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    VERFAHREN ZUR HERSTELLUNG VON ALDEHYDEN AUS ALKANEN UND SYNTHESEGAS
    5.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON ALDEHYDEN AUS ALKANEN UND SYNTHESEGAS 有权

    公开(公告)号：EP3114105A1

    公开(公告)日：2017-01-11

    申请号：EP15705590.6

    申请日：2015-02-16

    申请人： Evonik Degussa GmbH

    发明人： FRANKE, Robert ,  HAHN, Hanna ,  QUANDT, Thomas ,  WASSERSCHEID, Peter ,  HAUMANN, Marco ,  WALTER, Simon

    IPC分类号： C07C47/02 ,  C07C45/50

    CPC分类号： C07C45/50 ,  C07C47/02

    摘要： The invention relates to a method for producing one or more aldehydes from alkanes, comprising the steps: a) dehydrating at least one alkane in the presence of a heterogeneous catalyst to produce at least one alkene, b) conversion of the alkene or the alkenes from step a) with hydrogen and carbon monoxide in the presence of a heterogeneous catalyst which is different from the catalyst in step a). The method is characterised in that a catalytically effective composition is used as catalyst in step b), which composition has a solid substrate material which supports an ionic liquid which contains a catalyst including at least one transition metal and at least one ligand. The invention further relates to an apparatus suitable for dehydration of one or more alkanes to produce one or more alkenes, and hydroformylation of the alkene or alkenes obtained to produce aldehydes. Said apparatus is characterised in that the apparatus has at least two reaction zones, which are connected to one another in a fluid-conducting manner, wherein the first reaction zone is designed as a fixed bed and has a catalyst which catalyses the dehydration of alkanes to produce alkenes and the second reaction zone is designed as a fixed bed and has a catalyst which catalyses the hydroformylation of alkenes and is designed as a composition having a solid substrate material which supports an ionic liquid in which a catalyst, including at least one transition metal and at least one ligand, is contained.

    摘要翻译： 本发明涉及从烷烃生产一种或多种醛的方法，包括以下步骤：a）在非均相催化剂存在下使至少一种烷烃脱水以产生至少一种烯烃，b）将烯烃或烯烃从 步骤a）在不同于步骤a）中的催化剂的非均相催化剂存在下，使用氢气和一氧化碳。 该方法的特征在于在步骤b）中使用催化有效组合物作为催化剂，该组合物具有固体基质材料，其支持含有至少一种过渡金属和至少一种配体的催化剂的离子液体。 本发明还涉及一种适用于脱水一种或多种烷烃以产生一种或多种烯烃的装置，以及获得的烯烃或烯烃的加氢甲酰化以制备醛。 所述装置的特征在于，该装置具有至少两个以流体传导方式彼此连接的反应区，其中第一反应区设计为固定床，并具有催化剂将烷烃脱水至 产生烯烃，第二反应区被设计为固定床，并具有催化烯烃加氢甲酰化的催化剂，并被设计为具有固体基质材料的组合物，该基质材料支持离子液体，其中催化剂包括至少一种过渡金属 并含有至少一种配体。