摘要:
A method for producing monocyclic aromatic hydrocarbons includes a cracking/reforming reaction step of introducing the feedstock oil into a cracking/reforming reactor, bringing the feedstock oil into contact with the catalyst, and causing the feedstock oil to react, thereby obtaining a product, a purification/recovery step of purifying and recovering the monocyclic aromatic hydrocarbons separated from the product produced in the cracking/reforming reaction step, a hydrogenation reaction step of hydrogenating a heavy fraction separated from the product produced in the cracking/reforming reaction step, and a recycling step of returning a hydrogenation reactant of the heavy fraction obtained in the hydrogenation reaction step to the cracking/reforming reaction step. In the recycling step, the hydrogenation reactant of the heavy fraction is introduced at a location different from an introduction location of the feedstock oil into the cracking/reforming reactor so that a time during which the hydrogenation reactant of the heavy fraction is in contact with the catalyst for monocyclic aromatic hydrocarbon production in the cracking/reforming reactor becomes shorter than a time during which the feedstock oil is in contact with the catalyst for monocyclic aromatic hydrocarbon production in the cracking/reforming reactor.
摘要:
A method for producing monocyclic aromatic hydrocarbons includes a cracking and reforming reaction step of obtaining products containing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms and a heavy fraction having 9 or more carbon atoms by bringing the feedstock oil into contact with a catalyst for producing monocyclic aromatic hydrocarbons containing crystalline aluminosilicate to cause a reaction, a catalyst separation step of separating and removing the catalyst for producing monocyclic aromatic hydrocarbons together with tricyclic aromatic hydrocarbons contained in the products from a mixture of the products and a small amount of the catalyst for producing monocyclic aromatic hydrocarbons carried by the products, both of which are derived in the cracking and reforming reaction step, and a purification and recovery step of purifying and recovering the monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms which are separated from the products formed in the cracking and reforming reaction step.
摘要:
A method for producing an olefin and a monocyclic aromatic hydrocarbon of the present invention includes a cracking and reforming reaction step of obtaining a product containing an olefin and a monocyclic aromatic hydrocarbon by bringing a feedstock oil which is a thermally-cracked heavy oil obtained from an apparatus for producing ethylene which includes a cracking furnace and a product collection device that separates and collects an olefin and an aromatic hydrocarbon from a cracked product produced in the cracking furnace and which has a 90 volume% distillate temperature, as a distillation characteristic, of 390°C or lower into contact with a catalyst and reacting the feedstock oil; and a product collection step of collecting the olefin and the monocyclic aromatic hydrocarbon respectively by treating the product obtained in the cracking and reforming reaction step using the product collection device in the apparatus for producing ethylene.
摘要:
Provided is a method for producing aromatic hydrocarbons, by which a feedstock containing a hydrogenation-treated oil of a thermally cracked heavy oil obtainable from an ethylene production apparatus is brought into contact with a catalyst for monocyclic aromatic hydrocarbon production containing a crystalline aluminosilicate, and thereby aromatic hydrocarbons are produced. A raw material having an end point of the distillation characteristics of 400°C or lower is used as the feedstock. The contact between the feedstock and the catalyst for monocyclic aromatic hydrocarbon production is carried out at a pressure of 0.1 MPaG to 1.5 MPaG.
摘要:
A method of producing monocyclic aromatic hydrocarbons of the present invention includes bringing a light feedstock oil having a 10 vol% distillation temperature of 140°C to 205 °C and a 90 vol% distillation temperature of 300°C or lower, which has been prepared from a feedstock oil having a 10 vol% distillation temperature of 140°C or higher and a 90 vol% distillation temperature of 380°C or lower, into contact with a catalyst for monocyclic aromatic hydrocarbon production containing a crystalline aluminosilicate, in which a content ratio of monocyclic naphthenobenzenes in the light feedstock oil is adjusted by distillation of the feedstock oil such that the content ratio of monocyclic naphthenobenzenes in the light feedstock oil is higher than a content ratio of monocyclic naphthenobenzenes in the feedstock oil. According to the present invention, a method of producing a BTX fraction from a fraction containing a light cycle oil (LCO) produced by a FCC apparatus, which enables a more efficient production of the BTX fraction than conventional methods without the coexistence of high-pressure molecular hydrogen, can be provided.