公开(公告)号：EP2948426A1

公开(公告)日：2015-12-02

申请号：EP14743774.3

申请日：2014-01-27

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： DAKKA, Jihad, M. ,  DECAUL, Lorenzo, C. ,  COSTELLO, Christine, A. ,  MOZELESKI, Edmund, J. ,  OSTERRIETH, Pierre, J. ,  SMIRNOVA, Diana, S. ,  ZUSHMA, Stephen ,  GODWIN, Allen D. ,  FALER, Catherine, Anne ,  DEFLORIO, Victor ,  NAERT, Didier

IPC: C07C69/76 ,  C07C67/03

CPC classification number: C08K5/12 ,  C07C69/76 ,  C07C2601/14 ,  C08K5/0016 ,  C08K5/101 ,  C08L27/06

Abstract: Provided are compounds of the following: wherein R
1 is a saturated or unsaturated cyclic hydrocarbon optionally substituted with an alkyl and/or an OXO-ester, and R
2 is a C
4 to C
14 hydrocarbyl, preferably the residue of a C
4 to C
14 OXO-alcohol. Also provided are processes for making the compounds and plasticized polymer compositions containing said compounds.

公开(公告)号：EP2970045A1

公开(公告)日：2016-01-20

申请号：EP14775804.9

申请日：2014-03-07

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： DAKKA, Jihad, M. ,  DECAUL, Lorenzo, C. ,  DEFLORIO, Victor

IPC: C07C2/64 ,  C07C13/28

CPC classification number: C07C5/367 ,  B01J29/0325 ,  B01J29/085 ,  B01J29/12 ,  B01J29/14 ,  B01J29/7057 ,  B01J29/7084 ,  B01J29/7415 ,  B01J29/7469 ,  B01J29/7615 ,  B01J29/7669 ,  C07C2/74 ,  C07C51/265 ,  C07C67/08 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2529/70 ,  C07C2529/74 ,  C07C2601/14 ,  Y02P20/52 ,  C07C13/28 ,  C07C15/14 ,  C07C63/331 ,  C07C69/76

Abstract: In a process for producing methyl-substituted biphenyl compounds, a feed comprising at least one aromatic hydrocarbon selected from the group consisting of toluene, xylene and mixtures thereof is contacted with hydrogen in the presence of a hydroalkylation catalyst under conditions effective to produce a hydroalkylation reaction product comprising (methylcyclohexyl)toluenes and/or (dimethylcyclohexyl)xylenes together with dialkylated C
21 + compounds. At least part of the dialkylated C
21 + compounds is then removed from the hydroalkylation reaction product to produce a dehydrogenation feed; and at least part of the dehydrogenation feed is dehydrogenated in the presence of a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising a mixture of methyl-substituted biphenyl compounds.

Abstract translation: 在用于生产甲基substituiertem联苯化合物的方法中，包括至少一个芳族烃基选自甲苯，二甲苯和它们的混合物与氢气在加氢烷基化催化剂的存在下在有效产生加氢烷基化反应进料的条件下接触选定 包含产物（甲基环己基）甲苯和/或（二甲基）二甲苯连同二烷基化C21 +的化合物。 至少二烷基化C21 +的化合物的一部分，然后从加氢烷基化反应产物以产生脱氢进料除去; 和脱氢进料的至少一部分在脱氢催化剂的有效产生脱氢反应产物包含甲基 - 联苯substituiertem化合物的混合物的条件下的存在下脱氢。