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公开(公告)号：EP3442932A1
公开(公告)日：2019-02-20
申请号：EP17782779.7
申请日：2017-02-22
IPC分类号： C07C2/74 , C07C5/13 , C07C13/28 , C07C67/08 , C07C67/62 , C07C69/76 , B01J29/74 , B01J23/62 , B01J23/42 , B01J21/08
摘要： In a process for producing a methyl-substituted biphenyl compound, at least one methyl-substituted cyclohexylbenzene compound of the formula: wherein each of m and n is independently 1, 2, or 3, is contacted with hydrogen in the presence of a hydrogenation catalyst to produce a hydrogenation reaction product comprising at least one methyl- substituted bicyclohexane compound, and the methyl- substituted bicyclohexane compound is then contacted with a dehydrogenation catalyst to produce a dehydrogenation reaction product comprising at least one methyl-substituted biphenyl compound.
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2.发明公开METHYL-SUBSTITUTED BIPHENYL COMPOUNDS, THEIR PRODUCTION AND THEIR USE IN THE MANUFACTURE OF PLASTICIZERS 审中-公开甲基取代的联苯化合物，生产和它们在增塑剂的制造
公开(公告)号：EP2970045A1
公开(公告)日：2016-01-20
申请号：EP14775804.9
申请日：2014-03-07
CPC分类号： C07C5/367 , B01J29/0325 , B01J29/085 , B01J29/12 , B01J29/14 , B01J29/7057 , B01J29/7084 , B01J29/7415 , B01J29/7469 , B01J29/7615 , B01J29/7669 , C07C2/74 , C07C51/265 , C07C67/08 , C07C2521/04 , C07C2521/08 , C07C2523/14 , C07C2523/42 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C15/14 , C07C63/331 , C07C69/76
摘要： In a process for producing methyl-substituted biphenyl compounds, a feed comprising at least one aromatic hydrocarbon selected from the group consisting of toluene, xylene and mixtures thereof is contacted with hydrogen in the presence of a hydroalkylation catalyst under conditions effective to produce a hydroalkylation reaction product comprising (methylcyclohexyl)toluenes and/or (dimethylcyclohexyl)xylenes together with dialkylated C
21 + compounds. At least part of the dialkylated C
21 + compounds is then removed from the hydroalkylation reaction product to produce a dehydrogenation feed; and at least part of the dehydrogenation feed is dehydrogenated in the presence of a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising a mixture of methyl-substituted biphenyl compounds.摘要翻译： 在用于生产甲基substituiertem联苯化合物的方法中，包括至少一个芳族烃基选自甲苯，二甲苯和它们的混合物与氢气在加氢烷基化催化剂的存在下在有效产生加氢烷基化反应进料的条件下接触选定 包含产物（甲基环己基）甲苯和/或（二甲基）二甲苯连同二烷基化C21 +的化合物。 至少二烷基化C21 +的化合物的一部分，然后从加氢烷基化反应产物以产生脱氢进料除去; 和脱氢进料的至少一部分在脱氢催化剂的有效产生脱氢反应产物包含甲基 - 联苯substituiertem化合物的混合物的条件下的存在下脱氢。
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公开(公告)号：EP3233769A1
公开(公告)日：2017-10-25
申请号：EP15870658.0
申请日：2015-12-02
发明人： SALCICCIOLI, Michael , DAKKA, Jihad, M. , DE SMIT, Emiel , SANGAR, Neeraj , WEIGEL, Scott, J. , RAMAN, Sumathy , HELTON, Terry, E. , DECAUL, Lorenzo, C. , ELIA, Christine, N. , BAI, Chuansheng , GHOSE, Ranjita
CPC分类号： C07C2/74 , C07C2/864 , C07C5/2737 , C07C5/367 , C07C2521/02 , C07C2521/04 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C07C15/14 , C07C13/28
摘要： A process is described for converting at least one isomer of a dialkyl- substituted biphenyl compound, such as at least one 2,X' dialkylbiphenyl isomer (where X' is 2', 3' and/or 4'), into at least one different isomer, 3,3', 3,4' and/or 4,4' dialkylbiphenyl isomer. The process comprises contacting a feed comprising the dialkyl-substituted biphenyl compound isomer with an acid catalyst under isomerization conditions.
