烷基化反应进料的条件下接触选定 包含产物（甲基环己基）甲苯和/或（二甲基）二甲苯连同二烷基化C21 +的化合物。 至少二烷基化C21 +的化合物的一部分，然后从加氢烷基化反应产物以产生脱氢进料除去; 和脱氢进料的至少一部分在脱氢催化剂的有效产生脱氢反应产物包含甲基 - 联苯substituiertem化合物的混合物的条件下的存在下脱氢。

公开(公告)号：EP2934747A1

公开(公告)日：2015-10-28

申请号：EP13812012.6

申请日：2013-12-04

Applicant: IFP Énergies nouvelles

Inventor： GUILLON, Emmanuelle ,  BRANDHORST, Laure

IPC: B01J29/72 ,  B01J29/74 ,  B01J29/76 ,  B01J35/10 ,  B01J37/02 ,  B01J37/00 ,  B01J37/10 ,  C07C15/08 ,  C07C5/27

CPC classification number: B01J29/74 ,  B01J29/7269 ,  B01J29/7469 ,  B01J29/7669 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/08 ,  B01J37/10 ,  B01J37/18 ,  B01J2229/14 ,  B01J2229/18 ,  B01J2229/36 ,  B01J2229/42 ,  C07C5/2737 ,  C07C5/2775 ,  C07C2529/74 ,  Y02P20/52 ,  C07C15/08

Abstract: The invention concerns a catalyst comprising at least one zeolite having an MTW structure, a matrix, at least one metal from group VIII of the periodic table, said catalyst having a mesoporous volume increased by at least 10% relative to the initial mesoporous volume of same, generally between 0.55 and 0.75 m L/g, after a treatment with water vapour at a partial pressure of between 0.01 and 0.07 MPa and at a temperature of between 300 and 400° C, for at least 0.5 hour. The invention concerns the method for preparing said catalyst and an isomerisation method implementing said catalyst.

公开(公告)号：EP1902116A1

公开(公告)日：2008-03-26

申请号：EP06762434.6

申请日：2006-07-03

Applicant: ENI S.p.A. ,  Enitechnologie S.p.A.

Inventor： GIARDINO, Roberto ,  CALEMMA, Vincenzo ,  CORNARO, Ugo

IPC: C10G45/62 ,  B01J23/40

CPC classification number: B01J35/1061 ,  B01J21/12 ,  B01J23/40 ,  B01J29/7469 ,  B01J29/7669 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1057 ,  C10G2300/1044 ,  C10G2300/1051 ,  C10G2300/1055 ,  C10G2300/307 ,  C10G2300/4018 ,  C10G2400/04

Abstract: A process is described for improving the quality as a fuel of hydrotreated hydrocarbon blends by reaction with hydrogen in the presence of a bifunctional catalytic system comprising one or more metals selected from Pt, Pd, Ir, Ru, Rh and Re, and a silico-aluminate of an acidic nature, se- lected from a micro-mesoporous silico-alumina and a zeolite belonging to the MTW family. The process of the invention produces an increase in the cetane index and a decrease in the density and T95.

公开(公告)号：EP2720990B1

公开(公告)日：2018-03-07

申请号：EP12799829.2

申请日：2012-06-14

Applicant: UT-Battelle, LLC

Inventor： NARULA, Chaitanya, K. ,  DAVISON, Brian, H. ,  KELLER, Martin

IPC: C07C1/20 ,  C10G3/00 ,  B01J29/46 ,  B01J29/48 ,  C12P7/06 ,  C12P7/08 ,  C12P7/10 ,  B01J37/02 ,  B01J29/06 ,  B01J29/072 ,  B01J29/076 ,  B01J29/14 ,  B01J29/16 ,  B01J29/68 ,  B01J29/69 ,  B01J29/76 ,  B01J29/78 ,  B01J35/02 ,  B01J35/04 ,  C07C1/22 ,  C12P7/16

CPC classification number: C10G3/49 ,  B01J29/061 ,  B01J29/072 ,  B01J29/076 ,  B01J29/143 ,  B01J29/146 ,  B01J29/163 ,  B01J29/166 ,  B01J29/46 ,  B01J29/48 ,  B01J29/68 ,  B01J29/69 ,  B01J29/7615 ,  B01J29/7661 ,  B01J29/7669 ,  B01J29/7692 ,  B01J29/7815 ,  B01J29/7861 ,  B01J29/7869 ,  B01J29/7892 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0246 ,  B01J2229/183 ,  B01J2229/186 ,  C07C1/22 ,  C10G3/45 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/4006 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C12P7/06 ,  C12P7/08 ,  C12P7/10 ,  C12P7/16 ,  Y02E50/10 ,  Y02E50/16 ,  Y02E50/17 ,  Y02P30/20

Abstract: A method for converting an alcohol to a hydrocarbon, the method comprising contacting said alcohol with a metal-loaded zeolite catalyst at a temperature of at least 100° C. and up to 550° C., wherein said alcohol can be produced by a fermentation process, said metal is a positively-charged metal ion, and said metal-loaded zeolite catalyst is catalytically active for converting said alcohol to said hydrocarbon.