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1.发明公开
公开(公告)号：EP3322523A1
公开(公告)日：2018-05-23
申请号：EP16736076.7
申请日：2016-07-05
CPC分类号： C07C1/20 , B01J23/20 , B01J23/682 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/0201 , B01J37/0203 , B01J2523/00 , C07C2521/10 , C07C2523/02 , C07C2523/06 , C07C2523/14 , C07C2523/20 , C07C2523/68 , B01J2523/27 , B01J2523/3706 , B01J2523/41 , B01J2523/57 , B01J2523/23 , B01J2523/22 , B01J2523/43 , B01J2523/3712 , B01J2523/18 , C07C11/167
摘要： The invention relates to a catalyst including at least the element tantalum, at least one aldol-reaction element and at least one mesoporous oxide matrix, the mass of tantalum making up from 0.1 to 30% of the mass of the mesoporous oxide matrix, the mass of the at least one aldol-reaction element making up from 0.02 to 4% of the mass of the mesoporous oxide matrix, and to the use thereof to convert ethanol into butadiene.
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公开(公告)号：EP3322532A1
公开(公告)日：2018-05-23
申请号：EP16736077.5
申请日：2016-07-05
申请人： IFP Energies nouvelles , Compagnie Générale des Etablissements Michelin , Michelin Recherche et Technique S.A.
IPC分类号： B01J37/03 , B01J37/02 , B01J23/20 , B01J35/10 , C07C1/24 , C07C1/20 , B01J37/08 , B01J37/10 , B01J21/08
CPC分类号： B01J23/20 , B01J21/08 , B01J35/1019 , B01J35/1023 , B01J35/1028 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/0203 , B01J37/0205 , B01J37/036 , B01J37/08 , B01J37/10 , B01J2523/00 , C07C1/20 , C07C2521/06 , C07C2521/08 , C07C2523/06 , C07C2523/20 , B01J2523/41 , B01J2523/56 , B01J2523/57 , B01J2523/27 , C07C11/167
摘要： The invention relates to a catalyst including a mesoporous oxide matrix, said matrix including at least one oxide of an element X selected from among silicon and titanium, taken alone or in a mixture, said catalyst including at least the element tantalum and the element niobium, the mass of tantalum making up from 0.1 to 30% of the mass of the mesoporous oxide matrix, the mass of niobium making up from 0.02 to 6% of the mass of the mesoporous oxide matrix, the mass content of the element tantalum being no lower than the mass content of the element niobium. The invention also relates to the use of said catalyst in a method for producing 1,3-butadiene from a feedstock including at least ethanol.
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公开(公告)号：EP3322531A1
公开(公告)日：2018-05-23
申请号：EP16736075.9
申请日：2016-07-05
IPC分类号： B01J37/03 , B01J37/08 , B01J37/10 , B01J21/08 , B01J23/20 , B01J37/02 , C07C1/20 , B01J35/10 , B01J23/06 , B01J23/68 , B01J23/847
CPC分类号： B01J21/08 , B01J23/06 , B01J23/20 , B01J23/682 , B01J23/847 , B01J35/1023 , B01J35/1047 , B01J35/1061 , B01J37/0201 , B01J37/036 , B01J37/08 , B01J37/10 , B01J2523/00 , B01J2523/27 , B01J2523/41 , B01J2523/57 , C07C1/20 , C07C2521/08 , C07C2523/06 , C07C2523/20 , C07C11/167
摘要： The invention relates to a mesoporous mixed-oxide catalyst including silicon and at least one metal M chosen from the group made up of the elements of groups 4 and 5 of the periodic table and the mixtures thereof, the mass of metal M making up from 0.1 to 20% of the mass of the mixed oxide. The catalyst is preferably prepared by the modern metal-organic sol-gel process. The invention also relates to the use of the catalyst to convert ethanol into butadiene.
