公开(公告)号：EP3322532A1

公开(公告)日：2018-05-23

申请号：EP16736077.5

申请日：2016-07-05

申请人： IFP Energies nouvelles ,  Compagnie Générale des Etablissements Michelin ,  Michelin Recherche et Technique S.A.

发明人： CADRAN, Nicolas ,  CHAUMONNOT, Alexandra

IPC分类号： B01J37/03 ,  B01J37/02 ,  B01J23/20 ,  B01J35/10 ,  C07C1/24 ,  C07C1/20 ,  B01J37/08 ,  B01J37/10 ,  B01J21/08

CPC分类号： B01J23/20 ,  B01J21/08 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/036 ,  B01J37/08 ,  B01J37/10 ,  B01J2523/00 ,  C07C1/20 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/06 ,  C07C2523/20 ,  B01J2523/41 ,  B01J2523/56 ,  B01J2523/57 ,  B01J2523/27 ,  C07C11/167

摘要： The invention relates to a catalyst including a mesoporous oxide matrix, said matrix including at least one oxide of an element X selected from among silicon and titanium, taken alone or in a mixture, said catalyst including at least the element tantalum and the element niobium, the mass of tantalum making up from 0.1 to 30% of the mass of the mesoporous oxide matrix, the mass of niobium making up from 0.02 to 6% of the mass of the mesoporous oxide matrix, the mass content of the element tantalum being no lower than the mass content of the element niobium. The invention also relates to the use of said catalyst in a method for producing 1,3-butadiene from a feedstock including at least ethanol.

公开(公告)号：EP3322524A1

公开(公告)日：2018-05-23

申请号：EP16739054.1

申请日：2016-07-05

申请人： IFP Energies nouvelles ,  Compagnie Générale des Etablissements Michelin

发明人： CADRAN, Nicolas ,  CHAUMONNOT, Alexandra

IPC分类号： B01J23/20 ,  B01J21/08 ,  B01J35/10 ,  B01J37/02 ,  B01J37/06 ,  C07C11/167 ,  C07C1/20

CPC分类号： C07C1/20 ,  B01J21/08 ,  B01J23/20 ,  B01J29/0341 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1061 ,  B01J37/0207 ,  B01J37/06 ,  B01J37/08 ,  C07C2521/08 ,  C07C2523/20 ,  C07C11/167

摘要： The invention relates to a catalyst including at least the element tantalum, and at least one mesoporous oxide matrix having undergone acid leaching, including at least, before leaching, 90 wt % of silica, the mass of the element tantalum making up from 0.1 to 30% of the mass of said mesoporous oxide matrix.

公开(公告)号：EP3322531A1

公开(公告)日：2018-05-23

申请号：EP16736075.9

申请日：2016-07-05

申请人： IFP Energies nouvelles ,  Compagnie Générale des Etablissements Michelin

发明人： CADRAN, Nicolas ,  CHAUMONNOT, Alexandra ,  LAMBERT, Arnold

IPC分类号： B01J37/03 ,  B01J37/08 ,  B01J37/10 ,  B01J21/08 ,  B01J23/20 ,  B01J37/02 ,  C07C1/20 ,  B01J35/10 ,  B01J23/06 ,  B01J23/68 ,  B01J23/847

CPC分类号： B01J21/08 ,  B01J23/06 ,  B01J23/20 ,  B01J23/682 ,  B01J23/847 ,  B01J35/1023 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/036 ,  B01J37/08 ,  B01J37/10 ,  B01J2523/00 ,  B01J2523/27 ,  B01J2523/41 ,  B01J2523/57 ,  C07C1/20 ,  C07C2521/08 ,  C07C2523/06 ,  C07C2523/20 ,  C07C11/167

摘要： The invention relates to a mesoporous mixed-oxide catalyst including silicon and at least one metal M chosen from the group made up of the elements of groups 4 and 5 of the periodic table and the mixtures thereof, the mass of metal M making up from 0.1 to 20% of the mass of the mixed oxide. The catalyst is preferably prepared by the modern metal-organic sol-gel process. The invention also relates to the use of the catalyst to convert ethanol into butadiene.