摘要翻译： 描述了将二烷基取代的联苯化合物的至少一种异构体例如至少一种2，X'二烷基联苯异构体（其中X'是2'，3'和/或4'）转化成至少一种 不同的异构体，3,3'，3,4'和/或4,4'二烷基联苯异构体。 该方法包括在异构化条件下使包含二烷基取代的联苯化合物异构体的进料与酸催化剂接触。
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公开(公告)号：EP2948426A1
公开(公告)日：2015-12-02
申请号：EP14743774.3
申请日：2014-01-27
发明人： DAKKA, Jihad, M. , DECAUL, Lorenzo, C. , COSTELLO, Christine, A. , MOZELESKI, Edmund, J. , OSTERRIETH, Pierre, J. , SMIRNOVA, Diana, S. , ZUSHMA, Stephen , GODWIN, Allen D. , FALER, Catherine, Anne , DEFLORIO, Victor , NAERT, Didier
CPC分类号： C08K5/12 , C07C69/76 , C07C2601/14 , C08K5/0016 , C08K5/101 , C08L27/06
摘要： Provided are compounds of the following: wherein R
1 is a saturated or unsaturated cyclic hydrocarbon optionally substituted with an alkyl and/or an OXO-ester, and R
2 is a C
4 to C
14 hydrocarbyl, preferably the residue of a C
4 to C
14 OXO-alcohol. Also provided are processes for making the compounds and plasticized polymer compositions containing said compounds.-
公开(公告)号：EP2691359A1
公开(公告)日：2014-02-05
申请号：EP11794379.5
申请日：2011-12-02
发明人： CHEN, Tan-Jen , DAKKA, Jihad, M. , HELTON, Terry, E. , BENITEZ, Francisco, M. , SMITH, Charles, M. , DECAUL, Lorenzo, C.
CPC分类号： C07C5/367 , C07C5/325 , C07C2523/14 , C07C2523/42 , C07C2523/62 , C07C13/20
摘要： Disclosed herein is a process for dehydrogenating a saturated cyclic hydrocarbon and/or 5-membered ring compound with a dehydrogenation catalyst. The dehydrogenation catalyst comprises: (i) 0.05 wt % to 5 wt % of a metal selected from Group 14 of the Periodic Table of Elements; and (ii) 0.1 wt % to 10 wt % of a metal selected from Groups 6 to 10 of the Periodic Table of Elements. The process is conducted under dehydrogenation conditions effective to dehydrogenate at least a portion saturated cyclic hydrocarbon and/or 5-membered ring compound.
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公开(公告)号：EP2621630A2
公开(公告)日：2013-08-07
申请号：EP11831126.5
申请日：2011-08-26
发明人： CLEM, Kenneth, R. , IACCINO, Larry, L. , AFEWORKI, Mobae , HENAO, Juan, D. , SANGAR, Neeraj , ZHENG, Xiaobo , DECAUL, Lorenzo, C.
CPC分类号： C07C2/76 , B01J29/48 , B01J29/90 , B01J38/02 , B01J38/10 , C07C1/12 , C07C2/66 , C07C2/864 , C07C2/865 , C07C5/10 , C07C5/11 , C07C2521/06 , C07C2523/02 , C07C2523/06 , C07C2523/08 , C07C2523/10 , C07C2523/12 , C07C2523/14 , C07C2523/16 , C07C2523/18 , C07C2523/20 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/50 , C07C2523/52 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2527/22 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/60 , C07C2529/65 , C07C2529/70 , C07C2601/14 , C07C2601/16 , C07C2602/26 , C07C2602/28 , C10G50/00 , C10G2300/708 , C10G2400/30 , Y02P20/52 , Y02P20/584 , Y02P20/588 , C07C15/04 , C07C15/24 , C07C11/04 , C07C9/04 , C07C9/06 , C07C15/073 , C07C15/08 , C07C13/18 , C07C13/50 , C07C13/20 , C07C13/48
摘要： In a process for the regeneration of a coked metal-containing catalyst, the coked catalyst is contacted in a regeneration zone with an atmosphere which contains carbon dioxide and carbon monoxide at a temperature of at least 400 °C.