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4.发明公开
公开(公告)号：EP3322524A1
公开(公告)日：2018-05-23
申请号：EP16739054.1
申请日：2016-07-05
CPC分类号： C07C1/20 , B01J21/08 , B01J23/20 , B01J29/0341 , B01J35/1019 , B01J35/1023 , B01J35/1061 , B01J37/0207 , B01J37/06 , B01J37/08 , C07C2521/08 , C07C2523/20 , C07C11/167
摘要： The invention relates to a catalyst including at least the element tantalum, and at least one mesoporous oxide matrix having undergone acid leaching, including at least, before leaching, 90 wt % of silica, the mass of the element tantalum making up from 0.1 to 30% of the mass of said mesoporous oxide matrix.
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5.发明公开
公开(公告)号：EP4341332A1
公开(公告)日：2024-03-27
申请号：EP22727177.2
申请日：2022-05-05
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公开(公告)号：EP3380586A1
公开(公告)日：2018-10-03
申请号：EP16794567.4
申请日：2016-11-07
IPC分类号： C10G2/00 , B01J23/74 , B01J23/75 , B01J23/89 , B01J29/03 , B01J35/10 , B01J37/00 , B01J37/03 , B01J37/18
摘要： The invention relates to a method for synthesizing linear paraffinic hydrocarbons from a feed including carbon monoxide and dihydrogen in the presence of a catalyst including a mesoporous oxide matrix and a mass percentage of cobalt of between 0.5 and 60%, expressed in wt.% of metal relative to the total weight of said catalyst, said catalyst being prepared according to a preparation method including at least the steps of: a) mixing in an aqueous or hydro-organic solvent at least one molecular precursor including cobalt and at least one colloidal precursor of said mesoporous oxide matrix including at least one element X selected from the group consisting of silicon, aluminum, titanium, zirconium, cerium and mixtures thereof, said molecular precursor including cobalt being made soluble in said aqueous or hydro-organic solvent; b) atomizing the mixture obtained in step a) to result in the formation of spherical droplets; c) drying said spherical droplets to obtain solid particles at a temperature of between 10 and 300°C; d) activating said solid particles via reductive treatment so as to form cobalt nanoparticles having a valence state of 0.
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公开(公告)号：EP2831020B1
公开(公告)日：2018-09-05
申请号：EP13719583.0
申请日：2013-03-25
CPC分类号： C07C1/24 , B01J21/12 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/108 , B01J37/0009 , C07C5/2772 , C07C2529/03 , C07C11/09 , C07C11/08
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8.发明授权
公开(公告)号：EP2296808B1
公开(公告)日：2014-07-16
申请号：EP09754064.5
申请日：2009-05-13
IPC分类号： B01J21/04 , B01J21/08 , B01J29/04 , B01J29/06 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/70 , B01J29/80 , B01J35/08 , B01J35/10 , C10G45/12 , C10G45/64 , C10G47/20
CPC分类号： C10G45/04 , B01J29/041 , B01J29/064 , B01J29/076 , B01J29/16 , B01J29/48 , B01J29/78 , B01J29/7815 , B01J29/80 , B01J35/023 , B01J35/1019 , B01J35/1057 , B01J35/1061 , B01J35/1066 , B01J37/0054 , B01J2229/10 , B01J2229/186 , B01J2229/40 , B01J2229/62 , C10G45/06 , C10G47/20 , C10G65/12
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9.发明公开PROCEDE DE PREPARATION D'UN MATERIAU SPHERIQUE A POROSITE HIERARCHISEE COMPRENANT DES PARTICULES METALLIQUES PIEGEES DANS UNE MATRICE MESOSTRUCTUREE 审中-公开用于生产球状颗粒材料具有分级的多孔与一个介孔结构基质随附的金属颗粒