公开(公告)号：EP3322523A1

公开(公告)日：2018-05-23

申请号：EP16736076.7

申请日：2016-07-05

申请人： IFP Energies nouvelles ,  Compagnie Générale des Etablissements Michelin

发明人： CADRAN, Nicolas ,  CHAUMONNOT, Alexandra

IPC分类号： B01J23/20 ,  C07C1/20 ,  B01J35/10 ,  B01J37/02 ,  B01J23/68

CPC分类号： C07C1/20 ,  B01J23/20 ,  B01J23/682 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/0203 ,  B01J2523/00 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/06 ,  C07C2523/14 ,  C07C2523/20 ,  C07C2523/68 ,  B01J2523/27 ,  B01J2523/3706 ,  B01J2523/41 ,  B01J2523/57 ,  B01J2523/23 ,  B01J2523/22 ,  B01J2523/43 ,  B01J2523/3712 ,  B01J2523/18 ,  C07C11/167

摘要： The invention relates to a catalyst including at least the element tantalum, at least one aldol-reaction element and at least one mesoporous oxide matrix, the mass of tantalum making up from 0.1 to 30% of the mass of the mesoporous oxide matrix, the mass of the at least one aldol-reaction element making up from 0.02 to 4% of the mass of the mesoporous oxide matrix, and to the use thereof to convert ethanol into butadiene.

公开(公告)号：EP3074367B1

公开(公告)日：2018-08-01

申请号：EP14805885.2

申请日：2014-11-28

申请人： IFP Energies nouvelles ,  Compagnie Générale des Etablissements Michelin

发明人： DASTILLUNG, Rejane ,  CADRAN, Nicolas ,  FISCHER, Beatrice ,  JACQUIN, Marc ,  HUYGHE, Raphael

IPC分类号： C07C1/20 ,  C07C29/04

CPC分类号： C07C1/20 ,  C07C1/207 ,  C07C29/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2523/20 ,  C07C2523/26 ,  Y02P20/582 ,  Y02P30/42 ,  C07C31/08 ,  C07C11/167

公开(公告)号：EP3074367A1

公开(公告)日：2016-10-05

申请号：EP14805885.2

申请日：2014-11-28

申请人： IFP Énergies Nouvelles (IFPEN) ,  Michelin Recherche et Technique S.A. ,  Compagnie Générale des Etablissements Michelin

发明人： DASTILLUNG, Rejane ,  CADRAN, Nicolas ,  FISCHER, Beatrice ,  JACQUIN, Marc ,  HUYGHE, Raphael

IPC分类号： C07C1/20 ,  C07C29/04

CPC分类号： C07C1/20 ,  C07C1/207 ,  C07C29/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2523/20 ,  C07C2523/26 ,  Y02P20/582 ,  Y02P30/42 ,  C07C31/08 ,  C07C11/167

摘要： The invention relates to a process for producing 1,3-butadiene from an ethanol-rich feedstock, i.e. in which the ethanol represents more than 50% of the total weight of said feedstock, comprising at least: A) a step of converting at least said ethanol-rich feedstock and the ethanol effluent resulting from the separation step B into a conversion effluent predominantly comprising 1,3-butadiene, water and ethylene, and into a hydrogen effluent, operating at a pressure between 0.1 and 1.0 MPa, at a temperature between 300°C and 500°C in the presence of at least one catalyst; B) a step of separating at least said conversion effluent resulting from A and the hydration effluent resulting from C into at least an ethanol effluent, a butadiene effluent, a water effluent and an ethylene effluent; C) an ethylene hydration step supplied at least by said ethylene effluent and/or said water effluent both resulting from the separation step B, in order to produce a hydration effluent comprising ethanol, said hydration effluent then being recycled to the separation step B.

摘要翻译： 本发明涉及从富含乙醇的原料生产1,3-丁二烯的方法，即乙醇占所述原料总重量的50％以上，至少包括：A）至少转化的步骤 所述乙醇富集的原料和由分离步骤B产生的乙醇流出物转化为主要包含1,3-丁二烯，水和乙烯的转化流出物，并在温度为0.1-1.0MPa的压力下进行氢气流出物 在至少一种催化剂的存在下在300℃至500℃之间; B）至少将从A产生的所述转化流出物和由C产生的水合流出物分离成至少乙醇流出物，丁二烯流出物，水流出物和乙烯流出物的步骤; C）至少由所述乙烯流出物和/或所述水流出物供应的乙烯水合步骤，其由分离步骤B产生，以便产生包含乙醇的水合流出物，然后将所述水合流出物再循环至分离步骤B.

