Abstract:
A spectroscopic method and spectroscopy system therefrom for analyzing samples. A sample includes a first chemical component that has a characteristic first absorption peak is provided. The sample is irradiated in a measurement waveband proximate to the first absorption peak, and at a first and a second reference waveband where the first chemical component lacks characteristic absorption features. Reflected or transmitted detection data is obtained including a measured power proximate to the first absorption peak and first and second reference powers at the reference wavebands. A plurality of different waveband ratios are evaluated using pairs of detection data to generate a plurality of measured waveband ratio values. A parameter of the first chemical component is then determined by evaluating a multidimensional polynomial calibration equation that relates the parameter of the first chemical component to the plurality of different waveband ratios by substituting the measured waveband ratio values into the calibration relation.
Abstract:
Radiation scattering is one of the main contributors to the uncertainty of near infrared (NIR) measurements. Enhanced absorption-measurement accuracy for NIR sensors is achieved by using a combination of NIR spectroscopy and time-of-flight techniques to select photons that are the result of a given mean free path within a moving sample target. By measuring absorption as a function of path length or by windowing signals that are attributable to excessive scattering of NIR radiation within the sample, this technique affords the calculation of more accurate and more universal calibrations. The NIR sensor employs short or ultra-short laser pulses to create NIR that is directed to the moving sample and emerging radiation is detected over time. Windowing effectively truncates non-contributing measurements.
Abstract:
A method includes measuring a caliper of a sheet of material using a caliper sensor having first and second sensor modules. The method also includes adjusting the caliper measurement based on a transverse displacement between a first sensor component in the first sensor module and a second sensor component in the second sensor module to generate a corrected caliper measurement. Adjusting the caliper measurement can include applying a corrector function that adjusts the caliper measurement based on the measured transverse displacement. The corrector function can be identified by repeatedly creating misalignment between the first and second sensor components, measuring a known distance using the caliper sensor, and identifying an error between the measurement of the known distance and the known distance.
Abstract:
A method includes identifying a chlorophyll concentration/optical density (CCpOD) value using a chlorophyll concentration measurement of an autotroph culture and an optical density measurement of the autotroph culture. The method also includes identifying a change in the autotroph culture using the CCpOD value. The change in the autotroph culture can be identified by determining whether the CCpOD value falls outside upper and lower control limits. The upper and lower control limits can be identified using a specified number of previously-determined CCpOD values, which can be calculated when the autotroph culture is in a known healthy state. Multiple CCpOD values can be calculated, and an alarm can be generated if a specified number of the CCpOD values (such as one or more) fall outside the upper and lower control limits.