公开(公告)号：EP2654947A1
公开(公告)日：2013-10-30
申请号：EP11808895.4
申请日：2011-12-15
申请人： IFP Energies Nouvelles , Université Pierre et Marie Curie , Centre National de la Recherche Scientifique
发明人： CHAUMONNOT, Alexandra , SANCHEZ, Clément , BOISSIERE, Cédric , COLBEAU-JUSTIN, Frédéric , BONDUELLE, Audrey
IPC分类号： B01J21/12 , B01J23/24 , B01J23/882 , B01J23/883 , B01J27/188 , B01J37/00 , B01J35/10 , C10G45/04 , C10G45/12 , C10G3/00 , B01J29/40 , B01J29/70 , B01J29/08
CPC分类号： B29C66/727 , B01J27/186 , B01J27/188 , B01J27/19 , B01J29/005 , B01J29/0333 , B01J29/0341 , B01J29/041 , B01J29/044 , B01J29/045 , B01J29/08 , B01J29/40 , B01J29/46 , B01J29/48 , B01J29/7007 , B01J35/002 , B01J35/006 , B01J35/023 , B01J35/1019 , B01J35/1042 , B01J35/1057 , B01J35/1061 , B01J37/0045 , B01J37/033 , B01J37/10 , B01J37/20 , C01B37/02 , C01B39/06 , C01B39/40 , C10G49/04 , C10G49/08 , Y02P30/20
摘要： A process is described for the preparation of an inorganic material with a hierarchical porosity in the micropore and mesopore domains. The material has at least two elementary spherical particles having a maximum diameter of 200 microns. The process comprises: a) preparing a solution containing zeolitic nanocrystals with a maximum nanometric dimension equal to 60 nm based on silicon and/or precursor elements of proto-zeolitic entities based on silicon; b) mixing, in solution, metallic particles or at least one metallic precursor of metallic particles, a surfactant and the solution obtained in accordance with a) such that the ratio of the volumes of inorganic and organic materials, Vinorganic/Vorganic, is 0.29 to 0.50; c) aerosol atomization of the solution obtained in b) resulting in formation of spherical droplets; d) drying the droplets; g) eliminating the template and surfactant.
摘要翻译： 方法描述了制备的无机材料与微孔和中孔结构域分级的孔隙率。 该材料具有200微米的最大直径的至少两个基本球形颗粒。 该方法包括：a）基于硅和/或基于硅原沸石实体的前体元件制备含沸石纳米晶体具有最大尺寸纳米等于60纳米的溶液; b）将在溶液中的金属粒子或金属粒子中的至少一种金属前体，表面活性剂和在雅舞蹈获得具有溶液）检验做无机和有机材料，Vinorganic / Vorganic，的体积的比例为0时29至 零点50; c）以形成球形液滴的所得中B中获得的溶液）的气溶胶雾化; d）干燥微滴; 克）消除模板和表面活性剂。
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公开(公告)号：EP2197791B1
公开(公告)日：2011-10-19
申请号：EP08845167.9
申请日：2008-08-18
IPC分类号： C01B37/00 , C01B37/02 , C01B39/00 , B01J29/00 , B01J37/00 , C01B33/113 , B01J21/06 , B01J29/06
CPC分类号： C01B39/00 , B01J20/0288 , B01J20/18 , B01J20/28019 , B01J20/28057 , B01J20/2808 , B01J20/28083 , B01J20/28085 , B01J20/28092 , B01J21/08 , B01J21/12 , B01J29/035 , B01J29/08 , B01J29/40 , B01J29/7007 , B01J35/1061 , B01J35/1066 , B01J35/109 , B01J37/0045 , B01J37/033 , C01B37/00 , C01B37/02 , C07C4/18 , Y02P20/52 , Y10T428/2982 , C07C15/04 , C07C11/06
摘要： The invention relates to a material having a hierarchised porosity and consisting of at least two elementary spherical particles having a maximum diameter of 200 microns, at least one of said spherical particles comprising at least one matrix based on silicon oxide. Said material has a macroporous volume measured by mercury porosimetry of between 0.05 and 1 ml/g, a mesoporous volume measured by nitrogen volumetry of between 0.03 and 0.4 ml/g, and the matrix comprises amorphous walls. The invention also relates to the preparation of the material.
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