公开(公告)号：EP2313343A1

公开(公告)日：2011-04-27

申请号：EP09784285.0

申请日：2009-07-21

申请人： IFP Energies nouvelles

发明人： GUILLON, Emmanuelle ,  CADRAN, Nicolas ,  MAURY, Sylvie ,  CABIAC, Amandine

IPC分类号： C01B39/48 ,  B01J29/70 ,  C07C1/24 ,  C01B39/46 ,  C07C5/27 ,  C10G45/64 ,  C07C2/12

CPC分类号： B01J29/72 ,  B01J29/74 ,  B01J29/76 ,  B01J29/78 ,  B01J37/0009 ,  B01J2229/18 ,  B01J2229/42 ,  C01B39/48 ,  C07C1/24 ,  C07C2/12 ,  C07C5/2708 ,  C07C5/2775 ,  C07C6/126 ,  C07C11/02 ,  C07C2529/74 ,  C07C2529/76 ,  C07C2529/78 ,  C10G45/62 ,  C10G45/64 ,  C10G2300/1096 ,  C10G2300/70 ,  C10G2400/20 ,  C10G2400/22 ,  C10G2400/30 ,  Y02P20/52 ,  C07C15/08 ,  C07C9/16

摘要： A catalyst is described that comprises at least one IZM-2 zeolite, at least one matrix and at least one metal chosen from metals from groups VIII, VIB and VIIB, said zeolite having a chemical composition, expressed on an anhydrous basis, in terms of moles of oxides, by the following general formula: XO
2 :aY
2 O
3 :bM
2/n O in which X represents at least one tetravalent element, Y represents at least one trivalent element and M is at least one alkali metal and/or alkaline-earth metal of valency n, a and b respectively representing the number of moles of Y
2 O
3 and M
2/n O and a is between 0.001 and 0.5 and b is between 0 and 1.

公开(公告)号：EP2313343B1

公开(公告)日：2012-11-14

申请号：EP09784285.0

申请日：2009-07-21

申请人： IFP Energies nouvelles

发明人： GUILLON, Emmanuelle ,  CADRAN, Nicolas ,  MAURY, Sylvie ,  CABIAC, Amandine

IPC分类号： C01B39/48 ,  B01J29/70 ,  B01J29/76 ,  C07C1/24 ,  C01B39/46 ,  C07C5/27 ,  C10G45/64 ,  C07C2/12 ,  B01J29/78 ,  B01J37/00 ,  C07C6/12 ,  C07C11/02 ,  C10G45/62 ,  B01J29/72 ,  B01J29/74

CPC分类号： B01J29/72 ,  B01J29/74 ,  B01J29/76 ,  B01J29/78 ,  B01J37/0009 ,  B01J2229/18 ,  B01J2229/42 ,  C01B39/48 ,  C07C1/24 ,  C07C2/12 ,  C07C5/2708 ,  C07C5/2775 ,  C07C6/126 ,  C07C11/02 ,  C07C2529/74 ,  C07C2529/76 ,  C07C2529/78 ,  C10G45/62 ,  C10G45/64 ,  C10G2300/1096 ,  C10G2300/70 ,  C10G2400/20 ,  C10G2400/22 ,  C10G2400/30 ,  Y02P20/52 ,  C07C15/08 ,  C07C9/16

公开(公告)号：EP4341332A1

公开(公告)日：2024-03-27

申请号：EP22727177.2

申请日：2022-05-05

申请人： IFP Energies nouvelles

发明人： CADRAN, Nicolas ,  CHAUMONNOT, Alexandra ,  COUPARD, Vincent ,  DELCROIX, Damien ,  JACQUIN, Marc ,  PASQUIER, David

IPC分类号： C08J11/02 ,  C07C67/08 ,  C07C69/80 ,  B29B17/02 ,  C07C67/48 ,  C07C67/56 ,  C07C67/02

公开(公告)号：EP2707461A2

公开(公告)日：2014-03-19

申请号：EP12713204.1

申请日：2012-03-13

申请人： IFP Energies nouvelles

发明人： BREUIL, Pierre Alain ,  CADRAN, Nicolas ,  HUGUES, François ,  COUPARD, Vincent

IPC分类号： C10G25/00 ,  C10G50/00 ,  C10G57/02 ,  C10G67/06 ,  C10G69/12

CPC分类号： C10G25/05 ,  C10G25/00 ,  C10G25/003 ,  C10G50/00 ,  C10G57/02 ,  C10G67/06 ,  C10G69/126 ,  C10G2300/1088 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2400/04 ,  C10G2400/08

摘要： The invention relates to a method for the production of a diesel and middle distillate cut from an olefin feed having between 4 and 6 carbon atoms, said method including a first purification step performed on a resin, followed by an oligomerisation step performed on an acid catalyst.