摘要翻译： 在一种用于再生含焦炭金属的催化剂的方法中，焦化催化剂在再生区与包含二氧化碳和一氧化碳的气氛在至少400℃的温度下接触。
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公开(公告)号：EP2970049B1
公开(公告)日：2019-10-16
申请号：EP14774045.0
申请日：2014-03-07
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公开(公告)号：EP2621630B1
公开(公告)日：2019-03-27
申请号：EP11831126.5
申请日：2011-08-26
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9.发明公开METHYL-SUBSTITUTED BIPHENYL COMPOUNDS, THEIR PRODUCTION AND THEIR USE IN THE MANUFACTURE OF PLASTICIZERS 有权甲基取代的联苯化合物，生产和它们在增塑剂的制造
公开(公告)号：EP2970049A1
公开(公告)日：2016-01-20
申请号：EP14774045.0
申请日：2014-03-07
摘要： In a process for producing methyl-substituted biphenyl compounds, a feed comprising at least one aromatic hydrocarbon selected from the group consisting of toluene, xylene and mixtures thereof is contacted with hydrogen in the presence of a hydroalkylation catalyst under conditions effective to produce a hydroalkylation reaction product comprising (methylcyclohexyl)toluenes and/or (dimethylcyclohexyl)xylenes. At least part of the hydroalkylation reaction product is then dehydrogenated in the presence of a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising a mixture of methyl-substituted biphenyl compounds.
摘要翻译： 在用于生产甲基substituiertem联苯化合物的方法中，包括至少一个芳族烃基选自甲苯，二甲苯和它们的混合物与氢气在加氢烷基化催化剂的存在下在有效产生加氢烷基化反应进料的条件下接触选定 包含产物（甲基环己基）甲苯和/或（二甲基）二甲苯。 加氢烷基化反应产物的至少一部分随后在脱氢催化剂的有效产生脱氢反应产物包含甲基 - 联苯substituiertem化合物的混合物的条件下的存在脱氢。
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10.发明公开PROCESS FOR PRODUCING PHENOL AND/OR CYCLOHEXANONE 审中-公开VERFAHREN ZUR HERSTELLUNG VON PHENOL UND / ODER CYCLOHEXANON
公开(公告)号：EP2303809A1
公开(公告)日：2011-04-06
申请号：EP09735374.2
申请日：2009-03-16
发明人： DAKKA, Jihad, M. , BUCHANAN, John, S. , CHENG, Jane, C. , CHEN, Tan-jen , DECAUL, Lorenzo, C. , HELTON, Terry, E. , STANAT, Jon, E. , BENITEZ, Francisco, M.
IPC分类号： C07C2/74 , C07C13/28 , C07C5/367 , C07C15/04 , C07C37/08 , C07C45/53 , C07C49/403 , B01J29/72
CPC分类号： C07C37/08 , B01J29/064 , B01J29/7215 , B01J29/7276 , C07C2/74 , C07C37/07 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
摘要： In a process for producing phenol and/or cyclohexanone, benzene and hydrogen are contacted with a first catalyst in a hydroalkylation step to produce a first effluent stream comprising cyclohexylbenzene, cyclohexane, and unreacted benzene. At least part of the first effluent stream is supplied to a first separation system to divide the first effluent stream part into a cyclohexylbenzene-rich stream and a C6 product stream comprising unreacted benzene and cyclohexane.
摘要翻译： 在制备苯酚和/或环己酮的方法中，苯和氢在加氢烷基化步骤中与第一催化剂接触以产生包含环己基苯，环己烷和未反应苯的第一流出物流。 将第一流出物流的至少一部分供应到第一分离系统以将第一流出物流部分分成富含环己基苯的物流和包含未反应的苯和环己烷的C6产物流。
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